Home Polysulfonylamine, CLXI. Ein neuartiges 1,2-Dihydroimidazochinolinylium-Kation: Zufällige Isolierung und Kristallstruktur des entsprechenden Dimesylamids Polysulfonylamines, CLXI. A Novel 1,2-Dihydroimidazoquinolinylium Cation: Serendipitous Isolation and Crystal Structure of the Corresponding Dimesylamide
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Polysulfonylamine, CLXI. Ein neuartiges 1,2-Dihydroimidazochinolinylium-Kation: Zufällige Isolierung und Kristallstruktur des entsprechenden Dimesylamids Polysulfonylamines, CLXI. A Novel 1,2-Dihydroimidazoquinolinylium Cation: Serendipitous Isolation and Crystal Structure of the Corresponding Dimesylamide

  • Karna Wijaya , Oliver Moers , Armand Blaschette and Peter G. Jones EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 11

Orange-coloured 1,2-dihydro-2,2-dimethyl-imidazo[4,5,1-ij]quinolinylium dimesylamide (1) was accidentally obtained on treating 8-aminoquinoline with one equivalent of dimesylamine in acetone solution. To the best of the authors’ knowledge, the tricyclic cation in question or congeners thereof have not been reported previously. The crystal structure of 1 (monoclinic, space group P21/c, Z = 4; - 130 °C) consists of (MeSO2)N- layers, between which the cations are intercalated to form centrosymmetric (π-π)-bonded pairs. Each cation is connected to the adjacent anion layers by a conventional NDH···(O,N) three-centre hydrogen bond and a set of weak C(sp2)DH···O = S and CH2DH···O = S interactions.

Keywords: Heterocyclic Cation; Di(methanesulfonyl)amide; Hydrogen Bonding
Received: 2002-8-8
Published Online: 2014-6-2
Published in Print: 2002-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. A Pyrazine-Bridged Ni(II) Coordination Polymer
  2. Synthesis and Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium N,N'-Diphenylureate
  3. Darstellung und Thermolyse tert-butylsubstituierter Silatetrazoline – Erzeugung der Silanimine tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu) Synthesis and Thermolysis of the tert-Butyl-Substituted Silatetrazolines – Formation of the Silanimines tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu)
  4. Synthesis and Reactivity of Cyclopentadienyl and Indenyl Ligands Bearing ω-Fluorinated Pendant Groups. Crystal Structure of (ortho-F-C6H4)-CPh2-C5H4SiMe3
  5. Ternary Antimonides YbTSb (T = Ni, Pd, Pt, Cu, Ag, Au) – Synthesis, Structure, Homogeneity Ranges, and 121Sb Mössbauer Spectroscopy
  6. Studies of Monothiomalonamide and its Palladium(II) and Platinum(II) Complexes
  7. Synthese, Kristallstruktur und Spektroskopische Charakterisierung des Phosphaniminato-Komplexes [Cl2AlNPCl3]2 und des Phosphanimin-Komplexes [Me3SiNPCl3 · AlCl3]/Synthesis, Crystal Structure, and Spectroscopic Characterization of the Phosphorane Iminato Complex [Cl2AlNPCl3]2, and of the Phosphane Imine Complex [Me3SiNPCl3 · AlCl3]
  8. Magnetic Exchange Based on π-π Stacking Interactions: Synthesis, Crystal Structure, Thermal Decomposition and Magnetic Properties of [Ce(phen)2(H2O)2(NO3)2](NO3)(phen)2(H2O)
  9. Isomerisation of Alkenes Bearing Stannyl and Boryl Groups at the C=C Bond
  10. Tetrapodal Pentadentate Ligands with NS4 and NP4 Donor Sets: An Elusive Tetrathiol, and a Sterically Encumbered Tetraphosphane
  11. K1.10Zr2Se6, Rb0.86Zr2Se6 and Cs0.80Zr2Se6. The First Intercalation Compounds of Zirconium Triselenide
  12. Neue Pnictide im CaAl2Si2-Typ und dessen Existenzgebiet/New Pnictides with the CaAl2Si2 Type Structure and the Stability Range of this Type
  13. Polysulfonylamine, CLXI. Ein neuartiges 1,2-Dihydroimidazochinolinylium-Kation: Zufällige Isolierung und Kristallstruktur des entsprechenden Dimesylamids Polysulfonylamines, CLXI. A Novel 1,2-Dihydroimidazoquinolinylium Cation: Serendipitous Isolation and Crystal Structure of the Corresponding Dimesylamide
  14. A New Trinuclear Cyano-Bridged Sr-Fe(III) Complex, [Sr2(phen)4(H2O)3(NO3)Fe(CN)6] · H2O
  15. Synthese difluorierter cyclopropanoider Nucleosidanaloga/Synthesis of Difluorinated Cyclopropanoid Nucleoside Analogues
  16. Orthoamide, LIX. Formyl-aalen [Tris(diformylamino)methan] – ein neues Formylierungsmittel für aktivierte Aromaten/Orthoamides, LIX. Formyl-aalen [Tris(diformylamino)methane] – a New Formylating Reagent for Activated Aromatic Compounds
  17. Molecular Complexes, 13. Weak Arene Complexes of Nitroaromatics. 1H NMR Studies of Conformations and Polar Effects. syn-anti Selectivity of 5-Nitrofurfural
  18. Crystal and Molecular Structure of 4-Arylhexahydro-1H,3H-pyrido[1,2-c]pyrimidine-1,3-dione Derivatives
  19. Kinetic Studies of Condensation of Aromatic Aldehydes with Meldrum’s Acid
  20. Bischler-Napieralski Synthesis of Some New Pyrazole-Fused β-Carbolines
  21. Novel and Facile Synthesis of Pyrazolo[3,4-d]pyrimidines
https://doi.org/10.1515/znb-2002-1113
Keywords for this article
Heterocyclic Cation; Di(methanesulfonyl)amide; Hydrogen Bonding

Articles in the same Issue

  1. A Pyrazine-Bridged Ni(II) Coordination Polymer
  2. Synthesis and Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium N,N'-Diphenylureate
  3. Darstellung und Thermolyse tert-butylsubstituierter Silatetrazoline – Erzeugung der Silanimine tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu) Synthesis and Thermolysis of the tert-Butyl-Substituted Silatetrazolines – Formation of the Silanimines tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu)
  4. Synthesis and Reactivity of Cyclopentadienyl and Indenyl Ligands Bearing ω-Fluorinated Pendant Groups. Crystal Structure of (ortho-F-C6H4)-CPh2-C5H4SiMe3
  5. Ternary Antimonides YbTSb (T = Ni, Pd, Pt, Cu, Ag, Au) – Synthesis, Structure, Homogeneity Ranges, and 121Sb Mössbauer Spectroscopy
  6. Studies of Monothiomalonamide and its Palladium(II) and Platinum(II) Complexes
  7. Synthese, Kristallstruktur und Spektroskopische Charakterisierung des Phosphaniminato-Komplexes [Cl2AlNPCl3]2 und des Phosphanimin-Komplexes [Me3SiNPCl3 · AlCl3]/Synthesis, Crystal Structure, and Spectroscopic Characterization of the Phosphorane Iminato Complex [Cl2AlNPCl3]2, and of the Phosphane Imine Complex [Me3SiNPCl3 · AlCl3]
  8. Magnetic Exchange Based on π-π Stacking Interactions: Synthesis, Crystal Structure, Thermal Decomposition and Magnetic Properties of [Ce(phen)2(H2O)2(NO3)2](NO3)(phen)2(H2O)
  9. Isomerisation of Alkenes Bearing Stannyl and Boryl Groups at the C=C Bond
  10. Tetrapodal Pentadentate Ligands with NS4 and NP4 Donor Sets: An Elusive Tetrathiol, and a Sterically Encumbered Tetraphosphane
  11. K1.10Zr2Se6, Rb0.86Zr2Se6 and Cs0.80Zr2Se6. The First Intercalation Compounds of Zirconium Triselenide
  12. Neue Pnictide im CaAl2Si2-Typ und dessen Existenzgebiet/New Pnictides with the CaAl2Si2 Type Structure and the Stability Range of this Type
  13. Polysulfonylamine, CLXI. Ein neuartiges 1,2-Dihydroimidazochinolinylium-Kation: Zufällige Isolierung und Kristallstruktur des entsprechenden Dimesylamids Polysulfonylamines, CLXI. A Novel 1,2-Dihydroimidazoquinolinylium Cation: Serendipitous Isolation and Crystal Structure of the Corresponding Dimesylamide
  14. A New Trinuclear Cyano-Bridged Sr-Fe(III) Complex, [Sr2(phen)4(H2O)3(NO3)Fe(CN)6] · H2O
  15. Synthese difluorierter cyclopropanoider Nucleosidanaloga/Synthesis of Difluorinated Cyclopropanoid Nucleoside Analogues
  16. Orthoamide, LIX. Formyl-aalen [Tris(diformylamino)methan] – ein neues Formylierungsmittel für aktivierte Aromaten/Orthoamides, LIX. Formyl-aalen [Tris(diformylamino)methane] – a New Formylating Reagent for Activated Aromatic Compounds
  17. Molecular Complexes, 13. Weak Arene Complexes of Nitroaromatics. 1H NMR Studies of Conformations and Polar Effects. syn-anti Selectivity of 5-Nitrofurfural
  18. Crystal and Molecular Structure of 4-Arylhexahydro-1H,3H-pyrido[1,2-c]pyrimidine-1,3-dione Derivatives
  19. Kinetic Studies of Condensation of Aromatic Aldehydes with Meldrum’s Acid
  20. Bischler-Napieralski Synthesis of Some New Pyrazole-Fused β-Carbolines
  21. Novel and Facile Synthesis of Pyrazolo[3,4-d]pyrimidines
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