Article
Licensed
Unlicensed
Requires Authentication
Secondary Bonding Interactions in Some Halopyridinium and Dihalopyridinium Halides
-
Matthias Frey
Published/Copyright:
June 2, 2014
Abstract
The packing motifs of 2-and 3-chloropyridinium chloride can be interpreted in terms of classical hydrogen bonds N+-H···Cl- and non-classical C-H···Cl-" interactions, with halo-gen-halogen contacts playing a subordinate role. In the corresponding bromine derivatives, Br···Br interactions are much more important. Of the dihalo derivatives, 3,5-dichloropyridinium chloride crystallises with classical linear hydrogen bonds of the form N+-H···Cl- , but its chlorine-chlorine interactions are at best weak; the corresponding bromine derivative displays aggregates of bromine atoms and three-centre hydrogen bonds N+-H (···Br-)2 .
Received: 2001-5-15
Published Online: 2014-6-2
Published in Print: 2001-9-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Methylated Ammonium and Hydrazinium Salts of 5,5′-Azotetrazolate
- New Hydrazinium Salts of 5,5'-Azotetrazolate
- A Curious Case of Partial Spontaneous Resolution on Crystallization of a Racemate. The Crystal and Molecular Structures of N-Acetyl-DL-alanine Methylester and iV-Acetyl-L-alanine Methylester
- Group 12 Metal Complexes of 2-Formylpyrrole-(4PL1) and 2-Acetylpyrrole-N(4)-phenylthiosemicarbazone (4Pl2), as Examples form Different Donor Modes. Crystal and Molecular Structures of [Hg(4PL1- H)Br]2 and [Zn(4PL2)2Br2] · 2 EtOH
- Secondary Bonding Interactions in Some Halopyridinium and Dihalopyridinium Halides
- Magnetic Properties and Crystal Structure of a Dinuclear Iron(III) Complex
- Synthesis and Coordination Chemistry of Novel Binucleating Macrocyclic Ligands with Amine-thioether and Amine-thiophenolate Donor Functions
- Thermisches und kalorisches Verhalten von festem LaAl3Br12 und chemischer Transport von LaBr3 mit AlBr3 / Thermical and Calorical Behaviour of Solid LaAl3Br12 and Chemical Transport of LaBr3 with AlBr3
- Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2. II. Samariumselenoxide auf dem Schnitt Sm2O3-SeO2 / Thermochemical Investigations of Systems SE2O3-SeO2. II. Samarium Selenium Oxides on the Line Sm2O3-SeO2
- Synthesis and Crystal Structure of [Bis(N-oxo-2-acetylpyridine 4N-Methylthiosemicarbazone)zinc(II)] Monohydrate
- Spectroscopic and Magnetostructural Evidence for the Formation of [Cu0.5Co0.5(H2Tea)X] Mixed-Crystal Compounds from Zerovalent Cu and Co Salts in the Presence of Triethanolamine (H3Tea -Triethanolamine; X = SCN, Cl)
- Preparation and Structure of Lithium Bis[cis-ethene-l,2-di(tbutylamido)]gallate(III) Tetrahydrofuran
- Zwei- und dreikemige Organometallkomplexe (ReS4)[MCl(C5Me5)], M = Rh, Ir, und (μ-WS4)[IrCl(C5Me5)]2 / Dinuclear and Trinuclear Organometallic Complexes (ReS4)[MCl(C5Me5)], M = Rh, Ir, and (μ-WS4)[IrCl(C5Me5)]2
- 29Si-29Si and 29Si-13C Indirect Nuclear Spin-Spin Coupling, and Isotope-Induced Chemical Shifts 1Δ 12/13C(29Si) and 1Δ 28/29Si(13C), Determined for Silenes Stabilized by Intramolecular N-Si Coordination
- Organophosphorus Compounds, Part 146* Imidovanadium(V) Complexes as Reaction Partners for Kinetically Stabilized Phosphaalkynes. Synthesis and Reactivity of 3-Aza-l,2,4,6-tetraphospha-quadricyclanes
- Pyrazino-methyl-ethylenedithio- tetrathiafulvalene, Precursor o τ-Phase Conductors
Articles in the same Issue
- Methylated Ammonium and Hydrazinium Salts of 5,5′-Azotetrazolate
- New Hydrazinium Salts of 5,5'-Azotetrazolate
- A Curious Case of Partial Spontaneous Resolution on Crystallization of a Racemate. The Crystal and Molecular Structures of N-Acetyl-DL-alanine Methylester and iV-Acetyl-L-alanine Methylester
- Group 12 Metal Complexes of 2-Formylpyrrole-(4PL1) and 2-Acetylpyrrole-N(4)-phenylthiosemicarbazone (4Pl2), as Examples form Different Donor Modes. Crystal and Molecular Structures of [Hg(4PL1- H)Br]2 and [Zn(4PL2)2Br2] · 2 EtOH
- Secondary Bonding Interactions in Some Halopyridinium and Dihalopyridinium Halides
- Magnetic Properties and Crystal Structure of a Dinuclear Iron(III) Complex
- Synthesis and Coordination Chemistry of Novel Binucleating Macrocyclic Ligands with Amine-thioether and Amine-thiophenolate Donor Functions
- Thermisches und kalorisches Verhalten von festem LaAl3Br12 und chemischer Transport von LaBr3 mit AlBr3 / Thermical and Calorical Behaviour of Solid LaAl3Br12 and Chemical Transport of LaBr3 with AlBr3
- Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2. II. Samariumselenoxide auf dem Schnitt Sm2O3-SeO2 / Thermochemical Investigations of Systems SE2O3-SeO2. II. Samarium Selenium Oxides on the Line Sm2O3-SeO2
- Synthesis and Crystal Structure of [Bis(N-oxo-2-acetylpyridine 4N-Methylthiosemicarbazone)zinc(II)] Monohydrate
- Spectroscopic and Magnetostructural Evidence for the Formation of [Cu0.5Co0.5(H2Tea)X] Mixed-Crystal Compounds from Zerovalent Cu and Co Salts in the Presence of Triethanolamine (H3Tea -Triethanolamine; X = SCN, Cl)
- Preparation and Structure of Lithium Bis[cis-ethene-l,2-di(tbutylamido)]gallate(III) Tetrahydrofuran
- Zwei- und dreikemige Organometallkomplexe (ReS4)[MCl(C5Me5)], M = Rh, Ir, und (μ-WS4)[IrCl(C5Me5)]2 / Dinuclear and Trinuclear Organometallic Complexes (ReS4)[MCl(C5Me5)], M = Rh, Ir, and (μ-WS4)[IrCl(C5Me5)]2
- 29Si-29Si and 29Si-13C Indirect Nuclear Spin-Spin Coupling, and Isotope-Induced Chemical Shifts 1Δ 12/13C(29Si) and 1Δ 28/29Si(13C), Determined for Silenes Stabilized by Intramolecular N-Si Coordination
- Organophosphorus Compounds, Part 146* Imidovanadium(V) Complexes as Reaction Partners for Kinetically Stabilized Phosphaalkynes. Synthesis and Reactivity of 3-Aza-l,2,4,6-tetraphospha-quadricyclanes
- Pyrazino-methyl-ethylenedithio- tetrathiafulvalene, Precursor o τ-Phase Conductors
