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A Pyrazine-Bridged Ni(II) Coordination Polymer

  • Chirantan Roy Choudhury , Subrata Kumar Dey , Sutapa Sen , Bappaditya Bag , Samiran Mitra EMAIL logo and Volker Gramlich
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 11

The single pyrazine-bridged polymeric complex {[Ni(pyz)(H2O)4](NO3)2.2H2O}n has been synthesised and characterised by elemental analyses, IR and UV-vis spectra, and a single-crystal X-ray diffraction study. The coordination around the Ni centre is perfectly octahedral. The Ni(H2O)4 coordination planes are bridged by pyrazine ligands forming an infinite chain structure. Two nitrate anions and two water molecules exist in the lattice and are linked by intermolecular hydrogen bonds to the coordinated water molecules.

Keywords: Polymeric Ni(II) Complex; Pyrazine-Bridged Ni(II) Coordination Polymer
Received: 2002-5-28
Published Online: 2014-6-2
Published in Print: 2002-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. A Pyrazine-Bridged Ni(II) Coordination Polymer
  2. Synthesis and Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium N,N'-Diphenylureate
  3. Darstellung und Thermolyse tert-butylsubstituierter Silatetrazoline – Erzeugung der Silanimine tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu) Synthesis and Thermolysis of the tert-Butyl-Substituted Silatetrazolines – Formation of the Silanimines tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu)
  4. Synthesis and Reactivity of Cyclopentadienyl and Indenyl Ligands Bearing ω-Fluorinated Pendant Groups. Crystal Structure of (ortho-F-C6H4)-CPh2-C5H4SiMe3
  5. Ternary Antimonides YbTSb (T = Ni, Pd, Pt, Cu, Ag, Au) – Synthesis, Structure, Homogeneity Ranges, and 121Sb Mössbauer Spectroscopy
  6. Studies of Monothiomalonamide and its Palladium(II) and Platinum(II) Complexes
  7. Synthese, Kristallstruktur und Spektroskopische Charakterisierung des Phosphaniminato-Komplexes [Cl2AlNPCl3]2 und des Phosphanimin-Komplexes [Me3SiNPCl3 · AlCl3]/Synthesis, Crystal Structure, and Spectroscopic Characterization of the Phosphorane Iminato Complex [Cl2AlNPCl3]2, and of the Phosphane Imine Complex [Me3SiNPCl3 · AlCl3]
  8. Magnetic Exchange Based on π-π Stacking Interactions: Synthesis, Crystal Structure, Thermal Decomposition and Magnetic Properties of [Ce(phen)2(H2O)2(NO3)2](NO3)(phen)2(H2O)
  9. Isomerisation of Alkenes Bearing Stannyl and Boryl Groups at the C=C Bond
  10. Tetrapodal Pentadentate Ligands with NS4 and NP4 Donor Sets: An Elusive Tetrathiol, and a Sterically Encumbered Tetraphosphane
  11. K1.10Zr2Se6, Rb0.86Zr2Se6 and Cs0.80Zr2Se6. The First Intercalation Compounds of Zirconium Triselenide
  12. Neue Pnictide im CaAl2Si2-Typ und dessen Existenzgebiet/New Pnictides with the CaAl2Si2 Type Structure and the Stability Range of this Type
  13. Polysulfonylamine, CLXI. Ein neuartiges 1,2-Dihydroimidazochinolinylium-Kation: Zufällige Isolierung und Kristallstruktur des entsprechenden Dimesylamids Polysulfonylamines, CLXI. A Novel 1,2-Dihydroimidazoquinolinylium Cation: Serendipitous Isolation and Crystal Structure of the Corresponding Dimesylamide
  14. A New Trinuclear Cyano-Bridged Sr-Fe(III) Complex, [Sr2(phen)4(H2O)3(NO3)Fe(CN)6] · H2O
  15. Synthese difluorierter cyclopropanoider Nucleosidanaloga/Synthesis of Difluorinated Cyclopropanoid Nucleoside Analogues
  16. Orthoamide, LIX. Formyl-aalen [Tris(diformylamino)methan] – ein neues Formylierungsmittel für aktivierte Aromaten/Orthoamides, LIX. Formyl-aalen [Tris(diformylamino)methane] – a New Formylating Reagent for Activated Aromatic Compounds
  17. Molecular Complexes, 13. Weak Arene Complexes of Nitroaromatics. 1H NMR Studies of Conformations and Polar Effects. syn-anti Selectivity of 5-Nitrofurfural
  18. Crystal and Molecular Structure of 4-Arylhexahydro-1H,3H-pyrido[1,2-c]pyrimidine-1,3-dione Derivatives
  19. Kinetic Studies of Condensation of Aromatic Aldehydes with Meldrum’s Acid
  20. Bischler-Napieralski Synthesis of Some New Pyrazole-Fused β-Carbolines
  21. Novel and Facile Synthesis of Pyrazolo[3,4-d]pyrimidines
https://doi.org/10.1515/znb-2002-1101
Keywords for this article
Polymeric Ni(II) Complex; Pyrazine-Bridged Ni(II) Coordination Polymer

Articles in the same Issue

  1. A Pyrazine-Bridged Ni(II) Coordination Polymer
  2. Synthesis and Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium N,N'-Diphenylureate
  3. Darstellung und Thermolyse tert-butylsubstituierter Silatetrazoline – Erzeugung der Silanimine tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu) Synthesis and Thermolysis of the tert-Butyl-Substituted Silatetrazolines – Formation of the Silanimines tBu2Si=N-SiXtBu2 (X = F, Cl, Br, tBu)
  4. Synthesis and Reactivity of Cyclopentadienyl and Indenyl Ligands Bearing ω-Fluorinated Pendant Groups. Crystal Structure of (ortho-F-C6H4)-CPh2-C5H4SiMe3
  5. Ternary Antimonides YbTSb (T = Ni, Pd, Pt, Cu, Ag, Au) – Synthesis, Structure, Homogeneity Ranges, and 121Sb Mössbauer Spectroscopy
  6. Studies of Monothiomalonamide and its Palladium(II) and Platinum(II) Complexes
  7. Synthese, Kristallstruktur und Spektroskopische Charakterisierung des Phosphaniminato-Komplexes [Cl2AlNPCl3]2 und des Phosphanimin-Komplexes [Me3SiNPCl3 · AlCl3]/Synthesis, Crystal Structure, and Spectroscopic Characterization of the Phosphorane Iminato Complex [Cl2AlNPCl3]2, and of the Phosphane Imine Complex [Me3SiNPCl3 · AlCl3]
  8. Magnetic Exchange Based on π-π Stacking Interactions: Synthesis, Crystal Structure, Thermal Decomposition and Magnetic Properties of [Ce(phen)2(H2O)2(NO3)2](NO3)(phen)2(H2O)
  9. Isomerisation of Alkenes Bearing Stannyl and Boryl Groups at the C=C Bond
  10. Tetrapodal Pentadentate Ligands with NS4 and NP4 Donor Sets: An Elusive Tetrathiol, and a Sterically Encumbered Tetraphosphane
  11. K1.10Zr2Se6, Rb0.86Zr2Se6 and Cs0.80Zr2Se6. The First Intercalation Compounds of Zirconium Triselenide
  12. Neue Pnictide im CaAl2Si2-Typ und dessen Existenzgebiet/New Pnictides with the CaAl2Si2 Type Structure and the Stability Range of this Type
  13. Polysulfonylamine, CLXI. Ein neuartiges 1,2-Dihydroimidazochinolinylium-Kation: Zufällige Isolierung und Kristallstruktur des entsprechenden Dimesylamids Polysulfonylamines, CLXI. A Novel 1,2-Dihydroimidazoquinolinylium Cation: Serendipitous Isolation and Crystal Structure of the Corresponding Dimesylamide
  14. A New Trinuclear Cyano-Bridged Sr-Fe(III) Complex, [Sr2(phen)4(H2O)3(NO3)Fe(CN)6] · H2O
  15. Synthese difluorierter cyclopropanoider Nucleosidanaloga/Synthesis of Difluorinated Cyclopropanoid Nucleoside Analogues
  16. Orthoamide, LIX. Formyl-aalen [Tris(diformylamino)methan] – ein neues Formylierungsmittel für aktivierte Aromaten/Orthoamides, LIX. Formyl-aalen [Tris(diformylamino)methane] – a New Formylating Reagent for Activated Aromatic Compounds
  17. Molecular Complexes, 13. Weak Arene Complexes of Nitroaromatics. 1H NMR Studies of Conformations and Polar Effects. syn-anti Selectivity of 5-Nitrofurfural
  18. Crystal and Molecular Structure of 4-Arylhexahydro-1H,3H-pyrido[1,2-c]pyrimidine-1,3-dione Derivatives
  19. Kinetic Studies of Condensation of Aromatic Aldehydes with Meldrum’s Acid
  20. Bischler-Napieralski Synthesis of Some New Pyrazole-Fused β-Carbolines
  21. Novel and Facile Synthesis of Pyrazolo[3,4-d]pyrimidines
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