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Synthesis and Reactivity of Novel Bis(stannyl)silanes

  • P. Bleckmann , U. Englich , U. Hermann , I. Prass , K. Ruhlandt-Senge , M. Schürmann , C. Schwittekh and F. Uhlig EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 9

Bis(stannyl)silanes of types R3Sn-SiR′2-SnR3 and R2(H)Sn-SiR′2-Sn(H)R2 with R′ being methyl, phenyl, iso-propyl or terf-butyl have been synthesized by treatment of difunctionalized diorganosilanes with alkali stannides (R = Me, tBu; R′= Me, iPr; 1 - 6, 8 ) or with triphenyltin chloride and magnesium (R = Ph; R′ = Me, iPh;Pr; 7, 9). Me3Sn-SitBu2-SnMe3 4, was halogenated using SnCl4, to yield the bis(chlorostannyl)silane 11.

The reaction of bis(stannyl)diorganosilanes R3SnSiR′SnR3 with catalytic amounts of Pd(PPh3)4 resulted in unexpected rearrangements under formation of the silyldistannanes R3SnSnR2SiR′R2. These compounds undergo addition reactions with alkynes. All compounds have been identified by NMR, IR, MS and elemental analysis. Compounds 5, 6 and 7 have also been characterized by X-ray crystallography.

Keywords: Stannylsilanes; Rearrangement; Reactions with Alkynes; X-Ray Data
Received: 1999-6-30
Published Online: 2014-6-2
Published in Print: 1999-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Die Kristallstruktur von [PhMe3 N]4 [Pb3Br10] / Crystal Structure of [PhMe3N]4[Pb3B r10]
  2. Hexaborate Cluster Radical Anions [B6Haln Hal'6-n].- and [B6Hal5R].-(Hai, Hal' = CI, Br, I; R = H, alkyl). Chemical or Electrochemical Generation, Vibrational, UV-Vis and EPR Spectroscopy
  3. Schwingungsspektren und Normalkoordinatenanalysen der Dioxoosmate( VI) trans-[OsO2(CN)4]2-, trans-[OsO2(CN)2(0H )]22- und trans-[OsO2(CN)2(OCH3)]22 sowie Kristallstruktur von trans-(Ph3PNPPh3)2[OsO2(CN)2(OCH3)]2 / Vibrational Spectra and Normal Coordinate Analysis of the Dioxoosmates(VI) trans-[OsO2(CN)4]2-, trans-[OsO2 (CN)2(OH)]22- and trans-[OsO2(CN)2(OCH3]22- , and Crystal Structure of trans-(Ph3PNPPh3)2[OsO2(CN)2(OCH3)]2
  4. Darstellung, Schwingungsspektren und Normalkoordinatenanalysen der Dioxoosmate(VI) trans-[OsO2(CN)2(ox)]2-, transs-[OsO2(CN)2(mal)]2- und trans-[OsO2(CN)2(N2H2C2O2)]2- / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of the Dioxoosmates(VI) frans-[OsO2(CN)2(ox)]2- , trans-[OsO2 (CN)2(mal)]2- and trans-[OsO2 (CN)2(N2H2C2O2)]2-
  5. Structure of [μ-S2{Ru(PCy3)('S4')}2] · 2.5 THF ·0.5 Et2O Containing Homochiral Metal Complex Fragments ['S4'2- = 1,2-Bis(mercaptophenylthio)-ethane (2-)]
  6. The Crystal Structure of WC Type ZrTe. Advantages in Chemical Bonding as Contrasted to NiAs Type ZrTe
  7. Wrap-around Encapsulated Cs(dibenzo-24-crown-8)+ Cations form Linear Coordination Polymers with Dicyanoargentate Anions Ag(CN)2-
  8. Reaktionsverhalten von β-Oxo-carbonsäurederivaten der Anthracenreihe bei der Synthese von Pyrazolen / On the Reaction Behavior of ß-Oxo Carbonic Acid Derivatives of the Anthracene Series in Pyrazole Synthesis
  9. Electrochemical Electron Transfer Reactions of M(ttcn)23+/2+ (M = Co, Pd, Pt, Au; ttcn = 1,4,7-trithiacyclononane): the Relation of Reaction Volumes and Electron Transfer Rate Constants
  10. Tuning the Energy of the NIR Absorption of Dinuclear Triphos-Cobalt-Complexes
  11. Structure and Properties of the Stannide Eu2Au2Sn5, and its Relationship with the Family of BaAl4-Related Structures
  12. 2-[N,N-Bis(trimethylstannyl)amino]pyridine and Bis[N-(N-trimethyIsiIyI- 2-aminopyridyI)]dimethyltin - Intramolecular N-Sn Co-ordination
  13. Preparation and X-Ray Structure of 4-N,N′-Bis(trimethylsilyl)- amino-3,5-diisopropylphenylselenium Trichloride
  14. One- and Two- Dimensional Copper(I) Halide Based Coordination Polymers with Bridging Pyridazine or Pyrimidine Ligands
  15. Methoxyalky 1-funktionalisierte 2,3-Dihy droimidazol-2-ylidene [1] / Methoxyalkyl Functionalized 2,3-Dihydroimidazol-2-ylidenes [1]
  16. Synthesis and Reactivity of Novel Bis(stannyl)silanes
  17. Cinnamoylacetonitrile in Heterocyclic Synthesis, Part 7 [1]. Simple Synthesis of Benzothiazepines, Pyrones and Oxazolopyridine
  18. Synthesis of 3-Phenylisoxazolo[3,4-a]carbazoles
  19. New Simple and One-Pot Synthetic Routes to Polyfunctionally Substituted Pyridines; 1,4-Dihydropyridazines and 4H-1,2-Oxazine
  20. Syntheses of Selected Quaternary Phenacylbromopyridinium Compounds and their Biological Evaluation
https://doi.org/10.1515/znb-1999-0916
Keywords for this article
Stannylsilanes; Rearrangement; Reactions with Alkynes; X-Ray Data

Articles in the same Issue

  1. Die Kristallstruktur von [PhMe3 N]4 [Pb3Br10] / Crystal Structure of [PhMe3N]4[Pb3B r10]
  2. Hexaborate Cluster Radical Anions [B6Haln Hal'6-n].- and [B6Hal5R].-(Hai, Hal' = CI, Br, I; R = H, alkyl). Chemical or Electrochemical Generation, Vibrational, UV-Vis and EPR Spectroscopy
  3. Schwingungsspektren und Normalkoordinatenanalysen der Dioxoosmate( VI) trans-[OsO2(CN)4]2-, trans-[OsO2(CN)2(0H )]22- und trans-[OsO2(CN)2(OCH3)]22 sowie Kristallstruktur von trans-(Ph3PNPPh3)2[OsO2(CN)2(OCH3)]2 / Vibrational Spectra and Normal Coordinate Analysis of the Dioxoosmates(VI) trans-[OsO2(CN)4]2-, trans-[OsO2 (CN)2(OH)]22- and trans-[OsO2(CN)2(OCH3]22- , and Crystal Structure of trans-(Ph3PNPPh3)2[OsO2(CN)2(OCH3)]2
  4. Darstellung, Schwingungsspektren und Normalkoordinatenanalysen der Dioxoosmate(VI) trans-[OsO2(CN)2(ox)]2-, transs-[OsO2(CN)2(mal)]2- und trans-[OsO2(CN)2(N2H2C2O2)]2- / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of the Dioxoosmates(VI) frans-[OsO2(CN)2(ox)]2- , trans-[OsO2 (CN)2(mal)]2- and trans-[OsO2 (CN)2(N2H2C2O2)]2-
  5. Structure of [μ-S2{Ru(PCy3)('S4')}2] · 2.5 THF ·0.5 Et2O Containing Homochiral Metal Complex Fragments ['S4'2- = 1,2-Bis(mercaptophenylthio)-ethane (2-)]
  6. The Crystal Structure of WC Type ZrTe. Advantages in Chemical Bonding as Contrasted to NiAs Type ZrTe
  7. Wrap-around Encapsulated Cs(dibenzo-24-crown-8)+ Cations form Linear Coordination Polymers with Dicyanoargentate Anions Ag(CN)2-
  8. Reaktionsverhalten von β-Oxo-carbonsäurederivaten der Anthracenreihe bei der Synthese von Pyrazolen / On the Reaction Behavior of ß-Oxo Carbonic Acid Derivatives of the Anthracene Series in Pyrazole Synthesis
  9. Electrochemical Electron Transfer Reactions of M(ttcn)23+/2+ (M = Co, Pd, Pt, Au; ttcn = 1,4,7-trithiacyclononane): the Relation of Reaction Volumes and Electron Transfer Rate Constants
  10. Tuning the Energy of the NIR Absorption of Dinuclear Triphos-Cobalt-Complexes
  11. Structure and Properties of the Stannide Eu2Au2Sn5, and its Relationship with the Family of BaAl4-Related Structures
  12. 2-[N,N-Bis(trimethylstannyl)amino]pyridine and Bis[N-(N-trimethyIsiIyI- 2-aminopyridyI)]dimethyltin - Intramolecular N-Sn Co-ordination
  13. Preparation and X-Ray Structure of 4-N,N′-Bis(trimethylsilyl)- amino-3,5-diisopropylphenylselenium Trichloride
  14. One- and Two- Dimensional Copper(I) Halide Based Coordination Polymers with Bridging Pyridazine or Pyrimidine Ligands
  15. Methoxyalky 1-funktionalisierte 2,3-Dihy droimidazol-2-ylidene [1] / Methoxyalkyl Functionalized 2,3-Dihydroimidazol-2-ylidenes [1]
  16. Synthesis and Reactivity of Novel Bis(stannyl)silanes
  17. Cinnamoylacetonitrile in Heterocyclic Synthesis, Part 7 [1]. Simple Synthesis of Benzothiazepines, Pyrones and Oxazolopyridine
  18. Synthesis of 3-Phenylisoxazolo[3,4-a]carbazoles
  19. New Simple and One-Pot Synthetic Routes to Polyfunctionally Substituted Pyridines; 1,4-Dihydropyridazines and 4H-1,2-Oxazine
  20. Syntheses of Selected Quaternary Phenacylbromopyridinium Compounds and their Biological Evaluation
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