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ScOH(CH3SO3)2, a Basic Methanesulfonate of Scandium with Chain Structure
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Mathias S. Wickleder
and
Ingrid Müller
Published/Copyright:
June 2, 2014
Abstract
Single crystals of ScOH(CH3SO3)2 were obtained from a solution of Sc2(CO3)3 in methanesulfonic acid at pH 7. According to the X-ray single crystal structure determination, the compound crystallizes with the non-centrosymmetric orthorhombic space group Pmc21 (Z = 8, a = 743.92(8), b = 1497.7(3), c = 1540.1(2) pm, Rall = 0.0925) and contains the Sc3+ ions in octahedral coordination of oxygen atoms which belong to two OH− and four CH3SO3 − ions. The linkage of the Sc3+ ions leads to chains according to the formulation 1∞[Sc(CH3SO3)4/2(OH)2/2] which are oriented along the [100] direction and connected via hydrogen bonds. The IR spectrum of the compound shows the typical bands of the CH3SO3 − ion.
Received: 2003-10-22
Published Online: 2014-6-2
Published in Print: 2004-1-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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