Home Physical Sciences Synthese und Kristallstruktur der Benzyltriphenylphosphonium-bromide: [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 und [C6H5-CH2P(C6H5)3]+Br3- / Synthesis and Crystal Structures of (Benzyl)triphenylphosphonium Bromides, [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 and [C6H5-CH2P(C6H5)3]+Br3-
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Synthese und Kristallstruktur der Benzyltriphenylphosphonium-bromide: [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 und [C6H5-CH2P(C6H5)3]+Br3- / Synthesis and Crystal Structures of (Benzyl)triphenylphosphonium Bromides, [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 and [C6H5-CH2P(C6H5)3]+Br3-

  • J. Hübner , D. Wulff-Molder , H. Vogt and M. Meisel
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 11

(Benzyl)triphenylphosphonium bromide, [C6H5-CH2P(C6H5)3]+Br- (CH2Cl2) (1) has been prepared by the reaction of triphenylphosphine with benzylbromide and its structure determined. The colorless crystals are triclinic, space group P1̄, Z = 2, a = 976.0(3), b = 1069.0(3), c = 1226.1(4) pm, α = 94.13(3), β = 104.70(3), γ = 100.14(3)°. The lattice contains Br- anions and [C6H5-CH2P(C6H5)3]+ cations. [C6H5-CH2P(C6H5)3]Br3 (2) has been obtained by treating compound 1 with equimolar quantities of elemental bromine in methylene chloride solution. The red crystals of 2 are monoclinic, space group P21/c, Z = 4, a = 917.9(2), b = 1022.6(2), c = 2573.6(5) pm, β = 99.11(2)°, and comprise[C6H5-CH2P(C6H5)3]+ cations and linear, slightly asymmetrical Br3- anions with bromine-bromine distances of 246.19(11) and 263.69(11) pm.

: (Benzyl)triphenylphosphonium Bromides; Synthesis; Crystal Structure; Triphenylphosphine
Received: 1997-8-12
Published Online: 2014-6-2
Published in Print: 1997-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Oxotitan-Addukte mit Dimethylsulfoxid: [TiO(OSMe2)5]Cl2 und [Ti4O6(OSMe2)12]Cl4 · 5Me2SO · 1/2 H2O / Oxotitanium Compounds with Dimethylsulfoxide: [TiO(OSMe2)5]Cl2 and [Ti4O6(OSMe2)12]Cl4 · 5Me2SO · 1/2 H2O
  2. Reaktionen von Cadmium-und Quecksilber(II)halogeniden und -pseudohalogeniden mit Kronenethern: Kristallstrukturen der Komplexe von Benzo-18-krone-6 mit CdX2 und HgX2 (X = CI, Br) und von Dibenzo-18-krone-6 mit Hg(CN)2 / Reactions of Cadmium and Mercury(II) Halides and Pseudohalides with Crown Ethers: Crystal Structures of the Complexes of Benzo-18-crown-6 with CdX2 and HgX2 (X = Cl, Br) and of Dibenzo-18-crown-6 with Hg(CN)2
  3. [H2⊂(Mov2O4)6O4(μ2-OH)12(MoVIO3)4]6- and [Na⊂{(MoV2O4)3(μ2-OH)3H(PhP03)4}2]7-: A Further Example for the Validity of the Concept of Unit Construction in Polyoxometalate Chemistry
  4. Kristallstruktur von Bromnitrat BrONO2 / Crystal Structure of Bromine Nitrate BrONO2
  5. Crystal Structure of an Ammonium Dithiocyanatocuprate(I) Complex with 18-Crown-6, [NH4(18-Crown-6){Cu(NCS)2}] Obtained from Zero Valent Metal
  6. Donor-stabilisierte Trisalkinylborane. Kristallstruktur von H5C5N–B(C≡CH)3 und Elektronenstruktur von B(C≡CH)3 / Donor-Stabilized Trisalkinylboranes. Crystal Structure of H5C5N–B (C≡CH)3 and Electronic Structure of B(C≡CH)3
  7. Synthese und Kristallstruktur der Benzyltriphenylphosphonium-bromide: [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 und [C6H5-CH2P(C6H5)3]+Br3- / Synthesis and Crystal Structures of (Benzyl)triphenylphosphonium Bromides, [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 and [C6H5-CH2P(C6H5)3]+Br3-
  8. Nickel(II)-Tyrosine-and -Tryptophan-Nucleobase Ternary Complexes
  9. Crystal and Molecular Structures of N,N'-Diphenyl-N"-trichloroacetyl- phosphorictriamide and N,N,-Tetraethyl-N"-benzoylphosphorictriamide. The Effect of Various Substituents on the Structural Parameters of the [C(O)N(H)P(O)] Moiety
  10. Die Struktur von GaAsO4 ·2H2O : Ein neues Mitglied der Variscit-Familie / The Structure of GaAsO4·2H2O : A New Member of the Variscite Family
  11. Planare CuO4-Polygone und eine einseitig offene Te4+O3-Koordination in SrCuTe2O6 / Planar CuO4 Polygons and a One-Sided Open Te4+O3 Coordination in SrCuTe2O6
  12. Contribution to the Chemistry of Boron, 241. Improved Synthesis of 2,4,6-Trichloroborazine
  13. Die Kristallstrukturen der isotypen Erdalkalimetall-Nitridowolfra- mat(VI)-Nitrid-Oxide Ca51[WN4]12N8O3 und Sr51[WN4]12N8O3 / The Crystal Structures of the Isotypic Alkaline Earth-Nitridotungstate(VI)- Nitride-OxidesCa51[WN4]12N8O3 and Sr51[WN4]12N8O3
  14. Oxyfunctionalization of Allyl Thioether Ruthenium Complexes with Dimethyldioxirane
  15. Prediction of Dissociation Constants of Ammonium Ion in 20 Mass % Ethanol + Water Mixed Solvent Solutions Containing Sodium Chloride
  16. Synthesis of N-(2-Phenyl-cyclopropyI)-Substituted Nucleoside Analogues
  17. Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction, Part I
  18. Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction, Part II
  19. A Convenient One-Pot Synthesis of Pyrazolo[3,4-d]pyrimidines and s-Triazolo[3,4-b][1,3,5]thiadiazines
  20. Isolation and Characterization of 1-Tigloyl-3-acetylazadirachtol from the Seed Kernels of the Thai Neem Azadirachta siamensis Valeton
  21. ab initio MO Optimization of Molecular Structures of Fluoro- and Chloro-Substituted Dibenzo-p-dioxines and the Effect of Halogen Substitution at the 2,3,7,8-Positions on Metabolic Attack
  22. Rb[B2P2O8(OH)] und Cs[B2P2O8(OH )]: Die ersten Borophosphate mit dreidimensional vernetzter Anionenteilstruktur /Rb[B2P2O8(OH)] and Cs[B2P2O8(OH )]: The First Borophosphates with a Threedimensional Anionic Tetrahedral Structure
  23. Asymmetrische Katalysen, 116. Triaza-und Tetraaza-Makrocyclen mit chiralen "pendant arms" in der enantio- selektiven Cyclopropanierung / Asymmetrie Catalyses, 116. Triaza and Tetraaza Macrocycles with Chiral Pendant Arms in the Enantioselective Cyclopropanation
https://doi.org/10.1515/znb-1997-1107

Articles in the same Issue

  1. Oxotitan-Addukte mit Dimethylsulfoxid: [TiO(OSMe2)5]Cl2 und [Ti4O6(OSMe2)12]Cl4 · 5Me2SO · 1/2 H2O / Oxotitanium Compounds with Dimethylsulfoxide: [TiO(OSMe2)5]Cl2 and [Ti4O6(OSMe2)12]Cl4 · 5Me2SO · 1/2 H2O
  2. Reaktionen von Cadmium-und Quecksilber(II)halogeniden und -pseudohalogeniden mit Kronenethern: Kristallstrukturen der Komplexe von Benzo-18-krone-6 mit CdX2 und HgX2 (X = CI, Br) und von Dibenzo-18-krone-6 mit Hg(CN)2 / Reactions of Cadmium and Mercury(II) Halides and Pseudohalides with Crown Ethers: Crystal Structures of the Complexes of Benzo-18-crown-6 with CdX2 and HgX2 (X = Cl, Br) and of Dibenzo-18-crown-6 with Hg(CN)2
  3. [H2⊂(Mov2O4)6O4(μ2-OH)12(MoVIO3)4]6- and [Na⊂{(MoV2O4)3(μ2-OH)3H(PhP03)4}2]7-: A Further Example for the Validity of the Concept of Unit Construction in Polyoxometalate Chemistry
  4. Kristallstruktur von Bromnitrat BrONO2 / Crystal Structure of Bromine Nitrate BrONO2
  5. Crystal Structure of an Ammonium Dithiocyanatocuprate(I) Complex with 18-Crown-6, [NH4(18-Crown-6){Cu(NCS)2}] Obtained from Zero Valent Metal
  6. Donor-stabilisierte Trisalkinylborane. Kristallstruktur von H5C5N–B(C≡CH)3 und Elektronenstruktur von B(C≡CH)3 / Donor-Stabilized Trisalkinylboranes. Crystal Structure of H5C5N–B (C≡CH)3 and Electronic Structure of B(C≡CH)3
  7. Synthese und Kristallstruktur der Benzyltriphenylphosphonium-bromide: [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 und [C6H5-CH2P(C6H5)3]+Br3- / Synthesis and Crystal Structures of (Benzyl)triphenylphosphonium Bromides, [C6H5-CH2P(C6H5)3]+Br-CH2Cl2 and [C6H5-CH2P(C6H5)3]+Br3-
  8. Nickel(II)-Tyrosine-and -Tryptophan-Nucleobase Ternary Complexes
  9. Crystal and Molecular Structures of N,N'-Diphenyl-N"-trichloroacetyl- phosphorictriamide and N,N,-Tetraethyl-N"-benzoylphosphorictriamide. The Effect of Various Substituents on the Structural Parameters of the [C(O)N(H)P(O)] Moiety
  10. Die Struktur von GaAsO4 ·2H2O : Ein neues Mitglied der Variscit-Familie / The Structure of GaAsO4·2H2O : A New Member of the Variscite Family
  11. Planare CuO4-Polygone und eine einseitig offene Te4+O3-Koordination in SrCuTe2O6 / Planar CuO4 Polygons and a One-Sided Open Te4+O3 Coordination in SrCuTe2O6
  12. Contribution to the Chemistry of Boron, 241. Improved Synthesis of 2,4,6-Trichloroborazine
  13. Die Kristallstrukturen der isotypen Erdalkalimetall-Nitridowolfra- mat(VI)-Nitrid-Oxide Ca51[WN4]12N8O3 und Sr51[WN4]12N8O3 / The Crystal Structures of the Isotypic Alkaline Earth-Nitridotungstate(VI)- Nitride-OxidesCa51[WN4]12N8O3 and Sr51[WN4]12N8O3
  14. Oxyfunctionalization of Allyl Thioether Ruthenium Complexes with Dimethyldioxirane
  15. Prediction of Dissociation Constants of Ammonium Ion in 20 Mass % Ethanol + Water Mixed Solvent Solutions Containing Sodium Chloride
  16. Synthesis of N-(2-Phenyl-cyclopropyI)-Substituted Nucleoside Analogues
  17. Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction, Part I
  18. Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction, Part II
  19. A Convenient One-Pot Synthesis of Pyrazolo[3,4-d]pyrimidines and s-Triazolo[3,4-b][1,3,5]thiadiazines
  20. Isolation and Characterization of 1-Tigloyl-3-acetylazadirachtol from the Seed Kernels of the Thai Neem Azadirachta siamensis Valeton
  21. ab initio MO Optimization of Molecular Structures of Fluoro- and Chloro-Substituted Dibenzo-p-dioxines and the Effect of Halogen Substitution at the 2,3,7,8-Positions on Metabolic Attack
  22. Rb[B2P2O8(OH)] und Cs[B2P2O8(OH )]: Die ersten Borophosphate mit dreidimensional vernetzter Anionenteilstruktur /Rb[B2P2O8(OH)] and Cs[B2P2O8(OH )]: The First Borophosphates with a Threedimensional Anionic Tetrahedral Structure
  23. Asymmetrische Katalysen, 116. Triaza-und Tetraaza-Makrocyclen mit chiralen "pendant arms" in der enantio- selektiven Cyclopropanierung / Asymmetrie Catalyses, 116. Triaza and Tetraaza Macrocycles with Chiral Pendant Arms in the Enantioselective Cyclopropanation
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