Article
Licensed
Unlicensed
Requires Authentication
Multinuclear (1H, 13C and 15N) Magnetic Resonance Spectroscopy and Substituent Effects on N-Phenoxyethylanilines
-
Jorge L. Jios
,
Gustavo P. Romanelli
Published/Copyright:
June 2, 2014
1H, 13C and 15N NMR spectra of twenty substituted N-phenoxyethylanilines 1-20 were completely and unambiguously assigned using a combination of both homo- and heteronuclear (gs-COSY), 1H detected heteronuclear one-bond (gs-HMQC) and long-range (gs- HMBC) gradient-selected correlation experiments. Correlations between chemical shifts and substituent constants are analyzed separately for both phenyl rings using variable substituents para to the fixed substituent -OCH2CH2NHC6H5 (series I) and -NHCH2CH2OC6H5 (series II), respectively. The correlation coefficient for chemical shifts vs. a linear combination of inductive and resonance substituent constants is high and improves when only the six values, corresponding to each para-monosubstituted series, were used. For nitrogen chemical shifts excellent linear dependences were obtained. The results show that the ethylene chain is not able to transmit the substituent effect from one aromatic ring to the other.
Received: 2001-9-6
Published Online: 2014-6-2
Published in Print: 2002-2-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Crystal Structures and Properties of Eu2GeSe4 and Eu2Ge2Se5
- Gallium-Gallium Single Bonds Terminally Coordinated by Tropolonato Ligands
- Synthesis and Structures of Bis(pentafluorophenyl) Selenoxide / Telluroxide
- Experimental and Theoretical Study on the Structure of Nitramide H2NNO2
- Crystal and Molecular Structure of 1,2,4-Triazolium Chloride and its Salt with Antimony Trichloride - Bis(1,2,4-triazolium) pentachloroantimonate(III)-1,2,4-triazolium Chloride
- Quaternary Phosphide Oxides Pr3Cu4P4O2–x and Sm3Cu4P4O2–x with Ordered Zr3Cu4Si6-Type Structure
- S-, X-, Q- undW-Band-Pulver-EPR-Untersuchungen am mononuklearen AuII-Komplex [AuII([9]anS3)2](BF4)2 / S-, X-, Q- und W-Band Powder-EPR Investigations on the Mononuclear AuII-Complex [AuII([9]aneS3 )2](BF4)2
- Supersilyliertes Ammoniak und supersilyliertes Hydrazin: Synthese, Struktur und Eigenschaften / Supersilyl Ammonia and Supersilyl Hydrazine: Synthesis, Structure and Properties
- Synthesis and Structure of trans-Dichloro-tetra(pyrazole)-gallium(III) Chloride and Tetrachlorogallate(III)
- Synthesis and Characterization of Mn6(PO4)4·H2O, a New Metal(II) Phosphate Hydrate
- Carbon Supported Pt+Os Catalysts for Methanol Oxidation
- The Molecular Structures of the Three Disilylbenzenes Determined in the Gas Phase, the Solid State and by ab initio Calculations
- Anodische Oxidation von 2-Thiobarbitursäuren unter Bildung neuartiger, tetracyclischer Dimerer / Anodic Oxidation of 2-Thiobarbituric Acids under Formation of New Tetracyclic Dimers
- Multinuclear (1H, 13C and 15N) Magnetic Resonance Spectroscopy and Substituent Effects on N-Phenoxyethylanilines
- Two New Triterpenes from Fern Adiantum incisum
- Pollen Growth Regulator, Fusanolide A, and a Related Metabolite from Fusarium sp.
- Synthesis of C-Glycosides from S-Glycosyl Phosphorothioates
- Liegen in Imidazolium-Tetrafluoroboraten Wasserstoffbrückenbindungen vor? Die Struktur von 1,3-Diisopropyl-4,5-dimethylimidazolium- Tetrafluoroborat [1] / Is Hydrogen Bonding Present in Imidazolium Tetrafluoroborates? The Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium Tetrafluoroborate [1]
- Magnesium Anthranilate Dihydrate
- Tri(1-cyclohepta-2,4,6-trienyl)- phosphane, P(C7H7)3, as a Tripodal Tetradentate Ligand in Cationic, Five-coordinate Complexes of Platinum(II) and Palladium(II)
Articles in the same Issue
- Crystal Structures and Properties of Eu2GeSe4 and Eu2Ge2Se5
- Gallium-Gallium Single Bonds Terminally Coordinated by Tropolonato Ligands
- Synthesis and Structures of Bis(pentafluorophenyl) Selenoxide / Telluroxide
- Experimental and Theoretical Study on the Structure of Nitramide H2NNO2
- Crystal and Molecular Structure of 1,2,4-Triazolium Chloride and its Salt with Antimony Trichloride - Bis(1,2,4-triazolium) pentachloroantimonate(III)-1,2,4-triazolium Chloride
- Quaternary Phosphide Oxides Pr3Cu4P4O2–x and Sm3Cu4P4O2–x with Ordered Zr3Cu4Si6-Type Structure
- S-, X-, Q- undW-Band-Pulver-EPR-Untersuchungen am mononuklearen AuII-Komplex [AuII([9]anS3)2](BF4)2 / S-, X-, Q- und W-Band Powder-EPR Investigations on the Mononuclear AuII-Complex [AuII([9]aneS3 )2](BF4)2
- Supersilyliertes Ammoniak und supersilyliertes Hydrazin: Synthese, Struktur und Eigenschaften / Supersilyl Ammonia and Supersilyl Hydrazine: Synthesis, Structure and Properties
- Synthesis and Structure of trans-Dichloro-tetra(pyrazole)-gallium(III) Chloride and Tetrachlorogallate(III)
- Synthesis and Characterization of Mn6(PO4)4·H2O, a New Metal(II) Phosphate Hydrate
- Carbon Supported Pt+Os Catalysts for Methanol Oxidation
- The Molecular Structures of the Three Disilylbenzenes Determined in the Gas Phase, the Solid State and by ab initio Calculations
- Anodische Oxidation von 2-Thiobarbitursäuren unter Bildung neuartiger, tetracyclischer Dimerer / Anodic Oxidation of 2-Thiobarbituric Acids under Formation of New Tetracyclic Dimers
- Multinuclear (1H, 13C and 15N) Magnetic Resonance Spectroscopy and Substituent Effects on N-Phenoxyethylanilines
- Two New Triterpenes from Fern Adiantum incisum
- Pollen Growth Regulator, Fusanolide A, and a Related Metabolite from Fusarium sp.
- Synthesis of C-Glycosides from S-Glycosyl Phosphorothioates
- Liegen in Imidazolium-Tetrafluoroboraten Wasserstoffbrückenbindungen vor? Die Struktur von 1,3-Diisopropyl-4,5-dimethylimidazolium- Tetrafluoroborat [1] / Is Hydrogen Bonding Present in Imidazolium Tetrafluoroborates? The Structure of 1,3-Diisopropyl-4,5-dimethylimidazolium Tetrafluoroborate [1]
- Magnesium Anthranilate Dihydrate
- Tri(1-cyclohepta-2,4,6-trienyl)- phosphane, P(C7H7)3, as a Tripodal Tetradentate Ligand in Cationic, Five-coordinate Complexes of Platinum(II) and Palladium(II)
