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X-Ray and Raman Investigations on Cyanides ofMono- and DivalentMetals and Synthesis, Crystal Structure and Raman Spectrum of Tl5(CO3)2(CN)

  • Olaf Reckeweg EMAIL logo and Arndt Simon
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 8

Pseudobinary cyanides of monovalent and divalent metals were synthesized, and X-ray and Raman data of the cyanides were measured. Single crystal X-ray structure analyses were performed on Zn(CN)2 (Pn3̄m (No. 224), a = 591.32(7) pm), Hg(CN)2 (I4̄2d (No. 122), a = 969.22(14) and c = 890,15(18) pm) and for the first time on AgCN (I4̄2d (No. 166), a = 600.58(8) and c = 526.28(11) pm). The data are compared with literature data. The reaction of TlF and NaCN in 25% aqueous ammonia solution in air led to Tl5(CO3)2(CN) which was characterized by X-ray (Cmca (No. 64), 1468.1(3), 1171.6(2) and 1266.0(3) pm) and Raman spectroscopy.

Keywords: Carbonate; Cyanide; Raman Spectroscopy
Received: 2002-4-10
Published Online: 2014-6-2
Published in Print: 2002-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Wechselwirkungen in Molekülkristallen, 180 [1, 2]. σ-Donator/Akzeptor-Komplexe {S(CI)4···X⊖ }(X⊖ = I⊖ , SCN⊖ ) von Tetraiodthiophen in Tetra(n-butyl)ammoniumhalogenid-Salzen/Interaction in Molecular Crystals, 180 [1, 2]. -Donor/Acceptor Complexes {S(CI)4···X⊖} (X⊖= I⊖, SCN⊖ of Tetraiodothiophene in Tetra(n-butyl)ammonium Halide Salts
  2. Wechselwirkungen in Molekülkristallen, 181 [1, 2]. σ-Donator/Akzeptor-Komplexe {MAI4···X⊖ } (X⊖ = Br⊖ , I⊖ , SCN⊖ ) der Tetraiod-Akzeptormoleküle MAI4 (MA = Ethen, Thiophen, N-Methylpyrrol) in Tetraphenylphosphoniumhalogenid-Salzen Interaction in Molecular Crystals, 181 [1, 2]. σ-Donor/Acceptor Complexes {MAI4···X⊖ }(X⊖ = Br⊖, I⊖, SCN⊖ of Tetraiodo Acceptor Molecules MAI4 (MA = Ethene, Thiophene, N-Methylpyrrole) in Tetraphenylphosphonium Halide Salts
  3. Synthesis of SrxBa(1-x)TiO3 Solid Solutions from the Mechanically Activated System BaCO3 - SrCO3 - TiO2
  4. Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a Ligand
  5. Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2. V. Ytterbiumselenoxide auf dem Schnitt Yb2O3-SeO2/Thermochemical Investigations of Systems RE2O3-SeO2. V. Ytterbium Selenium Oxides on the Line Yb2O3-SeO2
  6. Implications of the Results of a Routine Structure Determination: Tris(triphenylphosphine)gold(I) Chloride Bis(dichloromethane)
  7. Structural, Spectroscopic and Theoretical Studies of (tButyl-isocyanide)gold(I) Iodide
  8. Preparation and Crystal Structure of Bis(isocyanide)gold(I) Bis(phenylene-1,2-dithiolato)aurates(III)
  9. X-Ray and Raman Investigations on Cyanides ofMono- and DivalentMetals and Synthesis, Crystal Structure and Raman Spectrum of Tl5(CO3)2(CN)
  10. A New Mixed Valent Europium Chloride: Na5Eu7Cl22
  11. Structure of N-Methylisatin N(4)-Dimethylthiosemicarbazone and its Electrochemically Synthesized 6-Coordinate Cadmium(II) Complex
  12. Crystal Structures of Seven Terephthaldiamide Derivatives
  13. [4 + 2]-Cycloaddition Reactions Involving α-Oxo Thioketone Intermediates
  14. Der (2-Phenyl-2-trimethylsilyl)ethyl-(PTMSE)-Ester – eine neutral spaltbare Carboxyschutzgruppe/The (2-Phenyl-2-trimethylsiylyl)ethyl (PTMSE) Ester – a Carboxy Protecting Group Cleavable under Neutral Conditions
  15. Synthesis and Structure of Bis-Urea Phenazines
  16. New Derivatives of Quinoxaline – Syntheses, Complex Formation and their Application as Controlling Ligands for Zinc Catalyzed Epoxide-CO2–Copolymerization
  17. Steroids and Terpenoids from Ajuga relicta
  18. Notizen: Montmorillonite K-10 as Highly Efficient and Mild Catalyst for Deprotection of Ketone Dimethylhydrazones Using Microwaves in a Solventless System
https://doi.org/10.1515/znb-2002-0809
Keywords for this article
Carbonate; Cyanide; Raman Spectroscopy

Articles in the same Issue

  1. Wechselwirkungen in Molekülkristallen, 180 [1, 2]. σ-Donator/Akzeptor-Komplexe {S(CI)4···X⊖ }(X⊖ = I⊖ , SCN⊖ ) von Tetraiodthiophen in Tetra(n-butyl)ammoniumhalogenid-Salzen/Interaction in Molecular Crystals, 180 [1, 2]. -Donor/Acceptor Complexes {S(CI)4···X⊖} (X⊖= I⊖, SCN⊖ of Tetraiodothiophene in Tetra(n-butyl)ammonium Halide Salts
  2. Wechselwirkungen in Molekülkristallen, 181 [1, 2]. σ-Donator/Akzeptor-Komplexe {MAI4···X⊖ } (X⊖ = Br⊖ , I⊖ , SCN⊖ ) der Tetraiod-Akzeptormoleküle MAI4 (MA = Ethen, Thiophen, N-Methylpyrrol) in Tetraphenylphosphoniumhalogenid-Salzen Interaction in Molecular Crystals, 181 [1, 2]. σ-Donor/Acceptor Complexes {MAI4···X⊖ }(X⊖ = Br⊖, I⊖, SCN⊖ of Tetraiodo Acceptor Molecules MAI4 (MA = Ethene, Thiophene, N-Methylpyrrole) in Tetraphenylphosphonium Halide Salts
  3. Synthesis of SrxBa(1-x)TiO3 Solid Solutions from the Mechanically Activated System BaCO3 - SrCO3 - TiO2
  4. Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a Ligand
  5. Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2. V. Ytterbiumselenoxide auf dem Schnitt Yb2O3-SeO2/Thermochemical Investigations of Systems RE2O3-SeO2. V. Ytterbium Selenium Oxides on the Line Yb2O3-SeO2
  6. Implications of the Results of a Routine Structure Determination: Tris(triphenylphosphine)gold(I) Chloride Bis(dichloromethane)
  7. Structural, Spectroscopic and Theoretical Studies of (tButyl-isocyanide)gold(I) Iodide
  8. Preparation and Crystal Structure of Bis(isocyanide)gold(I) Bis(phenylene-1,2-dithiolato)aurates(III)
  9. X-Ray and Raman Investigations on Cyanides ofMono- and DivalentMetals and Synthesis, Crystal Structure and Raman Spectrum of Tl5(CO3)2(CN)
  10. A New Mixed Valent Europium Chloride: Na5Eu7Cl22
  11. Structure of N-Methylisatin N(4)-Dimethylthiosemicarbazone and its Electrochemically Synthesized 6-Coordinate Cadmium(II) Complex
  12. Crystal Structures of Seven Terephthaldiamide Derivatives
  13. [4 + 2]-Cycloaddition Reactions Involving α-Oxo Thioketone Intermediates
  14. Der (2-Phenyl-2-trimethylsilyl)ethyl-(PTMSE)-Ester – eine neutral spaltbare Carboxyschutzgruppe/The (2-Phenyl-2-trimethylsiylyl)ethyl (PTMSE) Ester – a Carboxy Protecting Group Cleavable under Neutral Conditions
  15. Synthesis and Structure of Bis-Urea Phenazines
  16. New Derivatives of Quinoxaline – Syntheses, Complex Formation and their Application as Controlling Ligands for Zinc Catalyzed Epoxide-CO2–Copolymerization
  17. Steroids and Terpenoids from Ajuga relicta
  18. Notizen: Montmorillonite K-10 as Highly Efficient and Mild Catalyst for Deprotection of Ketone Dimethylhydrazones Using Microwaves in a Solventless System
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