Home Physical Sciences 1,2,4-Diazaphosphole und 1,2,4-DiazaarsoIe: Ringstruktur und Struktur wasserstoffbrücken-gebundener Paare und Helices/1,2,4-Diazaphospholes and 1,2,4-Diazaarsoles: Ring Structure and Structure of Hydrogen-Bonded Pairs and Helices
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1,2,4-Diazaphosphole und 1,2,4-DiazaarsoIe: Ringstruktur und Struktur wasserstoffbrücken-gebundener Paare und Helices/1,2,4-Diazaphospholes and 1,2,4-Diazaarsoles: Ring Structure and Structure of Hydrogen-Bonded Pairs and Helices

  • Kurt Polbom , Alfred Schmidpeter , Gottfried Märkl and Angela Willhalm
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 2

Among the large family of azaphospholes 1,2,4-diazaphospholes feature a particularly stable ring system. 3,5-Unsubstituted and 3,5-equally substituted 1,2,4-diazaphospholes and -diazaarsoles are best made from 1,3-bis(dimethylamino)-2-phospha/arsaallyl chlorides and hydrazines. This way four examples for single crystal X-ray structure investigations were prepared: The unsubstituted 1,2,4-diazaphosphole 2 and -diazaarsole 4, the N-substituted 1 -(2-pyridyl) 1.2.4-diazaphosphole 1, and the C-substituted 3,5-di-tert-butyl 1,2,4-diazaphosphole 3. They all possess planar rings with small angles at P (86°) and As (81°). The N-unsubstituted molecules are connected to each other by NH···N hydrogen bonds forming in case of the isotypic compounds 2 and 4 a helix along a crystallographic axis and in case of compound 3 for steric reasons a dimer. The structures of the aggregates found are compared to those of pyrazoles.

Keywords : Phosphaarenes; Arsaarenes; Hydrogen Bonds; Pyrazoles
Received: 1998-8-12
Published Online: 2014-6-2
Published in Print: 1999-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  1. Synthesis, Spectroscopy and Structure of Diorganotin(IV) Schiff Base Complexes
  2. NMR-spektroskopische Untersuchungen zur Hydrolyse von funktionellen Trialkoxysilanen/ NMR-Spectroscopic Investigations on the Hydrolysis of Functional Trialkoxysilanes
  3. Synthese, Struktur- und EPR-Untersuchungen an Bis(tetraphenylphosphonium)- bis(1,2-dithioquadratato)oxovanadat(IV), (Ph4P)2[VO(dtsq)2]/Synthesis, Structural and EPR Investigations on Bis(tetraphenylphosphonium)- bis(1,2-dithiosquarato)oxovanadate(IV), (Ph4P)2 [VO(dtsq)2]
  4. 3-Hexyne Complexes of Molybdenum(II) and Tungsten(II). Crystal Structures of [WI2(CO)(PPh3 )2 (η2-EtC2 Et)] and [WI2(CO){Ph2P(CH2)3PPh2}(η2-EtC2Et)]
  5. Synthese und Aggregatbildung eines 5-Hydroxy-2,5-dihydropyrrols. Enantiomerenreine, eindimensionale Stränge durch Wasserstoffbrückenbindungen und chiroselektive Selbstorganisation/Synthesis and Aggregation of a 5-H ydroxy-2,5-dihydropyrrole. Enantiomerically Pure, One-dimensional Strands via Hydrogen Bonds and Chiroselective Self Organization
  6. 1,2,4-Diazaphosphole und 1,2,4-DiazaarsoIe: Ringstruktur und Struktur wasserstoffbrücken-gebundener Paare und Helices/1,2,4-Diazaphospholes and 1,2,4-Diazaarsoles: Ring Structure and Structure of Hydrogen-Bonded Pairs and Helices
  7. Solvation Structure of Solvated Cu(I) Ions in Non-Aqueous Solvents as Studied by EXAFS and ab initio Molecular Orbital Methods
  8. Neue dikationische Silicium-Komplexe mit N-Methylimidazol/New Dicationic Silicon Complexes with N-Methylimidazole
  9. Metal Complexes of Heteroarenes, X [1].η1-Coordination of Phosphinine: Synthesis and Structure of cis-Dichloro-bis(2,6-dimethyl-4-phenyl-phosphinine)platinum
  10. Cyclisierungen über Enamin-Zwischenstufen bei Amindehydrierungen/Cyclizations via Enamine Intermediates with Amine Dehydrogenations
  11. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 1. Mitteilung. N-(Nitrophenyl)-substituierte Verbindungen/Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 1st Communication. N-(Nitrophenyl) Substituted Compounds
  12. Untersuchungen zum quasibinären System Bi2Te3/BiCl3/Investigations on the Pseudobinary System Bi2Te3/BiCl3
  13. Thermochemische Untersuchungen zum ternären System Bi/Se/O. II. Das Teilsystem Bi2O3– SeO2/Thermochemical Investigations on the Ternary System Bi/Se/O.II.The Binary System Bi2O3–SeO2
  14. Untersuchungen zum ternären System Bi/Te/O, III. Bestimmung thermodynamischer Daten der ternären Verbindungen/Investigations on the Ternary System Bi/Te/O,III. Determination of Thermodynamic Data of Ternary Compounds
  15. Thermochemische Untersuchungen am System Bi/Se/O III. Zum quasibinären System Bi2O3 –Bi2Se3 und zum ternären Bereich Bi2O3– Bi2O2Se – Se – SeO2/Thermochemical Investigations on the System Bi/Se/O III.The Quasy Binary System Bi2O3-Bi2Se3and the Ternary Range Bi2O3-Bi2O2Se–Se–SeO2
  16. Zur Darstellung von Organosiliciumpolymeren mit (-SiH2-)n-Gnippen/Synthesis of Organosilicon Polymers Containing ( – SiH2- )n-Units
  17. Synthese und Reaktionsverhalten von Stannyloligosilanen, I. Kettenförmige Stannyloligosilane mit SiMe2-Einheiten/Synthesis and Reactivity of Stannyloligosilanes, I. Stannyloligosilane Chains Containing SiMe2 Moieties
  18. Die Kristallstrukturen von Tetraphenylphosphonium- octahalogenodiarsenat( III) und -diantimonat(III) mit Acetonitril, (PPh4)2[E2X8] · CH3CN (E = As, Sb; X = CI, Br)/The Crystal Structures of Tetraphenylphosphonium Octahalogenodiarsenate (III) and Diantimonate (III) with Acetonitrile, (PPh4)2[E2X8]·CH3CN(E=As, Sb; X=Cl, Br)
  19. ERRATUM
https://doi.org/10.1515/znb-1999-0206
Keywords for this article
Phosphaarenes; Arsaarenes; Hydrogen Bonds; Pyrazoles

Articles in the same Issue

  1. Synthesis, Spectroscopy and Structure of Diorganotin(IV) Schiff Base Complexes
  2. NMR-spektroskopische Untersuchungen zur Hydrolyse von funktionellen Trialkoxysilanen/ NMR-Spectroscopic Investigations on the Hydrolysis of Functional Trialkoxysilanes
  3. Synthese, Struktur- und EPR-Untersuchungen an Bis(tetraphenylphosphonium)- bis(1,2-dithioquadratato)oxovanadat(IV), (Ph4P)2[VO(dtsq)2]/Synthesis, Structural and EPR Investigations on Bis(tetraphenylphosphonium)- bis(1,2-dithiosquarato)oxovanadate(IV), (Ph4P)2 [VO(dtsq)2]
  4. 3-Hexyne Complexes of Molybdenum(II) and Tungsten(II). Crystal Structures of [WI2(CO)(PPh3 )2 (η2-EtC2 Et)] and [WI2(CO){Ph2P(CH2)3PPh2}(η2-EtC2Et)]
  5. Synthese und Aggregatbildung eines 5-Hydroxy-2,5-dihydropyrrols. Enantiomerenreine, eindimensionale Stränge durch Wasserstoffbrückenbindungen und chiroselektive Selbstorganisation/Synthesis and Aggregation of a 5-H ydroxy-2,5-dihydropyrrole. Enantiomerically Pure, One-dimensional Strands via Hydrogen Bonds and Chiroselective Self Organization
  6. 1,2,4-Diazaphosphole und 1,2,4-DiazaarsoIe: Ringstruktur und Struktur wasserstoffbrücken-gebundener Paare und Helices/1,2,4-Diazaphospholes and 1,2,4-Diazaarsoles: Ring Structure and Structure of Hydrogen-Bonded Pairs and Helices
  7. Solvation Structure of Solvated Cu(I) Ions in Non-Aqueous Solvents as Studied by EXAFS and ab initio Molecular Orbital Methods
  8. Neue dikationische Silicium-Komplexe mit N-Methylimidazol/New Dicationic Silicon Complexes with N-Methylimidazole
  9. Metal Complexes of Heteroarenes, X [1].η1-Coordination of Phosphinine: Synthesis and Structure of cis-Dichloro-bis(2,6-dimethyl-4-phenyl-phosphinine)platinum
  10. Cyclisierungen über Enamin-Zwischenstufen bei Amindehydrierungen/Cyclizations via Enamine Intermediates with Amine Dehydrogenations
  11. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 1. Mitteilung. N-(Nitrophenyl)-substituierte Verbindungen/Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 1st Communication. N-(Nitrophenyl) Substituted Compounds
  12. Untersuchungen zum quasibinären System Bi2Te3/BiCl3/Investigations on the Pseudobinary System Bi2Te3/BiCl3
  13. Thermochemische Untersuchungen zum ternären System Bi/Se/O. II. Das Teilsystem Bi2O3– SeO2/Thermochemical Investigations on the Ternary System Bi/Se/O.II.The Binary System Bi2O3–SeO2
  14. Untersuchungen zum ternären System Bi/Te/O, III. Bestimmung thermodynamischer Daten der ternären Verbindungen/Investigations on the Ternary System Bi/Te/O,III. Determination of Thermodynamic Data of Ternary Compounds
  15. Thermochemische Untersuchungen am System Bi/Se/O III. Zum quasibinären System Bi2O3 –Bi2Se3 und zum ternären Bereich Bi2O3– Bi2O2Se – Se – SeO2/Thermochemical Investigations on the System Bi/Se/O III.The Quasy Binary System Bi2O3-Bi2Se3and the Ternary Range Bi2O3-Bi2O2Se–Se–SeO2
  16. Zur Darstellung von Organosiliciumpolymeren mit (-SiH2-)n-Gnippen/Synthesis of Organosilicon Polymers Containing ( – SiH2- )n-Units
  17. Synthese und Reaktionsverhalten von Stannyloligosilanen, I. Kettenförmige Stannyloligosilane mit SiMe2-Einheiten/Synthesis and Reactivity of Stannyloligosilanes, I. Stannyloligosilane Chains Containing SiMe2 Moieties
  18. Die Kristallstrukturen von Tetraphenylphosphonium- octahalogenodiarsenat( III) und -diantimonat(III) mit Acetonitril, (PPh4)2[E2X8] · CH3CN (E = As, Sb; X = CI, Br)/The Crystal Structures of Tetraphenylphosphonium Octahalogenodiarsenate (III) and Diantimonate (III) with Acetonitrile, (PPh4)2[E2X8]·CH3CN(E=As, Sb; X=Cl, Br)
  19. ERRATUM
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