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N-(Halogendimethylsilyl)-1 -methylphospholanimine/N-(Halogenodimethylsilyl)-1 -methylphospholane Imines
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W. Wolfsberger
Published/Copyright:
June 2, 2014
N-Trimethylsilyl-1 -methylphospholane imine has been prepared by the Staudinger reaction of 1-methylphospholane with trimethylsilyl azide. Transsilylation reactions of the phosphine imine with dichloro or dibromodimethylsilane lead to dimeric N-(halogenodimethylsilyl)-l-methylphospholane imines with an ionic type of structure, containing a dicationic four-membered Si-N ring system. Upon heating, the chloro compound undergoes a reversible isomerization to give the corresponding covalent monomer.
Keywords : N-Silyl-phosphine Imines; Transsilylation
Received: 2000-4-13
Published Online: 2014-6-2
Published in Print: 2000-7-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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