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Thermal Catalytic Hydrosilylation of Conjugated Dienes with Triethylsilane in the Presence of Tricarbonyl(o-xylene)Metal (Metal = Cr, Mo, W) Complexes

  • Ceyhan Kayran EMAIL logo and Pazilaiti Rouzi
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 56 Issue 11

The thermal catalytic hydrosilylation of 1,3-butadiene (1), trans-2-methyl-1,3-pentadiene (2), 2,3-dimethyl-1,3-butadiene (3), and isoprene (4), with triethylsilane were studied in the presence of M(CO)3 (o-xylene) (M = Cr, Mo, W) complexes in polar and nonpolar solvents such as tetrahydrofuran, hexane and toluene. Mo(CO)3 (o-xylene) was found to be the only active catalyst for the hydrosilylation of 3 with triethylsilane, which gave 1-triethylsilyl-2,3-dimethyl- 2-butene (3a). as hydrosilylated product in tetrahydrofuran. The product was identified by means of 1H and 13C-NMR and GLC. The same catalyst, Mo(CO)3 (o-xylene), decomposed to Mo(CO)6 without giving hydrosilylated products of 1, 2 and 4 in tetrahydrofuran. M(CO)3(o-xylene) (M = Cr, Mo, W) complexes were found to be stable for about 6 h in hexane and toluene, and showed no catalytic activity for the hydrosilylation of 1, 2, 3 and 4.

Keywords: Hydrosilylation; Tungsten; Carbonyl
Received: 2001-7-2
Published Online: 2014-6-2
Published in Print: 2001-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Structure Determination for the Crystalline Phase of Triphenyl Phosphite by Means of Multi-Dimensional Solid-State NMR and X-Ray Diffraction
  2. Amido-tert-butylimido-vanadium(V)-Verbindungen. Darstellung, Reaktionen und 51V-NMR-spektroskopische Untersuchungen / Amido-tert-butylimidovanadium(V) Compounds. Synthesis, Reactions and 51V NMR Spectroscopic Studies
  3. peri-Interactions in Naphthalenes, 5 [1]. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations
  4. [Co(NH3)6]C1C03 - ein Hexaammincobalt(III)-Komplex mit einer ‘idealen’ Carbonat-Gruppe / [Co(NH3)6]C1C03 - a Hexaamminecobalt(III) Complex with an ‘Ideal’ Carbonate Group
  5. Crystal Structure and Magnetic Properties of an Oxygen-Bridged Trinuclear Copper(II) Complex
  6. Importance of Orbital Complementarity in Spin Coupling through Two Different Bridging Groups. Synthesis, Crystal Structure, Magnetic Properties and Magneto-Structural Correlations in a Dicopper(II) Complex of Endogenous Alkoxo Bridging Ligand with Exogenous Pyrazolate
  7. Thermal Catalytic Hydrosilylation of Conjugated Dienes with Triethylsilane in the Presence of Tricarbonyl(o-xylene)Metal (Metal = Cr, Mo, W) Complexes
  8. Preparation, Properties, and Crystal Structure of Quaternary Silicide Carbides RCr2Si2C (R = Y, La - Nd, Sm, Gd - Ho)
  9. CsCu3Dy2S5 und CsCu3Er2S5 : Zwei isotype quaternäre Sulfide der Lanthanoide mit Kanalstrukturen / CsCu3Dy2S5 and CsCu3Er2S5: Two Isotypic Quaternary Sulfides of the Lanthanides with Channel Structures
  10. Donor-Acceptor Complexes between Simple Phosphines. First Structural Data for an Almost Forgotten Class of Compounds
  11. Donor-Acceptor Complexes between Organoamines and Phosphorus Tribromide
  12. Orthoamides, LVI [1]. A New Method of Wide Scope for the Preparation of Aryl Formates
  13. Orthoamide, LVII [1]. Lassen sich aromatische Aldehyde nach Fries aus Arylformiaten hersteilen? / Orthoamides, LVII [1]. Can Aromatic Aldehydes be Prepared from Aryl Formates via the Fries Rearrangement?
  14. Polysulfonylamine, CXLVII [1]. Die ersten N,N-disulfonylierten Thioharnstoffe: Synthese von (RSO2)2N-C(S)-NMe2 (R = Me, 4-Me-C6H4) und Kristallstruktur der Ditosylverbindung / Polysulfonylamines, CXLVII [1]. The First N,N-Disulfonylated Thioureas: Synthesis of (RSO2)2N-C(S)-NMe2 (R = Me, 4-Me-C6H4) and Crystal Structure of the Ditosyl Compound
  15. Einige Umsetzungen von Inhydrazinen mit Isocyanaten: [2+2]- und [4+2]Cycloadditionen, (Hydrazinoethinyl)metallierung / Some Reactions of Ynehydrazines with Isocyanates: [2+2]- and [4+2]Cycloadditions, (Hydrazinoethynyl)metallation
  16. Structural Influence of Hydrogen Bonding and π-Stacking in trans-Diazido-tetrakis( pyrazole)nickel(II) and trans-Diazido-tetrakis(3-methylpyrazoIe)nickel(II)
  17. 7-Azoniafluorenonderivate durch elektrostatisch aktivierte SNAr-Reaktionen / 7-Azoniafluorenone Derivatives by Electrostatically Activated SNAr-Reactions
  18. Palladium(II) and Platinum(II) Complexes of N-3-Pyridinylmethanesulfonamide
  19. Facile Approach to Versatile Chiral Intermediates for Fused Cyclopentanoid Natural Products
  20. Nukleophile Aromatische Substitution an 2-Fluoroimidazolium-Ionen: Synthese und Kristallstruktur eines dikationischen 2,2-Biimidazolyl- Derivates [1] / Nucleophilic Aromatic Substitution at 2-Fluoroimidazolium Ions: Synthesis and Crystal Structure of a Dicationic 2,2′-Biimidazolyl Derivative [1]
  21. Interpenetrierende Clusterstränge in der Kristallstruktur von K0,77Nb6Cl15 / Interpenetrating Cluster Chains in the Structure of K0.77Nb6Cl15
  22. Synthesis and Structure of RE2Rh2Cd (RE = La, Ce, Pr, Nd, Sm)
https://doi.org/10.1515/znb-2001-1107
Keywords for this article
Hydrosilylation; Tungsten; Carbonyl

Articles in the same Issue

  1. Structure Determination for the Crystalline Phase of Triphenyl Phosphite by Means of Multi-Dimensional Solid-State NMR and X-Ray Diffraction
  2. Amido-tert-butylimido-vanadium(V)-Verbindungen. Darstellung, Reaktionen und 51V-NMR-spektroskopische Untersuchungen / Amido-tert-butylimidovanadium(V) Compounds. Synthesis, Reactions and 51V NMR Spectroscopic Studies
  3. peri-Interactions in Naphthalenes, 5 [1]. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations
  4. [Co(NH3)6]C1C03 - ein Hexaammincobalt(III)-Komplex mit einer ‘idealen’ Carbonat-Gruppe / [Co(NH3)6]C1C03 - a Hexaamminecobalt(III) Complex with an ‘Ideal’ Carbonate Group
  5. Crystal Structure and Magnetic Properties of an Oxygen-Bridged Trinuclear Copper(II) Complex
  6. Importance of Orbital Complementarity in Spin Coupling through Two Different Bridging Groups. Synthesis, Crystal Structure, Magnetic Properties and Magneto-Structural Correlations in a Dicopper(II) Complex of Endogenous Alkoxo Bridging Ligand with Exogenous Pyrazolate
  7. Thermal Catalytic Hydrosilylation of Conjugated Dienes with Triethylsilane in the Presence of Tricarbonyl(o-xylene)Metal (Metal = Cr, Mo, W) Complexes
  8. Preparation, Properties, and Crystal Structure of Quaternary Silicide Carbides RCr2Si2C (R = Y, La - Nd, Sm, Gd - Ho)
  9. CsCu3Dy2S5 und CsCu3Er2S5 : Zwei isotype quaternäre Sulfide der Lanthanoide mit Kanalstrukturen / CsCu3Dy2S5 and CsCu3Er2S5: Two Isotypic Quaternary Sulfides of the Lanthanides with Channel Structures
  10. Donor-Acceptor Complexes between Simple Phosphines. First Structural Data for an Almost Forgotten Class of Compounds
  11. Donor-Acceptor Complexes between Organoamines and Phosphorus Tribromide
  12. Orthoamides, LVI [1]. A New Method of Wide Scope for the Preparation of Aryl Formates
  13. Orthoamide, LVII [1]. Lassen sich aromatische Aldehyde nach Fries aus Arylformiaten hersteilen? / Orthoamides, LVII [1]. Can Aromatic Aldehydes be Prepared from Aryl Formates via the Fries Rearrangement?
  14. Polysulfonylamine, CXLVII [1]. Die ersten N,N-disulfonylierten Thioharnstoffe: Synthese von (RSO2)2N-C(S)-NMe2 (R = Me, 4-Me-C6H4) und Kristallstruktur der Ditosylverbindung / Polysulfonylamines, CXLVII [1]. The First N,N-Disulfonylated Thioureas: Synthesis of (RSO2)2N-C(S)-NMe2 (R = Me, 4-Me-C6H4) and Crystal Structure of the Ditosyl Compound
  15. Einige Umsetzungen von Inhydrazinen mit Isocyanaten: [2+2]- und [4+2]Cycloadditionen, (Hydrazinoethinyl)metallierung / Some Reactions of Ynehydrazines with Isocyanates: [2+2]- and [4+2]Cycloadditions, (Hydrazinoethynyl)metallation
  16. Structural Influence of Hydrogen Bonding and π-Stacking in trans-Diazido-tetrakis( pyrazole)nickel(II) and trans-Diazido-tetrakis(3-methylpyrazoIe)nickel(II)
  17. 7-Azoniafluorenonderivate durch elektrostatisch aktivierte SNAr-Reaktionen / 7-Azoniafluorenone Derivatives by Electrostatically Activated SNAr-Reactions
  18. Palladium(II) and Platinum(II) Complexes of N-3-Pyridinylmethanesulfonamide
  19. Facile Approach to Versatile Chiral Intermediates for Fused Cyclopentanoid Natural Products
  20. Nukleophile Aromatische Substitution an 2-Fluoroimidazolium-Ionen: Synthese und Kristallstruktur eines dikationischen 2,2-Biimidazolyl- Derivates [1] / Nucleophilic Aromatic Substitution at 2-Fluoroimidazolium Ions: Synthesis and Crystal Structure of a Dicationic 2,2′-Biimidazolyl Derivative [1]
  21. Interpenetrierende Clusterstränge in der Kristallstruktur von K0,77Nb6Cl15 / Interpenetrating Cluster Chains in the Structure of K0.77Nb6Cl15
  22. Synthesis and Structure of RE2Rh2Cd (RE = La, Ce, Pr, Nd, Sm)
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