Home Physical Sciences Kristallstruktur des „supramolekularen“ Komplexes [K(Benzo-18-krone-6)][Zn(CN)3]*H2O mit einem polymeren kettenförmigen Tricyanozincat-Anion / Crystal Structure of the “Supramolecular” Complex [K(benzo-18-crown-6)][Zn(CN)3] •H2O with a Polymeric Tricyano Zincate Anion with Chain Structure
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Kristallstruktur des „supramolekularen“ Komplexes [K(Benzo-18-krone-6)][Zn(CN)3]*H2O mit einem polymeren kettenförmigen Tricyanozincat-Anion / Crystal Structure of the “Supramolecular” Complex [K(benzo-18-crown-6)][Zn(CN)3] •H2O with a Polymeric Tricyano Zincate Anion with Chain Structure

  • Joachim Pickardt EMAIL logo and Pirka Wischlinski
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 6

Crystals o f the complex [K (benzo-18-crown-6][Zn(CN)3] H2O were obtained from a solution o f Zn(CN)2, KCN, and benzo-18-crown-6 in water/methanol. The compound crystallizes in the triclinic space group PI (no. 2),: Z = 2, a = 818,6(5), b = 1236,7(8), c = 1359,6(6) pm, a = 67,02(4), β = 87,38(4), 7 = 75,46(5). Each Zn atom is bonded to one bridging cyanide ion to give chains -Zn(CN)Zn -, and to two terminal CN groups. The N atom of one of the terminal CN groups interacts with a potassium ion o f the [K (benzo-18-crown-6)]+ unit. The coordination spheres of the K ions are completed by water molecules, which in turn form hydrogen bonds to N atoms of terminal CN groups of neighbouring chains, whereby puckered sheets are formed

Keywords: Zinc Cyanide Complex; Crown Ether Complex; Crystal Structure
Received: 1999-2-10
Published Online: 2014-6-2
Published in Print: 1999-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Decomposition of Ethoxyethynyl(trimethyl)tin - Studied by 119Sn and 13C NMR Spectroscopy
  2. New Stannides CaTSn2 (T = Rh, Pd, Ir) and Ca2Pt3Sn5 - Synthesis, Structure and Chemical Bonding
  3. Synthesis and Structural Study of the Thermochromic Compounds Bis(2-amino-4-oxo-6-methylpyrimidinium) Tetrachlorocuprate(II) and Bis(2-amino-4-chloro-6-methylpyrimidinium) Hexachlorodicuprate(II)
  4. Cascade Reaction of Camphor-Derived Diynes with Transition Metal Compounds
  5. Metallkomplexe mit biologisch wichtigen Liganden, CXIX [1]. Ein tetraedrischer Zink-Komplex (L-terf-Leucin)2ZnCl2 mit Carboxylat-koordiniertem L-terf-Leucin in der / Zwitterform Metal Complexes of Biologically Important Ligands, CXIX [1]. A Tetrahedral Zinc Complex (L-terf-Leucine)2ZnCl2 of Carboxylate Coordinated L-terr-Leucine in the Zwitterionic Form
  6. Untersuchungen zum chemischen Transport intermetallischer Phasen, I: GeTe, SnTe, PbTe / Investigations on the Chemical Transport of Intermetallic Phases, I: GeTe, SnTe, PbTe
  7. Kristallstruktur des „supramolekularen“ Komplexes [K(Benzo-18-krone-6)][Zn(CN)3]*H2O mit einem polymeren kettenförmigen Tricyanozincat-Anion / Crystal Structure of the “Supramolecular” Complex [K(benzo-18-crown-6)][Zn(CN)3] •H2O with a Polymeric Tricyano Zincate Anion with Chain Structure
  8. 1.2-Verzweigte Carbosiloxan-Dendrimere mit Hauptgruppenelementund Übergangsmetall-modifizierten Oberflächen / 1.2-Branched Carbosiloxane-Dendrimers with Main-Group Element and Transition-Metal Modified Surfaces
  9. Darstellung und Kristallstruktur von Triammonium-trisulfimid (NH4)3(NSO2)3 / Preparation and Crystal Structure of Triammonium-trisulfimid (NH4)3(NSO2)3
  10. Synthese und Röntgenstrukturanalyse der ersten terf-Butylcalix[4]arensalze mit einem Phosphonium-Kation / Synthesis and X-Ray Structure Analysis of the First rm-Butylcalix[4]arene Salts with a Phosphonium Cation
  11. Kristallstrukturen und Normalkoordinatenanalyse von trans-(n-Bu4N)2 [ReCl4IX], X = NCS, NCSe / Crystal Structures and Normal Coordinate Analyses of trans-(n-Bu4 N)2[ReCl4 IX], X = NCS, NCSe
  12. Darstellung, 11B-NMR- und Schwingungsspektren von c/s-Monoethylmononitrotetrahydro- c/050-hexaborat(2-) sowie Kristallstruktur von cis (Ph4As)2[B6H4(C2H5)(NO2)] / Synthesis, 11B NMR and Vibrational Spectra of cis-Monoethylmononitrotetrahydroc-closo-hexaborate(2-) and Crystal Structure of cis-(Ph4As)2[B6 H4 (C2H5 )(NO2)]
  13. Complexes of Group 12 Metals with 2-Acetylpyridine 4N-Dimethylthiosemicarbazone and with 2-Acetylpyridine-N-oxide 4N-Dimethylthiosemicarbazone: Synthesis, Structure and Antifungal Activity
  14. Synthesis of Pyrimidine, Thiazolopyrimidine, Pyrimidotriazine and Triazolopyrimidine Derivatives and their Biological Evaluation
  15. SbCI3, BiCl3 and Na+ Complexes of Maleonitrile-Dithiacrown Ethers: Synthesis, Crystal Structures and DEP-MS Experiments
  16. Zatatriol: A New Aromatic Constituent from Zataria multiflora
  17. A Facile Synthesis of Naphthyl-Quinolyl Ethanes and Chromenyl-Quinolyl Ethanes
  18. Microwave-Assisted Oxidation of Alcohols Using Wet Alumina Supported Ammonium Chlorochromate in Solventless System
  19. Die Kristallstruktur von [(THF)LiCl]n / The Crystal Structure of [(THF)LiCl]n
  20. Fixation o f Neutral Molecules in the Binding Cavity of Nonplanar Porphyrins - A Third Dodecaphenylporphyrin Modification with NH -Solvent Hydrogen Bonding
https://doi.org/10.1515/znb-1999-0607
Keywords for this article
Zinc Cyanide Complex; Crown Ether Complex; Crystal Structure

Articles in the same Issue

  1. Decomposition of Ethoxyethynyl(trimethyl)tin - Studied by 119Sn and 13C NMR Spectroscopy
  2. New Stannides CaTSn2 (T = Rh, Pd, Ir) and Ca2Pt3Sn5 - Synthesis, Structure and Chemical Bonding
  3. Synthesis and Structural Study of the Thermochromic Compounds Bis(2-amino-4-oxo-6-methylpyrimidinium) Tetrachlorocuprate(II) and Bis(2-amino-4-chloro-6-methylpyrimidinium) Hexachlorodicuprate(II)
  4. Cascade Reaction of Camphor-Derived Diynes with Transition Metal Compounds
  5. Metallkomplexe mit biologisch wichtigen Liganden, CXIX [1]. Ein tetraedrischer Zink-Komplex (L-terf-Leucin)2ZnCl2 mit Carboxylat-koordiniertem L-terf-Leucin in der / Zwitterform Metal Complexes of Biologically Important Ligands, CXIX [1]. A Tetrahedral Zinc Complex (L-terf-Leucine)2ZnCl2 of Carboxylate Coordinated L-terr-Leucine in the Zwitterionic Form
  6. Untersuchungen zum chemischen Transport intermetallischer Phasen, I: GeTe, SnTe, PbTe / Investigations on the Chemical Transport of Intermetallic Phases, I: GeTe, SnTe, PbTe
  7. Kristallstruktur des „supramolekularen“ Komplexes [K(Benzo-18-krone-6)][Zn(CN)3]*H2O mit einem polymeren kettenförmigen Tricyanozincat-Anion / Crystal Structure of the “Supramolecular” Complex [K(benzo-18-crown-6)][Zn(CN)3] •H2O with a Polymeric Tricyano Zincate Anion with Chain Structure
  8. 1.2-Verzweigte Carbosiloxan-Dendrimere mit Hauptgruppenelementund Übergangsmetall-modifizierten Oberflächen / 1.2-Branched Carbosiloxane-Dendrimers with Main-Group Element and Transition-Metal Modified Surfaces
  9. Darstellung und Kristallstruktur von Triammonium-trisulfimid (NH4)3(NSO2)3 / Preparation and Crystal Structure of Triammonium-trisulfimid (NH4)3(NSO2)3
  10. Synthese und Röntgenstrukturanalyse der ersten terf-Butylcalix[4]arensalze mit einem Phosphonium-Kation / Synthesis and X-Ray Structure Analysis of the First rm-Butylcalix[4]arene Salts with a Phosphonium Cation
  11. Kristallstrukturen und Normalkoordinatenanalyse von trans-(n-Bu4N)2 [ReCl4IX], X = NCS, NCSe / Crystal Structures and Normal Coordinate Analyses of trans-(n-Bu4 N)2[ReCl4 IX], X = NCS, NCSe
  12. Darstellung, 11B-NMR- und Schwingungsspektren von c/s-Monoethylmononitrotetrahydro- c/050-hexaborat(2-) sowie Kristallstruktur von cis (Ph4As)2[B6H4(C2H5)(NO2)] / Synthesis, 11B NMR and Vibrational Spectra of cis-Monoethylmononitrotetrahydroc-closo-hexaborate(2-) and Crystal Structure of cis-(Ph4As)2[B6 H4 (C2H5 )(NO2)]
  13. Complexes of Group 12 Metals with 2-Acetylpyridine 4N-Dimethylthiosemicarbazone and with 2-Acetylpyridine-N-oxide 4N-Dimethylthiosemicarbazone: Synthesis, Structure and Antifungal Activity
  14. Synthesis of Pyrimidine, Thiazolopyrimidine, Pyrimidotriazine and Triazolopyrimidine Derivatives and their Biological Evaluation
  15. SbCI3, BiCl3 and Na+ Complexes of Maleonitrile-Dithiacrown Ethers: Synthesis, Crystal Structures and DEP-MS Experiments
  16. Zatatriol: A New Aromatic Constituent from Zataria multiflora
  17. A Facile Synthesis of Naphthyl-Quinolyl Ethanes and Chromenyl-Quinolyl Ethanes
  18. Microwave-Assisted Oxidation of Alcohols Using Wet Alumina Supported Ammonium Chlorochromate in Solventless System
  19. Die Kristallstruktur von [(THF)LiCl]n / The Crystal Structure of [(THF)LiCl]n
  20. Fixation o f Neutral Molecules in the Binding Cavity of Nonplanar Porphyrins - A Third Dodecaphenylporphyrin Modification with NH -Solvent Hydrogen Bonding
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