Startseite Schwingungsspektren und Normalkoordinatenanalyse der Tetrahalogeno-closo-1,2-diphosphahexaborane P2B4X4, X = Cl, Br / Vibrational Spectra and Normal Coordinate Analysis of the Tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Schwingungsspektren und Normalkoordinatenanalyse der Tetrahalogeno-closo-1,2-diphosphahexaborane P2B4X4, X = Cl, Br / Vibrational Spectra and Normal Coordinate Analysis of the Tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br

  • V. Lorenzen , W. Preetz , W. Keller und W. Haubold
Veröffentlicht/Copyright: 2. Juni 2014
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen Erkunden Sie dieses Fachgebiet
Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 54 Heft 10

High resolution vibrational spectra of the tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br have been measured at low temperatures (20 - 60 K). The boron-halogen stretching vibrations are observed below 370 cm-1 while the P-P valence vibrations are found at 414 (Cl) and 372 cm-1 (Br). Due to the presence of the boron isotopes 10B and 11B the P-P stretching vibrations and the cage modes in the region of 550 to 1200 cm-1 are split. Based on the crystallographic data of P2B4C14 normal coordinate analyses have been performed. Using a set of 16 force constants (e.g. fd(PP) = 1.35 (X = Cl) and 1.20 (Br), fd(BB) = 1.30 / 1.65 (Cl) and 1.45 /1.60 (Br), fd(BX) = 4.40 (Cl) and 3.53 (Br) mdyn / Å) a good agreement of observed and calculated frequencies has been achieved.

Keywords : Tetrahalogeno-closo-1,2-diphosphahexaboranes; Vibrational Spectra; Normal Coordinate Analyses; Force Constants
Received: 1999-8-10
Published Online: 2014-6-2
Published in Print: 1999-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Synthese, Spektren und Kristallstruktur von cis-Monobenzylmononitrotetrahydro-closo-hexaborat(2-) / Synthesis, Spectra and Crystal Structure of cis-Monobenzylmononitrotetrahydro-closo-hexaborate(2-)
  2. Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von bindungsisomeren Halogenoselenocyanatorhenaten(IV) sowie Kristallstrukturen von mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] und mer-(n-Bu4N)2[ReCl3I(NCSe)2cis] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Linkage Isomeric Halogenoselenocyanatorhenates(IV) and Crystal Structures of mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] and mer-(n-Bu4N)2[ReCl3I(NCSe)2cis]
  3. Schwingungsspektren und Normalkoordinatenanalyse der Tetrahalogeno-closo-1,2-diphosphahexaborane P2B4X4, X = Cl, Br / Vibrational Spectra and Normal Coordinate Analysis of the Tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br
  4. Formation of η1-P-(2-Phosphinophenol)Ni(0)(PMe3)3 and Oxidation to cis/trans-Bis(2-phosphinophenolato)nickel(II) Complexes
  5. Bis-phosphonio-isophosphindolide Copper Complexes
  6. Octachalcogen Cations Te82+, Se82+, and Mixed (Te8-xSex)82+ Stabilized by Chlorometallates of Bi, Zr, and Hf: Synthesis and Crystal Structures of Se8[Bi4Cl14] and E8[MCl6] (E = Se, Te; M = Zr, Hf)
  7. Bis[1,3-bis(diphenylmethylsilylamido)propane]zirconium: A Spirocyclic Complex Containing a Sterically Demanding Chelating Amido Ligand
  8. Synthesis and Oxidation of Ruthenium Allyl Thioether Complexes Bearing Phosphite and Phosphonite Coligands [1]
  9. Interaction between the Peroxide Adduct of Binuclear Iron(III) Complex with (HPTP) Anion and the Sugar Moiety of Nucleosides
  10. The Intermetallic Compounds GdRe2Al10 and TbRe2Al10, Crystallizing with a Stacking Variant of the YbFe2Al10 Type Structure
  11. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumneodymbromiden / Thermal Decomposition and Solution Calorimetry of Ammonium Neodymium Bromides
  12. Novel Dinucleating Ligand Systems Containing Two Adjacent Coordination Compartments of the Potential Triamidoamine-Type - Nickel(II) and Cobalt(II) Coordination Chemistry
  13. Thioanalogs of Sparteine Lactams [6]. Part II. (+)-2-Thionosparteinium Perchlorate
  14. Crystal and Molecular Structure of the Copper(I)-thiolate-selenide Complex [Ph4P][Cu(SeS2CNC4H8)(S2CN2C4H8)] with an Unusual Se-S Bond
  15. Synthesis and Structural Characterization of [Me4N]2[W2O2(μ-S)(η2-S2)4]·MeCN, a Novel Oxo-thiotungstate(VI)
  16. X-Ray Structure Analysis of iso-Sildenafil (iso- Viagra) [1]
  17. Syntheses and Evaluation of the Analgesic Activity of Some 4-Acetyl- 4-phenylpiperidine and 4-Hydroxy-4-phenylpiperidine Derivatives
  18. An Approach to the Synthesis of New 1-Phenylacridones and Naphthacridones
  19. Notizen: Role of the Hydroxymethyl Group for the Inhibitory Activity of Penienone
https://doi.org/10.1515/znb-1999-1003
Schlagwörter für diesen Artikel
Tetrahalogeno-closo-1,2-diphosphahexaboranes; Vibrational Spectra; Normal Coordinate Analyses; Force Constants

Artikel in diesem Heft

  1. Synthese, Spektren und Kristallstruktur von cis-Monobenzylmononitrotetrahydro-closo-hexaborat(2-) / Synthesis, Spectra and Crystal Structure of cis-Monobenzylmononitrotetrahydro-closo-hexaborate(2-)
  2. Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von bindungsisomeren Halogenoselenocyanatorhenaten(IV) sowie Kristallstrukturen von mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] und mer-(n-Bu4N)2[ReCl3I(NCSe)2cis] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Linkage Isomeric Halogenoselenocyanatorhenates(IV) and Crystal Structures of mer-(Ph4P)2[ReCl3(NCSe)2cis (SeCN)] and mer-(n-Bu4N)2[ReCl3I(NCSe)2cis]
  3. Schwingungsspektren und Normalkoordinatenanalyse der Tetrahalogeno-closo-1,2-diphosphahexaborane P2B4X4, X = Cl, Br / Vibrational Spectra and Normal Coordinate Analysis of the Tetrahalogeno-closo-1,2-diphosphahexaboranes P2B4X4, X = Cl, Br
  4. Formation of η1-P-(2-Phosphinophenol)Ni(0)(PMe3)3 and Oxidation to cis/trans-Bis(2-phosphinophenolato)nickel(II) Complexes
  5. Bis-phosphonio-isophosphindolide Copper Complexes
  6. Octachalcogen Cations Te82+, Se82+, and Mixed (Te8-xSex)82+ Stabilized by Chlorometallates of Bi, Zr, and Hf: Synthesis and Crystal Structures of Se8[Bi4Cl14] and E8[MCl6] (E = Se, Te; M = Zr, Hf)
  7. Bis[1,3-bis(diphenylmethylsilylamido)propane]zirconium: A Spirocyclic Complex Containing a Sterically Demanding Chelating Amido Ligand
  8. Synthesis and Oxidation of Ruthenium Allyl Thioether Complexes Bearing Phosphite and Phosphonite Coligands [1]
  9. Interaction between the Peroxide Adduct of Binuclear Iron(III) Complex with (HPTP) Anion and the Sugar Moiety of Nucleosides
  10. The Intermetallic Compounds GdRe2Al10 and TbRe2Al10, Crystallizing with a Stacking Variant of the YbFe2Al10 Type Structure
  11. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumneodymbromiden / Thermal Decomposition and Solution Calorimetry of Ammonium Neodymium Bromides
  12. Novel Dinucleating Ligand Systems Containing Two Adjacent Coordination Compartments of the Potential Triamidoamine-Type - Nickel(II) and Cobalt(II) Coordination Chemistry
  13. Thioanalogs of Sparteine Lactams [6]. Part II. (+)-2-Thionosparteinium Perchlorate
  14. Crystal and Molecular Structure of the Copper(I)-thiolate-selenide Complex [Ph4P][Cu(SeS2CNC4H8)(S2CN2C4H8)] with an Unusual Se-S Bond
  15. Synthesis and Structural Characterization of [Me4N]2[W2O2(μ-S)(η2-S2)4]·MeCN, a Novel Oxo-thiotungstate(VI)
  16. X-Ray Structure Analysis of iso-Sildenafil (iso- Viagra) [1]
  17. Syntheses and Evaluation of the Analgesic Activity of Some 4-Acetyl- 4-phenylpiperidine and 4-Hydroxy-4-phenylpiperidine Derivatives
  18. An Approach to the Synthesis of New 1-Phenylacridones and Naphthacridones
  19. Notizen: Role of the Hydroxymethyl Group for the Inhibitory Activity of Penienone
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 16.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/znb-1999-1003/html
Button zum nach oben scrollen