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[((C6H5)3P)2N ]O3 und [(((CH3 )2 N)3 PN)4 P]O3 , neue ionische Ozonide mit Phasentransfer-geeigneten Kationen

[((C6H5 )3P)2N] O3 and [(((CH3)2N)3PN)4P]O3, New Ionic Ozonides with Cations Suitable for Phase Transfer
  • Wilhelm Klein and Martin Jansen EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 56 Issue 3

Abstract

Ionic ozonides soluble in organic solvents have been synthesized. The crystal structures of bis(triphenylphosphine)iminium-ozonide bis(dimethylamine) (1/2) (P21/c, a = 969.9(2) pm, b = 2007.1(3) pm, c = 1852.4(4) pm, Z = 4, R1 = 14.34%, 3343 independent reflections), tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium-ozonide (P21/n, a = 1120(1) pm, b = 3192(5) pm, c = 1162(1) pm, Z = 4, R1 = 9.18%, 1428 independent reflections) and tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium-ozonide dimethylamine (1/1) (Pbcn, a = 1080.9(6) pm, b = 3560(5) pm, c = 1154(2) pm, Z = 4, R1 = 12.22%, 2624 independent reflections) have been solved. While these ozonides react with ethers and nitriles, stable solutions in amines and CH2Cl2 have been obtained.

Keywords: Ionic Ozonides; Phase Transfer
Received: 2000-11-20
Published Online: 2014-6-2
Published in Print: 2001-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  1. Synthesis and Structural Characterization of Metal Complexes of 2-Formylpyrrole 4N-Methylthiosemicarbazone (4ML1) and 2-Acetyl- pyrrole 4N-Methylthiosemicarbazone (4ML2). The X-Ray Crystal Structures of [Ni(4ML1-H)2], [Pd(4ML1-H)2] and [Cd(4ML2)2I2]
  2. Structural Study of a Binuclear Zinc Complex of 2,6-Diacetylpyridine Bis{N(4)-dimethylthiosemicarbazone}, [Zn(2,6Ac4DM)]2 · MeCN
  3. Synthesis, Spectroscopic Characterization and Crystal and Molecular Structures of {Ph4P[(Se04 )(SnPh3 )(SnPh3X)]}n (X = Cl, Br)
  4. New Magnesium Compounds RE2Cu2Mg (RE = Y, La -Nd, Sm, Gd -Tm, Lu) with Mo2FeB2 Type Structure
  5. Die Kristallstrukturen von [(TMEDA)LiCl]2·Toluol und [(MeCN)2LiCl]n
  6. A New Binuclear Lutetium(III) Dimethyl-N-trichloroacetylamidophosphate Complex with a γ, γ'-Dipyridyl Bridge, {Lu[CCl3C(O)NP(O)(OCH3)2]3}2-μ(γ,γ'-dipy)
  7. Darstellung, Reaktionen und 51V-NMR-spektroskopische Untersuchungen der Imidovanadium(V)-trichloride: RN=VCl3 (R = H, SiMe3, Alkyl)
  8. Oxovanadium(IV), Nickel(II) and Palladium(II) Complexes of Tridentate Salicylaldiminates Derived from 2,4-Di-ter-butyl-6-aminophenol
  9. Untersuchungen an Polyhalogeniden, XXXXII [1]. Das Pentaiodid-Ion I5-; Eine Übersicht: Darstellung und Kristallstruktur der Verbindung [Rb(C16H24O6)](I5) · H2O
  10. Kinetics of the Substitution of Norbornadiene in Tetracarbonyl(norbomadiene)molybdenum(0) by 2,2'-Bipyridine
  11. [((C6H5)3P)2N ]O3 und [(((CH3 )2 N)3 PN)4 P]O3 , neue ionische Ozonide mit Phasentransfer-geeigneten Kationen
  12. Metallkomplexe mit biologisch wichtigen Liganden, CXXXIII [1], a-Aminocarboxylat-Chelate von cyclometallierten Rhodium-Komplexen Metal Complexes of Biologically Important Ligands, CXXXIII [1]. α-Aminocarboxylate Chelates of Cyclometalated Rhodium -Komplexes
  13. New π -Donor Molecules with a Pyrazino Group and their Conducting Salts
  14. Synthesis, Characterization, Crystal Structure and hybrid DFT Computation of the Chlorooxoarsenate(III), [NMe4]2[As4O2Cl10]·2 CH3CN
  15. Reaktionen von C(NMe2)4 mit Carbonylverbindungen der 6. Gruppe. Kristallstrukturen von [C(NMe2)3][(CO)5CrC(O)NMe2], [C(NMe2)3]2[Mo2(CO)10] und [C(NMe2)3][(CO)4Mo(O2CNMe2)] / Reactions of C(NMe2,)4 with Group 6 Carbonyl Compounds. Crystal Structures of [C(NMe2 )3 ][(CO)5 CrC(O)NMe2], [C(NMe2)3]2[Mo2(CO)10] and [C(NMe2)3][(CO)4 Mo(O2CNMe2)]
  16. Quassinoids and Other Constituents from Picrasma crenata
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  18. Total Synthesis of S-(+)-Argentilactone
https://doi.org/10.1515/znb-2001-0311
Keywords for this article
Ionic Ozonides; Phase Transfer

Articles in the same Issue

  1. Synthesis and Structural Characterization of Metal Complexes of 2-Formylpyrrole 4N-Methylthiosemicarbazone (4ML1) and 2-Acetyl- pyrrole 4N-Methylthiosemicarbazone (4ML2). The X-Ray Crystal Structures of [Ni(4ML1-H)2], [Pd(4ML1-H)2] and [Cd(4ML2)2I2]
  2. Structural Study of a Binuclear Zinc Complex of 2,6-Diacetylpyridine Bis{N(4)-dimethylthiosemicarbazone}, [Zn(2,6Ac4DM)]2 · MeCN
  3. Synthesis, Spectroscopic Characterization and Crystal and Molecular Structures of {Ph4P[(Se04 )(SnPh3 )(SnPh3X)]}n (X = Cl, Br)
  4. New Magnesium Compounds RE2Cu2Mg (RE = Y, La -Nd, Sm, Gd -Tm, Lu) with Mo2FeB2 Type Structure
  5. Die Kristallstrukturen von [(TMEDA)LiCl]2·Toluol und [(MeCN)2LiCl]n
  6. A New Binuclear Lutetium(III) Dimethyl-N-trichloroacetylamidophosphate Complex with a γ, γ'-Dipyridyl Bridge, {Lu[CCl3C(O)NP(O)(OCH3)2]3}2-μ(γ,γ'-dipy)
  7. Darstellung, Reaktionen und 51V-NMR-spektroskopische Untersuchungen der Imidovanadium(V)-trichloride: RN=VCl3 (R = H, SiMe3, Alkyl)
  8. Oxovanadium(IV), Nickel(II) and Palladium(II) Complexes of Tridentate Salicylaldiminates Derived from 2,4-Di-ter-butyl-6-aminophenol
  9. Untersuchungen an Polyhalogeniden, XXXXII [1]. Das Pentaiodid-Ion I5-; Eine Übersicht: Darstellung und Kristallstruktur der Verbindung [Rb(C16H24O6)](I5) · H2O
  10. Kinetics of the Substitution of Norbornadiene in Tetracarbonyl(norbomadiene)molybdenum(0) by 2,2'-Bipyridine
  11. [((C6H5)3P)2N ]O3 und [(((CH3 )2 N)3 PN)4 P]O3 , neue ionische Ozonide mit Phasentransfer-geeigneten Kationen
  12. Metallkomplexe mit biologisch wichtigen Liganden, CXXXIII [1], a-Aminocarboxylat-Chelate von cyclometallierten Rhodium-Komplexen Metal Complexes of Biologically Important Ligands, CXXXIII [1]. α-Aminocarboxylate Chelates of Cyclometalated Rhodium -Komplexes
  13. New π -Donor Molecules with a Pyrazino Group and their Conducting Salts
  14. Synthesis, Characterization, Crystal Structure and hybrid DFT Computation of the Chlorooxoarsenate(III), [NMe4]2[As4O2Cl10]·2 CH3CN
  15. Reaktionen von C(NMe2)4 mit Carbonylverbindungen der 6. Gruppe. Kristallstrukturen von [C(NMe2)3][(CO)5CrC(O)NMe2], [C(NMe2)3]2[Mo2(CO)10] und [C(NMe2)3][(CO)4Mo(O2CNMe2)] / Reactions of C(NMe2,)4 with Group 6 Carbonyl Compounds. Crystal Structures of [C(NMe2 )3 ][(CO)5 CrC(O)NMe2], [C(NMe2)3]2[Mo2(CO)10] and [C(NMe2)3][(CO)4 Mo(O2CNMe2)]
  16. Quassinoids and Other Constituents from Picrasma crenata
  17. Modes of Xanthine Complexation to Dirhodium Tetrakis[(R)-α-methoxy-α- (trifluoromethyl)-phenylacetate] in Solution and in the Solid State
  18. Total Synthesis of S-(+)-Argentilactone
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