Abstract
Relationships between bond lengths and bond numbers and also between atomic volumes and valencies are derived and parameters for their calculation are given for the s-block, p-block, and d-block metals. From the atomic volumes under pressure, the valencies of three solid lanthanoids have been confirmed or redetermined: La 3; Ce 2. 3. and 4; Yb 2 and 3.
Received: 2000-12-15
Published Online: 2014-6-2
Published in Print: 2001-5-1
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Artikel in diesem Heft
- Chemischer Transport intermetallischer Phasen IV: Das System Fe - Ge/Chemical Vapour Transport of Intermetallic Phases IV: The System Fe - Ge
- A Simple High-Yield Synthesis of Gallium(I) Tetrachlorogallate(III) and the Reaction of Digallium Tetrachloride Tetrahydrofuran Solvate with 1,2-Diols
- Ethylboration of Stannyl-Substituted Sulfur Diimides
- A Novel Access to Tertiary and Secondary ortho-Aminophenylphosphines by Protected Group Synthesis and Palladium Catalyzed P-C Coupling Reactions
- X-Ray Structure of 6(E)-[2(Z)-(Hydroxyimino)-2-phenylethyIidene]- 7,7,8,8,9,9-hexamethyl-3-phenyl-1,2-oxazaspiro[4.4]non-2-ene
- Synthesis and Characterization of the Manganese Pyroarsenate Mn2As2O7 · 2H2O
- Atomvolumen, Atomabstände und chemische Bindung in festen metallischen Elementen/Atomic Volume, Atomic Distances and Chemical Bonding in Solid Metallic Elements
- Structural Study of an N(4)-Substituted Thiosemicarbazone Prepared from 1-Phenyl-1,2-propanedione-2-oxime, and of a Related Nickel(II) Complex
- Crystal Structure and Conformation of 2-{(2′-Aminobenzyl)iminoethyl}- 5-methoxyphenol
- Synthesis of Novel Tetracarboxylato Dirhenium(III) Compounds and Crystal Structure of [Re2(1-Adamantylcarboxylate)4Cl2] · 4 CHCl3
- The Chemical Evolution of a Nitrogenase Model, XXIII. The Nature of the Active Site and the Role of Homocitric Acid in MoFe-Nitrogenase
- New Dinuclear Transition Metal Complexes with the [M2(μ-dhbq)]n+ Core and 2-(2′-Pyridyl)quinoxaline (L) as a Terminal Ligand: Preparation and Characterization (dhbq2-= the Dianion of 2,5-Dihydroxy -1,4- benzoquinone; M = AgI, MnII, CoII, NiII, CuII, RuII, PdII, FeIII, RhIII; n = 0, 2, 4)
- Metallkomplexe mit biologisch wichtigen Liganden, CXXXVII [1]. Halbsandwich-Komplexe mit N, O-Chelaten und Schiff-Basen von β-Aminosäuren/ Metal Complexes of Biologically Important Ligands, CXXXVII [1]. Halfsandwich Complexes with N, O-Chelates and Schiff Bases of β-Amino Acids
- Synthesis of α-Tocopheryl Glycosides
- Synthesis of 3,4-Dihydro-2H-pyrans by Hetero-Diels-Alder Reactions of Functionalized α,β-Unsaturated Carbonyl Compounds with Styrenes
- Alkalimetall-Oxosilicate A6[Si3O9] und A6[Si2O7] (A = Rb, Cs): Darstellung und Kristallstruktur/ The Alkaline Metal Oxo-Silicates A6[Si3O9] and A6[Si2O7] (A = Rb, Cs): Preparation and Crystal Structure
- Notizen: Optical Outer-Sphere Charge Transfer and Photoreactivity of the Ion Pair Tetrabutylammonium Tetrabutylborate
- Notizen: Rb8AlO4Au3 ≡ Rb5AlO4 · 3RbAu – ein Aluminat-Aurid/ Rb8AlO4Au3 ≡ Rb5AlO4 · 3RbAu – an Aluminate Auride
- Notizen: Efficient Medium-Scale Synthesis of 2-Bromo-5-tert-butylbenzene-1,3-dicarbaldehyde
- Notizen: Cocrystallisation of Trimethylchlorostannane with a Distannoxane
- Notizen: Crystal Structure of a Lithium Chloride Cubane Cluster Solvated by Diethyl Ether
- Notizen: Synthesis and Structure of YbPdSn2
- Notizen: Deoxycyclopaldic Acid and Cyclopaldic Acid, Plant Growth Regulators, Produced by Penicillium sp.
Artikel in diesem Heft
- Chemischer Transport intermetallischer Phasen IV: Das System Fe - Ge/Chemical Vapour Transport of Intermetallic Phases IV: The System Fe - Ge
- A Simple High-Yield Synthesis of Gallium(I) Tetrachlorogallate(III) and the Reaction of Digallium Tetrachloride Tetrahydrofuran Solvate with 1,2-Diols
- Ethylboration of Stannyl-Substituted Sulfur Diimides
- A Novel Access to Tertiary and Secondary ortho-Aminophenylphosphines by Protected Group Synthesis and Palladium Catalyzed P-C Coupling Reactions
- X-Ray Structure of 6(E)-[2(Z)-(Hydroxyimino)-2-phenylethyIidene]- 7,7,8,8,9,9-hexamethyl-3-phenyl-1,2-oxazaspiro[4.4]non-2-ene
- Synthesis and Characterization of the Manganese Pyroarsenate Mn2As2O7 · 2H2O
- Atomvolumen, Atomabstände und chemische Bindung in festen metallischen Elementen/Atomic Volume, Atomic Distances and Chemical Bonding in Solid Metallic Elements
- Structural Study of an N(4)-Substituted Thiosemicarbazone Prepared from 1-Phenyl-1,2-propanedione-2-oxime, and of a Related Nickel(II) Complex
- Crystal Structure and Conformation of 2-{(2′-Aminobenzyl)iminoethyl}- 5-methoxyphenol
- Synthesis of Novel Tetracarboxylato Dirhenium(III) Compounds and Crystal Structure of [Re2(1-Adamantylcarboxylate)4Cl2] · 4 CHCl3
- The Chemical Evolution of a Nitrogenase Model, XXIII. The Nature of the Active Site and the Role of Homocitric Acid in MoFe-Nitrogenase
- New Dinuclear Transition Metal Complexes with the [M2(μ-dhbq)]n+ Core and 2-(2′-Pyridyl)quinoxaline (L) as a Terminal Ligand: Preparation and Characterization (dhbq2-= the Dianion of 2,5-Dihydroxy -1,4- benzoquinone; M = AgI, MnII, CoII, NiII, CuII, RuII, PdII, FeIII, RhIII; n = 0, 2, 4)
- Metallkomplexe mit biologisch wichtigen Liganden, CXXXVII [1]. Halbsandwich-Komplexe mit N, O-Chelaten und Schiff-Basen von β-Aminosäuren/ Metal Complexes of Biologically Important Ligands, CXXXVII [1]. Halfsandwich Complexes with N, O-Chelates and Schiff Bases of β-Amino Acids
- Synthesis of α-Tocopheryl Glycosides
- Synthesis of 3,4-Dihydro-2H-pyrans by Hetero-Diels-Alder Reactions of Functionalized α,β-Unsaturated Carbonyl Compounds with Styrenes
- Alkalimetall-Oxosilicate A6[Si3O9] und A6[Si2O7] (A = Rb, Cs): Darstellung und Kristallstruktur/ The Alkaline Metal Oxo-Silicates A6[Si3O9] and A6[Si2O7] (A = Rb, Cs): Preparation and Crystal Structure
- Notizen: Optical Outer-Sphere Charge Transfer and Photoreactivity of the Ion Pair Tetrabutylammonium Tetrabutylborate
- Notizen: Rb8AlO4Au3 ≡ Rb5AlO4 · 3RbAu – ein Aluminat-Aurid/ Rb8AlO4Au3 ≡ Rb5AlO4 · 3RbAu – an Aluminate Auride
- Notizen: Efficient Medium-Scale Synthesis of 2-Bromo-5-tert-butylbenzene-1,3-dicarbaldehyde
- Notizen: Cocrystallisation of Trimethylchlorostannane with a Distannoxane
- Notizen: Crystal Structure of a Lithium Chloride Cubane Cluster Solvated by Diethyl Ether
- Notizen: Synthesis and Structure of YbPdSn2
- Notizen: Deoxycyclopaldic Acid and Cyclopaldic Acid, Plant Growth Regulators, Produced by Penicillium sp.