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Antimony as a Donor Atom in Silver Coordination Chemistry: Synthesis, IR Spectra and Structure of the Silver(I) Cyanoximate Complexes with Triphenylstibine and Triphenylphosphine Model Compounds

  • Konstantin V. Domasevitch , Elena G. Petkova , Alexander Yu. Nazarenko , Vera V. Ponomareva EMAIL logo , Joachim Sieler , N. Kent Dalley and Eduard B. Rusanov
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 7

Silver(I) cyanoximate complexes Ag{ONC(CN)-R} (R = COPh, {L1}; COC(CH3)3, {L2}; benzothiazol-2-yl, {L3}) with triphenylphosphine and -stibine of compositions Ag(PPh3)n{L} (n = 2, 4) and Ag(SbPh3)n{L} (n = 3 for {L1} and {L2}, n = 2 for {L3}) were synthesized by the reaction of the components in acetonitrile solution and characterized by elemental analyses and IR spectroscopy. The crystal structures of Ag(SbPh3)3{L} (L = {L1} (1), {L2} (2), Ag(SbPh3)2{L3} ∙ CH3CN (3) and Ag(PPh3)2{L1} ∙ CH3CN (4), have been determined by X-ray diffraction. For all the compounds examined the coordination environment of the silver atom has the geometry of a distorted terahedron ([AgP2NO] (4); [AgSb3N] (1), (2); [AgSb2N2] (3)). The bis adducts Ag(EPh3)n{L} adopt molecular structures, in which the organic anions are coordinated in bidentate chelate fashion via the nitroso nitrogen atom and the oxygen (nitrogen for {L3}) atom of the substituent R. In the tris-stibino complexes (Ag-Sb 2.670(4) - 2.7748(8) Å; Sb-Ag-Sb 108.87(4) - 115.00(2)°) the cyanoximates are unidentate ligands and coordinated via the nitroso nitrogen atoms (Ag-N ca. 2.35(1) Å). The different behaviour of N ,O and N,N chelating cyanoximes under the same conditions suggests, that the Sb donor triphenylstibine is able to substitute the oxygen atoms in the silver(I) coordination sphere, but not the nitrogen ones. This causes the formation of 1:3 adducts of Ag{L} with SbPh3 for N ,O donors {L1} and {L2}, and only 1:2 for N,N donor anionic {L3}.

Keywords: Silver; Triphenylphosphine; Triphenylstibine; Cyanoximes; X-Ray Data
Received: 1998-12-15
Published Online: 2014-6-2
Published in Print: 1999-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  1. Titelei
  2. The Structural Chemistry of GoId(I) Quinoline-2-thiolate and Iodide Complexes of Polytertiary Phosphines
  3. EPR-Einkristall-Untersuchungen an (n-Bu4N)2[Cu(dmit)2] im antiferromagnetisch gekoppelten Wirtsgitter (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: Ein Beitrag zur Aufklärung der sogenannten „paramagnetischen Verunreinigung“ im Wirtsgitter / A Single Crystal EPR Investigation on (n-Bu4N)2[Cu(dmit)2] in the Antiferromagnetically Coupled Host Lattice (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: A Contribution to the Nature of the So-called “Paramagnetic Impurities”
  4. Reaktionen von [(η5-C5R5)2WH2] mit Boranen / Reactions of [(η5-C5R5)2WH2] with Boranes
  5. [Ni(NH3 )6]S04 : Kristallstruktur und Infrarotspektren / [Ni(NH3)6]SO4: Crystal Structure and Infrared Spectra
  6. Zur Reaktion von 2,4-Dioxo-4-ferrocenyl-butansäureethylester mit primären aromatischen Aminen / On the Reaction of Ethyl 2,4-Dioxo-4-ferrocenyl-butanoate with Primary Aromatic Amines
  7. Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides
  8. Condensed [Ru4Sn6] Units in the Stannides LnRu4Sn6 (Ln = La, Pr, Nd, Sm, Gd) - Synthesis, Structure, and Chemical Bonding
  9. Neutronen- und Röntgenbeugungsuntersuchungen an Pulvern und Einkristallen von Strukturverwandten des Berliner Blaus: CsMnIICrIII(CN)6 · D2O , NMe4MnII(Cr0,06,Mn0,94)III(CN)6 · 8 H2O , NMe4MnIICoIII(CN)6 · 8 H20 , Mn3II[MnIII(CN)6]2 · 15 H2O und Cd3[FeIII(CN)6]2 · 15 H2O / Neutron and X-Ray Diffraction Studies on Powders and Single Crystals of Compounds Structurally Related to Prussian Blue: CsMnIICrIII(CN)6 · D2O, NMe4MnII(Cr0,06Mn0,94)III(CN)6 · 8 H2O, NMe4MnIICoIII(CN)6 · 8 H2O, Mn3II[MnIII(CN)6]2 · 15 H2O and Cd3[FeIII(CN)6]2 · 15 H2O
  10. Über das Octastannandiid R*6Sn8[Na(THF)2 ]2 und zur möglichen Existenz des Octastannans R*6Sn8 [1] / On an Octastannanediide R*6Sn8[Na(THF)2]2 and the Possible Existence of an Octastannane R*6Sn8 [1]
  11. Ligandenaustauschreaktionen von NiCl2 (PPh3)2 mit O(S)⌒N⌒S-Liganden / Ligand Exchange Reactions of NiCl2(PPh3)2 with O(S )⌒ N ⌒ S Ligands
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  14. Mixed-Sandwich η5/η7 Vanadium Complexes. The Molecular Structure of (η5-2-Methyl-indenyl)-(η7-cycloheptatrienyl)-vanadium
  15. Antimony as a Donor Atom in Silver Coordination Chemistry: Synthesis, IR Spectra and Structure of the Silver(I) Cyanoximate Complexes with Triphenylstibine and Triphenylphosphine Model Compounds
  16. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 3. Mitteilung. Mechanismus der Aminoxid-Bildung / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 3rd Communication. Mechanism of Amine Oxide Generation
  17. Alkyl Heteroaromatics as Building Blocks in Organic Synthesis: The Reactivity of Alkyl Azoles toward Electrophilic Reagents
  18. Electronic Structure of 2,6-Bis{.N-(2-hydroxyphenyl)immoinethyl}-4-methylphenol
  19. Two New Aromatic Constituents from Stocksia brahuica
  20. Structure and Conformation of Tetra-meso-, Octa-β-, and Dodecasubstituted 22,24-Dihydroporphyrins (Porphyrin Dications)
  21. Organoactinide Chemistry: Polysilylated Actinidocenes of Thorium, Uranium, and Neptunium
https://doi.org/10.1515/znb-1999-0714
Keywords for this article
Silver; Triphenylphosphine; Triphenylstibine; Cyanoximes; X-Ray Data

Articles in the same Issue

  1. Titelei
  2. The Structural Chemistry of GoId(I) Quinoline-2-thiolate and Iodide Complexes of Polytertiary Phosphines
  3. EPR-Einkristall-Untersuchungen an (n-Bu4N)2[Cu(dmit)2] im antiferromagnetisch gekoppelten Wirtsgitter (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: Ein Beitrag zur Aufklärung der sogenannten „paramagnetischen Verunreinigung“ im Wirtsgitter / A Single Crystal EPR Investigation on (n-Bu4N)2[Cu(dmit)2] in the Antiferromagnetically Coupled Host Lattice (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: A Contribution to the Nature of the So-called “Paramagnetic Impurities”
  4. Reaktionen von [(η5-C5R5)2WH2] mit Boranen / Reactions of [(η5-C5R5)2WH2] with Boranes
  5. [Ni(NH3 )6]S04 : Kristallstruktur und Infrarotspektren / [Ni(NH3)6]SO4: Crystal Structure and Infrared Spectra
  6. Zur Reaktion von 2,4-Dioxo-4-ferrocenyl-butansäureethylester mit primären aromatischen Aminen / On the Reaction of Ethyl 2,4-Dioxo-4-ferrocenyl-butanoate with Primary Aromatic Amines
  7. Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides
  8. Condensed [Ru4Sn6] Units in the Stannides LnRu4Sn6 (Ln = La, Pr, Nd, Sm, Gd) - Synthesis, Structure, and Chemical Bonding
  9. Neutronen- und Röntgenbeugungsuntersuchungen an Pulvern und Einkristallen von Strukturverwandten des Berliner Blaus: CsMnIICrIII(CN)6 · D2O , NMe4MnII(Cr0,06,Mn0,94)III(CN)6 · 8 H2O , NMe4MnIICoIII(CN)6 · 8 H20 , Mn3II[MnIII(CN)6]2 · 15 H2O und Cd3[FeIII(CN)6]2 · 15 H2O / Neutron and X-Ray Diffraction Studies on Powders and Single Crystals of Compounds Structurally Related to Prussian Blue: CsMnIICrIII(CN)6 · D2O, NMe4MnII(Cr0,06Mn0,94)III(CN)6 · 8 H2O, NMe4MnIICoIII(CN)6 · 8 H2O, Mn3II[MnIII(CN)6]2 · 15 H2O and Cd3[FeIII(CN)6]2 · 15 H2O
  10. Über das Octastannandiid R*6Sn8[Na(THF)2 ]2 und zur möglichen Existenz des Octastannans R*6Sn8 [1] / On an Octastannanediide R*6Sn8[Na(THF)2]2 and the Possible Existence of an Octastannane R*6Sn8 [1]
  11. Ligandenaustauschreaktionen von NiCl2 (PPh3)2 mit O(S)⌒N⌒S-Liganden / Ligand Exchange Reactions of NiCl2(PPh3)2 with O(S )⌒ N ⌒ S Ligands
  12. Bis(n-pentanethiolato)mercury(II), Hg(SC5H11)2 - Preparation, Characterization, Crystal and Molecular Structure; Reactivity towards Organic Thiols
  13. K[B6PO10(OH)4]: Ein Borophosphat mit gestreckten Bändern aus Tetraeder-Vierer-Ringen und offen-zyklischen Verzweigungen über planare B2O3(OH)2-Gruppen / K[B6PO10(OH)4]: A Borophosphate Containing Rods of Tetrahedral Vierer-Rings with Additional Open-Loop Branchings via Planar B2O3(OH)2 Groups
  14. Mixed-Sandwich η5/η7 Vanadium Complexes. The Molecular Structure of (η5-2-Methyl-indenyl)-(η7-cycloheptatrienyl)-vanadium
  15. Antimony as a Donor Atom in Silver Coordination Chemistry: Synthesis, IR Spectra and Structure of the Silver(I) Cyanoximate Complexes with Triphenylstibine and Triphenylphosphine Model Compounds
  16. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 3. Mitteilung. Mechanismus der Aminoxid-Bildung / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 3rd Communication. Mechanism of Amine Oxide Generation
  17. Alkyl Heteroaromatics as Building Blocks in Organic Synthesis: The Reactivity of Alkyl Azoles toward Electrophilic Reagents
  18. Electronic Structure of 2,6-Bis{.N-(2-hydroxyphenyl)immoinethyl}-4-methylphenol
  19. Two New Aromatic Constituents from Stocksia brahuica
  20. Structure and Conformation of Tetra-meso-, Octa-β-, and Dodecasubstituted 22,24-Dihydroporphyrins (Porphyrin Dications)
  21. Organoactinide Chemistry: Polysilylated Actinidocenes of Thorium, Uranium, and Neptunium
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