Startseite Atomvolumen, Atomabstände und chemische Bindung in festen metallischen Elementen/Atomic Volume, Atomic Distances and Chemical Bonding in Solid Metallic Elements
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Atomvolumen, Atomabstände und chemische Bindung in festen metallischen Elementen/Atomic Volume, Atomic Distances and Chemical Bonding in Solid Metallic Elements

  • Martin Trömel EMAIL logo und Sven Hübner
Veröffentlicht/Copyright: 2. Juni 2014
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Abstract

Relationships between bond lengths and bond numbers and also between atomic volumes and valencies are derived and parameters for their calculation are given for the s-block, p-block, and d-block metals. From the atomic volumes under pressure, the valencies of three solid lanthanoids have been confirmed or redetermined: La 3; Ce 2. 3. and 4; Yb 2 and 3.

Received: 2000-12-15
Published Online: 2014-6-2
Published in Print: 2001-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Chemischer Transport intermetallischer Phasen IV: Das System Fe - Ge/Chemical Vapour Transport of Intermetallic Phases IV: The System Fe - Ge
  2. A Simple High-Yield Synthesis of Gallium(I) Tetrachlorogallate(III) and the Reaction of Digallium Tetrachloride Tetrahydrofuran Solvate with 1,2-Diols
  3. Ethylboration of Stannyl-Substituted Sulfur Diimides
  4. A Novel Access to Tertiary and Secondary ortho-Aminophenylphosphines by Protected Group Synthesis and Palladium Catalyzed P-C Coupling Reactions
  5. X-Ray Structure of 6(E)-[2(Z)-(Hydroxyimino)-2-phenylethyIidene]- 7,7,8,8,9,9-hexamethyl-3-phenyl-1,2-oxazaspiro[4.4]non-2-ene
  6. Synthesis and Characterization of the Manganese Pyroarsenate Mn2As2O7 · 2H2O
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  8. Structural Study of an N(4)-Substituted Thiosemicarbazone Prepared from 1-Phenyl-1,2-propanedione-2-oxime, and of a Related Nickel(II) Complex
  9. Crystal Structure and Conformation of 2-{(2′-Aminobenzyl)iminoethyl}- 5-methoxyphenol
  10. Synthesis of Novel Tetracarboxylato Dirhenium(III) Compounds and Crystal Structure of [Re2(1-Adamantylcarboxylate)4Cl2] · 4 CHCl3
  11. The Chemical Evolution of a Nitrogenase Model, XXIII. The Nature of the Active Site and the Role of Homocitric Acid in MoFe-Nitrogenase
  12. New Dinuclear Transition Metal Complexes with the [M2(μ-dhbq)]n+ Core and 2-(2′-Pyridyl)quinoxaline (L) as a Terminal Ligand: Preparation and Characterization (dhbq2-= the Dianion of 2,5-Dihydroxy -1,4- benzoquinone; M = AgI, MnII, CoII, NiII, CuII, RuII, PdII, FeIII, RhIII; n = 0, 2, 4)
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