Home Decarbonylation of Pentamethylcyclopentadienyl Tetracarbonylvanadium, Cp*V(CO)4, in the Presence of Oxygen. The X-Ray Crystal Structure Analyses of Cp*V(CO)4 and [Cp*V(O)(μ-O)]4
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Decarbonylation of Pentamethylcyclopentadienyl Tetracarbonylvanadium, Cp*V(CO)4, in the Presence of Oxygen. The X-Ray Crystal Structure Analyses of Cp*V(CO)4 and [Cp*V(O)(μ-O)]4

  • Max Herberhold EMAIL logo , Anna-Maria Dietel and Wolfgang Milius
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 58 Issue 4

The reaction of Cp*V(CO)4 (1) with molecular oxygen in diluted pentane solution leads to a tetrameric dioxide, [Cp*V(O)(μ-O)]4 (2), which is a precursor of the octanuclear aggregate Cp*6V8O17 (3). The molecular structures of 1 and 2 have been determined by X-ray crystallography.

Keywords: Vanadium; Organometallic Oxides; Crystal Structures
Received: 2002-12-17
Published Online: 2014-6-2
Published in Print: 2003-4-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Bis(trimethylphosphan)-η5-cyclopentadienyl- tert- butylimidovanadium( III): Reaktionen mit Schwefel, Selen, Tellur und Iod
  2. Von Fluorsilylamiden zu Element-Silylamiden und Iminosilanen
  3. β-CaB4O7: A New Polymorph Synthesized under High-Pressure/High-Temperature Conditions
  4. New Dinuclear Mn(II) Phenanthroline Adipato Complex: Synthesis and Structural and Thermal Characterization of Mn2(phen)2(H2O)2(C6H8O4)2
  5. Crystal Structure and Magnetic Properties of a New Hetero-Dinuclear CuIIMnII Schiff Base Complex
  6. High-Pressure Preparation, Crystal Structure, and Properties of RE4B6O15 (RE = Dy, Ho) with an Extension of the “Fundamental Building Block”-Descriptors
  7. Novel Asymmetrical Dianionic Polyimido-Sulfur(IV)-Ylides
  8. Decarbonylation of Pentamethylcyclopentadienyl Tetracarbonylvanadium, Cp*V(CO)4, in the Presence of Oxygen. The X-Ray Crystal Structure Analyses of Cp*V(CO)4 and [Cp*V(O)(μ-O)]4
  9. Formation of a Doubly C,N-Bridged Six-Membered Metallacyclic Bis[(2-imidazolyl)zirconocene] Dication
  10. Metallkomplexe mit biologisch wichtigen Liganden, CL [1]. 1,1-Dithiolato-Komplex von Palladium(II), Platin(II) und Gold(I) aus Diphenylmethylenglycinester sowie N,N-Dimethylglycinester und Schwefelkohlenstoff
  11. Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat
  12. Methoxyabietane Diterpenoid from the Root of Salvia phlomoides and Structural Correction of Another Diterpene from Cryptomeria japonica
  13. Access to Orthogonal Protected Phenols – Synthesis of a Silylated Quinol
  14. A New Prenylated Hydroquinone from the Roots of Garcinia atroviridis Griff ex T. Anders (Guttiferae)
  15. Simple Synthesis, Characterization and Structure of Diorganotin(IV) Complexes Containing the N-(2-Salicylidene)-N'-benzoylhydrazone Ligand
  16. Synthese monofluorierter cyclopropanoider Nucleosidanaloga
  17. Crystal Structure of a New Dimethyl Carbonate/2,4,6-Tris(trifluoromethyl)- 1,3,5-triazine 1:1 Adduct
  18. Synthesis and Molecular Structure of [Fe2Cl2(μ-S-tBu)2(η1-η1-μ-dppe)] (dppe = Ph2P(CH2)2PPh2)
https://doi.org/10.1515/znb-2003-0408
Keywords for this article
Vanadium; Organometallic Oxides; Crystal Structures

Articles in the same Issue

  1. Bis(trimethylphosphan)-η5-cyclopentadienyl- tert- butylimidovanadium( III): Reaktionen mit Schwefel, Selen, Tellur und Iod
  2. Von Fluorsilylamiden zu Element-Silylamiden und Iminosilanen
  3. β-CaB4O7: A New Polymorph Synthesized under High-Pressure/High-Temperature Conditions
  4. New Dinuclear Mn(II) Phenanthroline Adipato Complex: Synthesis and Structural and Thermal Characterization of Mn2(phen)2(H2O)2(C6H8O4)2
  5. Crystal Structure and Magnetic Properties of a New Hetero-Dinuclear CuIIMnII Schiff Base Complex
  6. High-Pressure Preparation, Crystal Structure, and Properties of RE4B6O15 (RE = Dy, Ho) with an Extension of the “Fundamental Building Block”-Descriptors
  7. Novel Asymmetrical Dianionic Polyimido-Sulfur(IV)-Ylides
  8. Decarbonylation of Pentamethylcyclopentadienyl Tetracarbonylvanadium, Cp*V(CO)4, in the Presence of Oxygen. The X-Ray Crystal Structure Analyses of Cp*V(CO)4 and [Cp*V(O)(μ-O)]4
  9. Formation of a Doubly C,N-Bridged Six-Membered Metallacyclic Bis[(2-imidazolyl)zirconocene] Dication
  10. Metallkomplexe mit biologisch wichtigen Liganden, CL [1]. 1,1-Dithiolato-Komplex von Palladium(II), Platin(II) und Gold(I) aus Diphenylmethylenglycinester sowie N,N-Dimethylglycinester und Schwefelkohlenstoff
  11. Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat
  12. Methoxyabietane Diterpenoid from the Root of Salvia phlomoides and Structural Correction of Another Diterpene from Cryptomeria japonica
  13. Access to Orthogonal Protected Phenols – Synthesis of a Silylated Quinol
  14. A New Prenylated Hydroquinone from the Roots of Garcinia atroviridis Griff ex T. Anders (Guttiferae)
  15. Simple Synthesis, Characterization and Structure of Diorganotin(IV) Complexes Containing the N-(2-Salicylidene)-N'-benzoylhydrazone Ligand
  16. Synthese monofluorierter cyclopropanoider Nucleosidanaloga
  17. Crystal Structure of a New Dimethyl Carbonate/2,4,6-Tris(trifluoromethyl)- 1,3,5-triazine 1:1 Adduct
  18. Synthesis and Molecular Structure of [Fe2Cl2(μ-S-tBu)2(η1-η1-μ-dppe)] (dppe = Ph2P(CH2)2PPh2)
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