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The Structural Chemistry of GoId(I) Quinoline-2-thiolate and Iodide Complexes of Polytertiary Phosphines

  • Biing-Chiau Tzeng , Johann Zank , Annette Schier and Hubert Schmidbaur
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 7

Treatment of (chloro)gold(I) complexes of di- and tetra-tertiary phosphines with equivalent quantities of sodium quinoline-2-thiolate in methanol / dichloromethane affords the corresponding (phosphine)gold(I) quinoline-2-thiolates in high yields. The di- and tetranuclear complexes, respectively, of α, ω-bis(diphenylphosphino)-propane (1), -butane (2) and -pentane (3) and of tris(2-diphenylphosphino-ethyl)phosphine (4) have been obtained as crystalline solids, and the structures of 2 and 4 have been determined by single crystal X-ray diffraction studies. Unexpectedly, the molecules of 2 are loosely aggregated into strings via weak intermolecular gold-sulfur, not via Au ∙∙∙ Au interactions. Compound 4 is a monomeric tetranuclear cluster in the solid state with two intramolecular gold-gold bonds. Bis(2-diphenylphosphino-ethyl)- phenylphosphine (PPP) forms trinuclear complexes with gold(I) chloride, bromide and iodide (5a - c). The iodide complex features a chain structure through intermolecular Au ∙∙∙ Au contacts between the two terminal P-Au-I units. The closest contacts between the chains are determined by Au ∙∙∙ I and I ∙∙∙ I interactions of the central P-Au-I unit.

Keywords: Gold(I) Complexes; Thiolate Complexes; Aurophilicity; Hydrogen Bonding; Polytertiary Phosphine Complexes
Received: 1999-4-19
Published Online: 2014-6-2
Published in Print: 1999-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Titelei
  2. The Structural Chemistry of GoId(I) Quinoline-2-thiolate and Iodide Complexes of Polytertiary Phosphines
  3. EPR-Einkristall-Untersuchungen an (n-Bu4N)2[Cu(dmit)2] im antiferromagnetisch gekoppelten Wirtsgitter (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: Ein Beitrag zur Aufklärung der sogenannten „paramagnetischen Verunreinigung“ im Wirtsgitter / A Single Crystal EPR Investigation on (n-Bu4N)2[Cu(dmit)2] in the Antiferromagnetically Coupled Host Lattice (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: A Contribution to the Nature of the So-called “Paramagnetic Impurities”
  4. Reaktionen von [(η5-C5R5)2WH2] mit Boranen / Reactions of [(η5-C5R5)2WH2] with Boranes
  5. [Ni(NH3 )6]S04 : Kristallstruktur und Infrarotspektren / [Ni(NH3)6]SO4: Crystal Structure and Infrared Spectra
  6. Zur Reaktion von 2,4-Dioxo-4-ferrocenyl-butansäureethylester mit primären aromatischen Aminen / On the Reaction of Ethyl 2,4-Dioxo-4-ferrocenyl-butanoate with Primary Aromatic Amines
  7. Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides
  8. Condensed [Ru4Sn6] Units in the Stannides LnRu4Sn6 (Ln = La, Pr, Nd, Sm, Gd) - Synthesis, Structure, and Chemical Bonding
  9. Neutronen- und Röntgenbeugungsuntersuchungen an Pulvern und Einkristallen von Strukturverwandten des Berliner Blaus: CsMnIICrIII(CN)6 · D2O , NMe4MnII(Cr0,06,Mn0,94)III(CN)6 · 8 H2O , NMe4MnIICoIII(CN)6 · 8 H20 , Mn3II[MnIII(CN)6]2 · 15 H2O und Cd3[FeIII(CN)6]2 · 15 H2O / Neutron and X-Ray Diffraction Studies on Powders and Single Crystals of Compounds Structurally Related to Prussian Blue: CsMnIICrIII(CN)6 · D2O, NMe4MnII(Cr0,06Mn0,94)III(CN)6 · 8 H2O, NMe4MnIICoIII(CN)6 · 8 H2O, Mn3II[MnIII(CN)6]2 · 15 H2O and Cd3[FeIII(CN)6]2 · 15 H2O
  10. Über das Octastannandiid R*6Sn8[Na(THF)2 ]2 und zur möglichen Existenz des Octastannans R*6Sn8 [1] / On an Octastannanediide R*6Sn8[Na(THF)2]2 and the Possible Existence of an Octastannane R*6Sn8 [1]
  11. Ligandenaustauschreaktionen von NiCl2 (PPh3)2 mit O(S)⌒N⌒S-Liganden / Ligand Exchange Reactions of NiCl2(PPh3)2 with O(S )⌒ N ⌒ S Ligands
  12. Bis(n-pentanethiolato)mercury(II), Hg(SC5H11)2 - Preparation, Characterization, Crystal and Molecular Structure; Reactivity towards Organic Thiols
  13. K[B6PO10(OH)4]: Ein Borophosphat mit gestreckten Bändern aus Tetraeder-Vierer-Ringen und offen-zyklischen Verzweigungen über planare B2O3(OH)2-Gruppen / K[B6PO10(OH)4]: A Borophosphate Containing Rods of Tetrahedral Vierer-Rings with Additional Open-Loop Branchings via Planar B2O3(OH)2 Groups
  14. Mixed-Sandwich η5/η7 Vanadium Complexes. The Molecular Structure of (η5-2-Methyl-indenyl)-(η7-cycloheptatrienyl)-vanadium
  15. Antimony as a Donor Atom in Silver Coordination Chemistry: Synthesis, IR Spectra and Structure of the Silver(I) Cyanoximate Complexes with Triphenylstibine and Triphenylphosphine Model Compounds
  16. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 3. Mitteilung. Mechanismus der Aminoxid-Bildung / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 3rd Communication. Mechanism of Amine Oxide Generation
  17. Alkyl Heteroaromatics as Building Blocks in Organic Synthesis: The Reactivity of Alkyl Azoles toward Electrophilic Reagents
  18. Electronic Structure of 2,6-Bis{.N-(2-hydroxyphenyl)immoinethyl}-4-methylphenol
  19. Two New Aromatic Constituents from Stocksia brahuica
  20. Structure and Conformation of Tetra-meso-, Octa-β-, and Dodecasubstituted 22,24-Dihydroporphyrins (Porphyrin Dications)
  21. Organoactinide Chemistry: Polysilylated Actinidocenes of Thorium, Uranium, and Neptunium
https://doi.org/10.1515/znb-1999-0701
Keywords for this article
Gold(I) Complexes; Thiolate Complexes; Aurophilicity; Hydrogen Bonding; Polytertiary Phosphine Complexes

Articles in the same Issue

  1. Titelei
  2. The Structural Chemistry of GoId(I) Quinoline-2-thiolate and Iodide Complexes of Polytertiary Phosphines
  3. EPR-Einkristall-Untersuchungen an (n-Bu4N)2[Cu(dmit)2] im antiferromagnetisch gekoppelten Wirtsgitter (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: Ein Beitrag zur Aufklärung der sogenannten „paramagnetischen Verunreinigung“ im Wirtsgitter / A Single Crystal EPR Investigation on (n-Bu4N)2[Cu(dmit)2] in the Antiferromagnetically Coupled Host Lattice (n-Bu4N)2[(dmit)Cu(tto)Cu(dmit)]: A Contribution to the Nature of the So-called “Paramagnetic Impurities”
  4. Reaktionen von [(η5-C5R5)2WH2] mit Boranen / Reactions of [(η5-C5R5)2WH2] with Boranes
  5. [Ni(NH3 )6]S04 : Kristallstruktur und Infrarotspektren / [Ni(NH3)6]SO4: Crystal Structure and Infrared Spectra
  6. Zur Reaktion von 2,4-Dioxo-4-ferrocenyl-butansäureethylester mit primären aromatischen Aminen / On the Reaction of Ethyl 2,4-Dioxo-4-ferrocenyl-butanoate with Primary Aromatic Amines
  7. Complexes of N-Aryltriphenylphosphinimines with Mercury(II) Halides
  8. Condensed [Ru4Sn6] Units in the Stannides LnRu4Sn6 (Ln = La, Pr, Nd, Sm, Gd) - Synthesis, Structure, and Chemical Bonding
  9. Neutronen- und Röntgenbeugungsuntersuchungen an Pulvern und Einkristallen von Strukturverwandten des Berliner Blaus: CsMnIICrIII(CN)6 · D2O , NMe4MnII(Cr0,06,Mn0,94)III(CN)6 · 8 H2O , NMe4MnIICoIII(CN)6 · 8 H20 , Mn3II[MnIII(CN)6]2 · 15 H2O und Cd3[FeIII(CN)6]2 · 15 H2O / Neutron and X-Ray Diffraction Studies on Powders and Single Crystals of Compounds Structurally Related to Prussian Blue: CsMnIICrIII(CN)6 · D2O, NMe4MnII(Cr0,06Mn0,94)III(CN)6 · 8 H2O, NMe4MnIICoIII(CN)6 · 8 H2O, Mn3II[MnIII(CN)6]2 · 15 H2O and Cd3[FeIII(CN)6]2 · 15 H2O
  10. Über das Octastannandiid R*6Sn8[Na(THF)2 ]2 und zur möglichen Existenz des Octastannans R*6Sn8 [1] / On an Octastannanediide R*6Sn8[Na(THF)2]2 and the Possible Existence of an Octastannane R*6Sn8 [1]
  11. Ligandenaustauschreaktionen von NiCl2 (PPh3)2 mit O(S)⌒N⌒S-Liganden / Ligand Exchange Reactions of NiCl2(PPh3)2 with O(S )⌒ N ⌒ S Ligands
  12. Bis(n-pentanethiolato)mercury(II), Hg(SC5H11)2 - Preparation, Characterization, Crystal and Molecular Structure; Reactivity towards Organic Thiols
  13. K[B6PO10(OH)4]: Ein Borophosphat mit gestreckten Bändern aus Tetraeder-Vierer-Ringen und offen-zyklischen Verzweigungen über planare B2O3(OH)2-Gruppen / K[B6PO10(OH)4]: A Borophosphate Containing Rods of Tetrahedral Vierer-Rings with Additional Open-Loop Branchings via Planar B2O3(OH)2 Groups
  14. Mixed-Sandwich η5/η7 Vanadium Complexes. The Molecular Structure of (η5-2-Methyl-indenyl)-(η7-cycloheptatrienyl)-vanadium
  15. Antimony as a Donor Atom in Silver Coordination Chemistry: Synthesis, IR Spectra and Structure of the Silver(I) Cyanoximate Complexes with Triphenylstibine and Triphenylphosphine Model Compounds
  16. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 3. Mitteilung. Mechanismus der Aminoxid-Bildung / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 3rd Communication. Mechanism of Amine Oxide Generation
  17. Alkyl Heteroaromatics as Building Blocks in Organic Synthesis: The Reactivity of Alkyl Azoles toward Electrophilic Reagents
  18. Electronic Structure of 2,6-Bis{.N-(2-hydroxyphenyl)immoinethyl}-4-methylphenol
  19. Two New Aromatic Constituents from Stocksia brahuica
  20. Structure and Conformation of Tetra-meso-, Octa-β-, and Dodecasubstituted 22,24-Dihydroporphyrins (Porphyrin Dications)
  21. Organoactinide Chemistry: Polysilylated Actinidocenes of Thorium, Uranium, and Neptunium
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