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Interaction between the Peroxide Adduct of Binuclear Iron(III) Complex with (HPTP) Anion and the Sugar Moiety of Nucleosides

  • Satoshi Nishino , Mami Kunita , Teruyuki Kobayashi , Hideaki Matsushima , Tadashi Tokii and Yuzo Nishida EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 10

We have in this study obtained the experimental evidence to suggest that the peroxide adduct of binuclear iron(III) complex with H(HPTP) directly reacts with the sugar moiety of the DNA chain, to cleave it; H(HPTP) denotes N,N,N′,N′-tetrakis(2-pyridylmethyl)-1,3-diamino- 2 -propanol.

Keywords : DNA Cleavage; Peroxide Adduct of Binuclear Iron(III); Interaction with Sugar moiety
Received: 1999-2-15
Published Online: 2014-6-2
Published in Print: 1999-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Synthese, Spektren und Kristallstruktur von cis-Monobenzylmononitrotetrahydro-closo-hexaborat(2-) / Synthesis, Spectra and Crystal Structure of cis-Monobenzylmononitrotetrahydro-closo-hexaborate(2-)
  2. Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von bindungsisomeren Halogenoselenocyanatorhenaten(IV) sowie Kristallstrukturen von mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] und mer-(n-Bu4N)2[ReCl3I(NCSe)2cis] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Linkage Isomeric Halogenoselenocyanatorhenates(IV) and Crystal Structures of mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] and mer-(n-Bu4N)2[ReCl3I(NCSe)2cis]
  3. Schwingungsspektren und Normalkoordinatenanalyse der Tetrahalogeno-closo-1,2-diphosphahexaborane P2B4X4, X = Cl, Br / Vibrational Spectra and Normal Coordinate Analysis of the Tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br
  4. Formation of η1-P-(2-Phosphinophenol)Ni(0)(PMe3)3 and Oxidation to cis/trans-Bis(2-phosphinophenolato)nickel(II) Complexes
  5. Bis-phosphonio-isophosphindolide Copper Complexes
  6. Octachalcogen Cations Te82+, Se82+, and Mixed (Te8-xSex)82+ Stabilized by Chlorometallates of Bi, Zr, and Hf: Synthesis and Crystal Structures of Se8[Bi4Cl14] and E8[MCl6] (E = Se, Te; M = Zr, Hf)
  7. Bis[1,3-bis(diphenylmethylsilylamido)propane]zirconium: A Spirocyclic Complex Containing a Sterically Demanding Chelating Amido Ligand
  8. Synthesis and Oxidation of Ruthenium Allyl Thioether Complexes Bearing Phosphite and Phosphonite Coligands [1]
  9. Interaction between the Peroxide Adduct of Binuclear Iron(III) Complex with (HPTP) Anion and the Sugar Moiety of Nucleosides
  10. The Intermetallic Compounds GdRe2Al10 and TbRe2Al10, Crystallizing with a Stacking Variant of the YbFe2Al10 Type Structure
  11. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumneodymbromiden / Thermal Decomposition and Solution Calorimetry of Ammonium Neodymium Bromides
  12. Novel Dinucleating Ligand Systems Containing Two Adjacent Coordination Compartments of the Potential Triamidoamine-Type - Nickel(II) and Cobalt(II) Coordination Chemistry
  13. Thioanalogs of Sparteine Lactams [6]. Part II. (+)-2-Thionosparteinium Perchlorate
  14. Crystal and Molecular Structure of the Copper(I)-thiolate-selenide Complex [Ph4P][Cu(SeS2CNC4H8)(S2CN2C4H8)] with an Unusual Se-S Bond
  15. Synthesis and Structural Characterization of [Me4N]2[W2O2(μ-S)(η2-S2)4]·MeCN, a Novel Oxo-thiotungstate(VI)
  16. X-Ray Structure Analysis of iso-Sildenafil (iso- Viagra) [1]
  17. Syntheses and Evaluation of the Analgesic Activity of Some 4-Acetyl- 4-phenylpiperidine and 4-Hydroxy-4-phenylpiperidine Derivatives
  18. An Approach to the Synthesis of New 1-Phenylacridones and Naphthacridones
  19. Notizen: Role of the Hydroxymethyl Group for the Inhibitory Activity of Penienone
https://doi.org/10.1515/znb-1999-1009
Keywords for this article
DNA Cleavage; Peroxide Adduct of Binuclear Iron(III); Interaction with Sugar moiety

Articles in the same Issue

  1. Synthese, Spektren und Kristallstruktur von cis-Monobenzylmononitrotetrahydro-closo-hexaborat(2-) / Synthesis, Spectra and Crystal Structure of cis-Monobenzylmononitrotetrahydro-closo-hexaborate(2-)
  2. Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von bindungsisomeren Halogenoselenocyanatorhenaten(IV) sowie Kristallstrukturen von mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] und mer-(n-Bu4N)2[ReCl3I(NCSe)2cis] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Linkage Isomeric Halogenoselenocyanatorhenates(IV) and Crystal Structures of mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] and mer-(n-Bu4N)2[ReCl3I(NCSe)2cis]
  3. Schwingungsspektren und Normalkoordinatenanalyse der Tetrahalogeno-closo-1,2-diphosphahexaborane P2B4X4, X = Cl, Br / Vibrational Spectra and Normal Coordinate Analysis of the Tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br
  4. Formation of η1-P-(2-Phosphinophenol)Ni(0)(PMe3)3 and Oxidation to cis/trans-Bis(2-phosphinophenolato)nickel(II) Complexes
  5. Bis-phosphonio-isophosphindolide Copper Complexes
  6. Octachalcogen Cations Te82+, Se82+, and Mixed (Te8-xSex)82+ Stabilized by Chlorometallates of Bi, Zr, and Hf: Synthesis and Crystal Structures of Se8[Bi4Cl14] and E8[MCl6] (E = Se, Te; M = Zr, Hf)
  7. Bis[1,3-bis(diphenylmethylsilylamido)propane]zirconium: A Spirocyclic Complex Containing a Sterically Demanding Chelating Amido Ligand
  8. Synthesis and Oxidation of Ruthenium Allyl Thioether Complexes Bearing Phosphite and Phosphonite Coligands [1]
  9. Interaction between the Peroxide Adduct of Binuclear Iron(III) Complex with (HPTP) Anion and the Sugar Moiety of Nucleosides
  10. The Intermetallic Compounds GdRe2Al10 and TbRe2Al10, Crystallizing with a Stacking Variant of the YbFe2Al10 Type Structure
  11. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumneodymbromiden / Thermal Decomposition and Solution Calorimetry of Ammonium Neodymium Bromides
  12. Novel Dinucleating Ligand Systems Containing Two Adjacent Coordination Compartments of the Potential Triamidoamine-Type - Nickel(II) and Cobalt(II) Coordination Chemistry
  13. Thioanalogs of Sparteine Lactams [6]. Part II. (+)-2-Thionosparteinium Perchlorate
  14. Crystal and Molecular Structure of the Copper(I)-thiolate-selenide Complex [Ph4P][Cu(SeS2CNC4H8)(S2CN2C4H8)] with an Unusual Se-S Bond
  15. Synthesis and Structural Characterization of [Me4N]2[W2O2(μ-S)(η2-S2)4]·MeCN, a Novel Oxo-thiotungstate(VI)
  16. X-Ray Structure Analysis of iso-Sildenafil (iso- Viagra) [1]
  17. Syntheses and Evaluation of the Analgesic Activity of Some 4-Acetyl- 4-phenylpiperidine and 4-Hydroxy-4-phenylpiperidine Derivatives
  18. An Approach to the Synthesis of New 1-Phenylacridones and Naphthacridones
  19. Notizen: Role of the Hydroxymethyl Group for the Inhibitory Activity of Penienone
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