Article
Licensed
Unlicensed
Requires Authentication
Synthesis and Characterization of N-Methyl-Substituted Germocanes. Crystal Structure of MeN(CH2CH2O)2GeBr2
-
,
Published/Copyright:
June 2, 2014
The reaction of GeHal4 with MeN(CH2CH2OSiMe3)2 affords dihalogermocanes MeN(CH2 CH2O)2GeHal2 (1, Hal = Br; 2, Hal = Cl). Treatment of Me2Ge(NMe2)2 with MeN(CH2CH2OH)2 leads to dimethylgermocane MeN(CH2CH2O)2GeMe2 (3). The composition and structure of 1-3 were established by elemental analyses, 1H, 13C NMR spectroscopy, and mass spectrometry. The crystal structure of 1 is reported; structural data obtained from geometry DFT optimization on 1 are in good agreement with experimental results. Values of the electron density in the N→Ge bond critical point and the Laplacian of charge density for 1-3 indicate a closed-shell interaction between the Ge and N atoms.
Received: 2003-7-31
Published Online: 2014-6-2
Published in Print: 2003-12-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Atomvolumen, Packungsdichte undWertigkeit von Caesium unter Druck Atomic Volume, Packing Density and Valence of Cesium under Pressure
- Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene
- Synthesis and Characterization of N-Methyl-Substituted Germocanes. Crystal Structure of MeN(CH2CH2O)2GeBr2
- Molecular Structure and Thermal Analysis of Potassium Hydrogenphthalate Monohydrate
- Synthese flexibler difluorierter cyclopropanoider Nucleosidanaloga / Synthesis of Flexible Difluorinated Cyclopropanoid Nucleoside Analogues
- Electroreduction of Organic Compounds, 34 [1]. Cathodic Dehalogenation of Chloroarenes with Electron-Donating Substituents
- Kinetics of Oxidation of Benzaldehydes by Quinolinium Dichromate
- New Isoflavonoid from Dipterix odorata
- Frankiamide: A Structural Revision to Demethyl (C-11) Cezomycin
- Xyloccensin M and N, Two New B, D-seco Limonoids from Xylocarpus granatum
- Titanyl Acetylacetonate as an Efficient Catalyst for a Mild and Convenient Reduction of Carbonyl Compounds with NaBH4 under Aprotic Condition
- A Convenient Synthesis of New Pentaazacyclopentanaphthalene and Pentaazaphenanthrene Derivates
- A New Pyranoacridone Alkaloid from the Bark of Medicosma subsessilis (Rutaceae)
- Synthesis of Some New Furocoumarins and their Usage in Peptide Synthesis
- Isolation, Structure Elucidation and Activity of Anthracycline Acetates from a Terrestrial Streptomyces sp.
- Synthesis of Spacered Cyclopropanoid Muramyldipeptide Analogues as Potential Immunostimulants
Articles in the same Issue
- Atomvolumen, Packungsdichte undWertigkeit von Caesium unter Druck Atomic Volume, Packing Density and Valence of Cesium under Pressure
- Dinuclear Nickel(II) and Palladium(II) Complexes in Combination with Different Co-Catalysts as Highly Active Catalysts for the Vinyl/Addition Polymerization of Norbornene
- Synthesis and Characterization of N-Methyl-Substituted Germocanes. Crystal Structure of MeN(CH2CH2O)2GeBr2
- Molecular Structure and Thermal Analysis of Potassium Hydrogenphthalate Monohydrate
- Synthese flexibler difluorierter cyclopropanoider Nucleosidanaloga / Synthesis of Flexible Difluorinated Cyclopropanoid Nucleoside Analogues
- Electroreduction of Organic Compounds, 34 [1]. Cathodic Dehalogenation of Chloroarenes with Electron-Donating Substituents
- Kinetics of Oxidation of Benzaldehydes by Quinolinium Dichromate
- New Isoflavonoid from Dipterix odorata
- Frankiamide: A Structural Revision to Demethyl (C-11) Cezomycin
- Xyloccensin M and N, Two New B, D-seco Limonoids from Xylocarpus granatum
- Titanyl Acetylacetonate as an Efficient Catalyst for a Mild and Convenient Reduction of Carbonyl Compounds with NaBH4 under Aprotic Condition
- A Convenient Synthesis of New Pentaazacyclopentanaphthalene and Pentaazaphenanthrene Derivates
- A New Pyranoacridone Alkaloid from the Bark of Medicosma subsessilis (Rutaceae)
- Synthesis of Some New Furocoumarins and their Usage in Peptide Synthesis
- Isolation, Structure Elucidation and Activity of Anthracycline Acetates from a Terrestrial Streptomyces sp.
- Synthesis of Spacered Cyclopropanoid Muramyldipeptide Analogues as Potential Immunostimulants
