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Tris(ethyldimethylphenylammonium) nonahalogenodibismuthates(III)

  • H. Eickmeier , Bernd Jaschinski , A. Hepp , Jürgen Nuß , Hans Reuter and Roger Blachnik
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 3

The halogenobismuthates Q3Bi2X9 (Q = EtMe2PhN; X = Cl, Br, I) were prepared by reaction of BiX3 with EtMe2PhNX in ethanol. Single crystal structure determinations yielded: [EtMe2PhN]3[Bi2Cl9], S.G. P212121, Nr. 19, a = 952.5(3), b = 1184.1(4), c = 3726.4(9 pm, Z = 2;[EtMe2PhN]3[Bi2Br9] S.G .P21/c , No. 14, a= 1839.4(4),b= 1329.5(3), c = 1817.3(6)pm, β = 92.68(3)°, Z = 4, [EtMe2PhN]3[Bi2l9], ], S.G . P21/c, No. 14, a = 1915.3(2), b = 1379.0(3), c = 1890.9(5) pm, β = 92.48(1)°, Z = 4. The thermal behaviour was investigated with the aid of DSC measurements and temperature dependent X-ray powder diffraction. All compounds undergo a transition into a high temperature modification which could be obtained in case of [EtMe2PhN]3[Bi2Br9-xIx] in form of single crystals: S.G . P21/c, Nr. 14, a = 1002.7(5), b = 1278.7 (8), c = 3584.3(5) pm, β = 90.12(2)°, Z = 4. Surprisingly in this compound the iodine atoms are not statistically distributed over all possible bromine positions, but occupy only one position. Lattice parameters of the other high temperature modifications and enthalpies of transition of the compounds are given. In addition a second iodobismuthate was isolated:[EtMe2PhN]4[Bi6l22], S.G . P1̄, Nr. 2 , with lattice parameters of a = 1343.4(3), b = 1554.3(3), c = 2262.5(6) pm, a = 100.89(3)°, β = 96.63(1)°, 7 = 98.94(2)° and Z = 2.

: Bismuth; Tris(ethyldimethylphenylammonium) nonachlorodibismuthate; Tris(ethyldimethylphenylammonium) nonabromodibismuthate; Tris(ethyldimethylphenylammonium) nonaiododibismuthate; Enthalpy of Transition
Received: 1998-8-7
Published Online: 2014-6-2
Published in Print: 1999-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Synthese, Struktur und Reaktivität von 3-Triorganostannyl-N-diphenylmethylen-alaninestern / Synthesis, Structure and Reactivity of 3-Triorganostannyl-N-diphenylmethylenealanine Esters
  2. Metal Complexes of Biologically Important Ligands, CX. Orthopalladation of N-(Diphenylmethylene) Schiff Bases from Peptide Esters - C,N versus C,N,O Coordination - Crystal Structure of ClPd[C6H4(C6H5)C=N(Gly-L-Pro -L-Ala-OMe)-C,N,O] with cis/trans Peptide Bonds
  3. Tris(ethyldimethylphenylammonium) nonahalogenodibismuthates(III)
  4. 2.4.6-Tri-tert-butylphenylaminofluorsilane und Lithium-bis(2,4,6-tri tert- butylphenyldifluorsilyl)amid - im Kristall ein Polymer / 2.4.6-Tri-tert-butylphenylaminofluorosilanes and Lithium-bis(2,4,6-tri-tert-butylphenyldifluorosilyl) amide - in the Crystal a Polymer
  5. Komplexe zweier vierzehngliedriger Tetraazadibenzo-Makrocyclen. Strukturen eines freien Liganden und von Nickel(II)-, Kupfer(II)- und Zink(II)-Komplexen / Complexes of Two 14-Membered N4 Dibenzo Macrocycles. Crystal Structures of a Free Ligand and of Nickel(II), Copper(II) and Zinc(II) Complexes
  6. Metallkomplexe mit 2,2'-Dipyridylamin als Liganden: Kristallstrukturen der Komplexe mit CdX2 (X = Cl, Br, I) und CuCN / Metal Complexes with 2,2'-Dipyridylamine as Ligand: Crystal Structures of the Complexes with CdX2 (X = Cl, Br, I) and CuCN
  7. Copper Complexes with the Ligand [Cp2MoH2]
  8. Synthesis and Spectroscopic Properties of 1,2-Diiminetricarbonylrhenium( I)chloride Complexes with Aliphatic Diimines (or 1,4-Diaza-1,3-butadienes) as Ligands
  9. Hexahydro-closo-hexaborate as a Ligand in Coordination Compounds: A Second Polymorph of [Au2(μ-bis-η3-B6H6)(PPh3)2]
  10. Darstellung und spektroskopische Charakterisierung von Methylnitro-closo-hexaboraten sowie Kristallstrukturen von cis-(Ph4As)2[B6H4(CH3)(NO2)],fac-(Ph4As)2[B6H3(CH3)(NO2)2] · CH3CN und mer-(Ph4P)2[B6H3(CH3)(NO2)C2] / Synthesis and Spectroscopic Characterization of Methylnitro-closo-hexaborates and Crystal Structures of cis -(Ph4As)2[B6H4(CH3)(NO2)],fac-(Ph4As)2[B6H3(CH3)(NO2)2] · CH3CN and mer-(Ph4P)2[B6H3(CH3)(NO2)C2]
  11. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalyse von cis- und trans-[ReCl4 (NCSe)(SeCN)]2- / Crystal Structures, Vibrational Spectra, and Normal Coordinate Analysis of cis- and trans-[ReCl4 (NCSe)(SeCN)]2-
  12. Synthese, Struktur und Reaktivität von 2-Amino- und 2-Imino-2,3-dihydro-1H-1,3,2-diazaborolen / Synthesis, Structure and Reactivity of 2-Amino- and 2-Imino-2,3-dihydro-1H-1,3,2-diazaboroles
  13. Kristallstruktur und thermische Phasenumwandlung von Tetramethylammoniumcyanid, (CH3)4N+CN- / Crystal Structure and Thermal Phase Transition of Tetramethylammonium Cyanide, (CH3)4N+CN-
  14. Kristallstruktur von Hydrogenoxonium-Hexachloroantimonat-Bisacetonitril / Crystal Structure of Hydrogenoxonium Hexachloroantimonate-Bisacetonitrile
  15. Synthese und Kristallstruktur von [Au(AuNCO)(AuPPh3)8]Cl / Synthesis and Crystal Structure of [Au(AuNCO)(AuPPh3)8]Cl
  16. Metallkomplexe mit biologisch wichtigen Liganden, CXV. Addition von α-Aminosäureestern an [CpFe(CO)3]+: Carbamoylkomplexe Cp(OC)2Fe-C(O)NHCHRCO2R’ und Kristallstruktur von Cp(OC)2Fe-C(O)NHCH2CO2Et / Metal Complexes of Biologically Important Ligands, CXV. Addition of α-Amino Acid Esters to [CpFe(CO)3]+: Carbamoyl Complexes Cp(OC)2Fe-C(O)NHCHRCO2R' and Crystal Structure of Cp(OC)2Fe-C(O)NHCH2CO2Et
  17. Structure of a Cs(18-crown-6)N(CN)2 · H2O Complex: Assembly of the Dimeric 2:2 Anion Paired Encapsulate by Means of μ2-Bridging Water Molecules
  18. Direct Oxidative Deprotection of Trimethylsilyl and Tetrahydropyranyl Ethers Using Alumina-Supported lodobenzene Diacetate under Non-Aqueous Conditions
  19. Untersuchungen zur Trifluoracetylierung der Methylderivate von Tryptamin und Serotonin mit verschiedenen Derivatisierungsreagentien: Synthesen, Spektroskopie sowie analytische Trennungen mittels Kapillar-GC / Trifluoroacetylation of Methylated -Derivatives of Tryptamine and Serotonine by Different Reagents: Synthesis, Spectroscopic Characterizations, and Separations by C apillary-Gas-Chromatography
  20. Isoperadione: A New Triterpenoid from Salvia bucharica
  21. Synthese von muscarinanalogen Epoxiden aus Campholenund Fencholenverbindungen / Synthesis of Muscarin Analogue Epoxides from Campholenic and Fencholenic Compounds
  22. 2.2..5.5,-Tetra-tert-butyl-3,3’-bis(trimethylsilyl)-1,1’-diazacobaltocen / 2.2..5.5,-Tetra-tert-butyl-3,3’-bis(trimethylsilyl)-1,1’-diazacobaltocene
https://doi.org/10.1515/znb-1999-0303

Articles in the same Issue

  1. Synthese, Struktur und Reaktivität von 3-Triorganostannyl-N-diphenylmethylen-alaninestern / Synthesis, Structure and Reactivity of 3-Triorganostannyl-N-diphenylmethylenealanine Esters
  2. Metal Complexes of Biologically Important Ligands, CX. Orthopalladation of N-(Diphenylmethylene) Schiff Bases from Peptide Esters - C,N versus C,N,O Coordination - Crystal Structure of ClPd[C6H4(C6H5)C=N(Gly-L-Pro -L-Ala-OMe)-C,N,O] with cis/trans Peptide Bonds
  3. Tris(ethyldimethylphenylammonium) nonahalogenodibismuthates(III)
  4. 2.4.6-Tri-tert-butylphenylaminofluorsilane und Lithium-bis(2,4,6-tri tert- butylphenyldifluorsilyl)amid - im Kristall ein Polymer / 2.4.6-Tri-tert-butylphenylaminofluorosilanes and Lithium-bis(2,4,6-tri-tert-butylphenyldifluorosilyl) amide - in the Crystal a Polymer
  5. Komplexe zweier vierzehngliedriger Tetraazadibenzo-Makrocyclen. Strukturen eines freien Liganden und von Nickel(II)-, Kupfer(II)- und Zink(II)-Komplexen / Complexes of Two 14-Membered N4 Dibenzo Macrocycles. Crystal Structures of a Free Ligand and of Nickel(II), Copper(II) and Zinc(II) Complexes
  6. Metallkomplexe mit 2,2'-Dipyridylamin als Liganden: Kristallstrukturen der Komplexe mit CdX2 (X = Cl, Br, I) und CuCN / Metal Complexes with 2,2'-Dipyridylamine as Ligand: Crystal Structures of the Complexes with CdX2 (X = Cl, Br, I) and CuCN
  7. Copper Complexes with the Ligand [Cp2MoH2]
  8. Synthesis and Spectroscopic Properties of 1,2-Diiminetricarbonylrhenium( I)chloride Complexes with Aliphatic Diimines (or 1,4-Diaza-1,3-butadienes) as Ligands
  9. Hexahydro-closo-hexaborate as a Ligand in Coordination Compounds: A Second Polymorph of [Au2(μ-bis-η3-B6H6)(PPh3)2]
  10. Darstellung und spektroskopische Charakterisierung von Methylnitro-closo-hexaboraten sowie Kristallstrukturen von cis-(Ph4As)2[B6H4(CH3)(NO2)],fac-(Ph4As)2[B6H3(CH3)(NO2)2] · CH3CN und mer-(Ph4P)2[B6H3(CH3)(NO2)C2] / Synthesis and Spectroscopic Characterization of Methylnitro-closo-hexaborates and Crystal Structures of cis -(Ph4As)2[B6H4(CH3)(NO2)],fac-(Ph4As)2[B6H3(CH3)(NO2)2] · CH3CN and mer-(Ph4P)2[B6H3(CH3)(NO2)C2]
  11. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalyse von cis- und trans-[ReCl4 (NCSe)(SeCN)]2- / Crystal Structures, Vibrational Spectra, and Normal Coordinate Analysis of cis- and trans-[ReCl4 (NCSe)(SeCN)]2-
  12. Synthese, Struktur und Reaktivität von 2-Amino- und 2-Imino-2,3-dihydro-1H-1,3,2-diazaborolen / Synthesis, Structure and Reactivity of 2-Amino- and 2-Imino-2,3-dihydro-1H-1,3,2-diazaboroles
  13. Kristallstruktur und thermische Phasenumwandlung von Tetramethylammoniumcyanid, (CH3)4N+CN- / Crystal Structure and Thermal Phase Transition of Tetramethylammonium Cyanide, (CH3)4N+CN-
  14. Kristallstruktur von Hydrogenoxonium-Hexachloroantimonat-Bisacetonitril / Crystal Structure of Hydrogenoxonium Hexachloroantimonate-Bisacetonitrile
  15. Synthese und Kristallstruktur von [Au(AuNCO)(AuPPh3)8]Cl / Synthesis and Crystal Structure of [Au(AuNCO)(AuPPh3)8]Cl
  16. Metallkomplexe mit biologisch wichtigen Liganden, CXV. Addition von α-Aminosäureestern an [CpFe(CO)3]+: Carbamoylkomplexe Cp(OC)2Fe-C(O)NHCHRCO2R’ und Kristallstruktur von Cp(OC)2Fe-C(O)NHCH2CO2Et / Metal Complexes of Biologically Important Ligands, CXV. Addition of α-Amino Acid Esters to [CpFe(CO)3]+: Carbamoyl Complexes Cp(OC)2Fe-C(O)NHCHRCO2R' and Crystal Structure of Cp(OC)2Fe-C(O)NHCH2CO2Et
  17. Structure of a Cs(18-crown-6)N(CN)2 · H2O Complex: Assembly of the Dimeric 2:2 Anion Paired Encapsulate by Means of μ2-Bridging Water Molecules
  18. Direct Oxidative Deprotection of Trimethylsilyl and Tetrahydropyranyl Ethers Using Alumina-Supported lodobenzene Diacetate under Non-Aqueous Conditions
  19. Untersuchungen zur Trifluoracetylierung der Methylderivate von Tryptamin und Serotonin mit verschiedenen Derivatisierungsreagentien: Synthesen, Spektroskopie sowie analytische Trennungen mittels Kapillar-GC / Trifluoroacetylation of Methylated -Derivatives of Tryptamine and Serotonine by Different Reagents: Synthesis, Spectroscopic Characterizations, and Separations by C apillary-Gas-Chromatography
  20. Isoperadione: A New Triterpenoid from Salvia bucharica
  21. Synthese von muscarinanalogen Epoxiden aus Campholenund Fencholenverbindungen / Synthesis of Muscarin Analogue Epoxides from Campholenic and Fencholenic Compounds
  22. 2.2..5.5,-Tetra-tert-butyl-3,3’-bis(trimethylsilyl)-1,1’-diazacobaltocen / 2.2..5.5,-Tetra-tert-butyl-3,3’-bis(trimethylsilyl)-1,1’-diazacobaltocene
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