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Darstellung, Kristallstruktur und Schwingungsspektren von Rubidiumperoxoniobat (Rb3NbO8) / Preparation, Crystal Structure, and Vibrational Spectra of Rubidiumperoxoniobate (Rb3NbO8)

  • H. Haeuseler , M. Wagener and H. Müller
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 9

Abstract

The crystal structure of Rb3NbO8 (SG I4̅2m, Nr. 121) has been determined on single crystals to a final R = 0.041. The structure is isotypic to the K3CrO8 type. Vibrational spectra of the title compound have been recorded on powdered samples and are discussed with respect to the internal vibrations of the peroxo-group and the dodecahedral NbO83- ion. The stretching vibrations of the O22- groups are found at 838 (Raman) and 813 cm- 1(IR). A factor group analysis for the K3CrO8 type is given.

Keywords: Rubidiumperoxoniobate; Vibrational Spectra; Preparation
Received: 1997-6-23
Published Online: 2014-6-2
Published in Print: 1997-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  2. Darstellung und Kristallstrukturanalyse von K3BiO3 und Rb3BiO3 / Synthesis and Crystal Structure Determination of K3BiO3 and Rb3BiO3
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  4. Synthese dreizähniger Liganden durch Spaltung von 3,5-Diphenyl-1,2-dithioliumsalzen mit (Thio)benzoylhydrazin oder 2-Hydroxy-5-methyl-anilin. Strukturen der gebildeten Nickelchelate / Synthesis of Tridentate Ligands by Cleavage of 3.5-Diphenyl-1.2-dithiolium Salts with (Thio)benzoylhydrazine or 2-Hydroxy-5-methyl-aniline. Structures of the Corresponding Nickel Chelates
  5. Synthese thermisch stabiler N-Silylformaldehyd-hydrazone / Synthesis of Thermally Stable N-Silylformaldehyde-Hydrazones
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  9. Weitere Verbindungen des Ba17Ln16Zn8Pt4O57- Typs mit Ln = Dy, Ho, Er, Y / More Compounds of the Ba17Ln16Zn8Pt4O57 Type with Ln = Dy, Ho, Er, Y
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  12. Darstellung, Kristallstruktur und Schwingungsspektren von Rubidiumperoxoniobat (Rb3NbO8) / Preparation, Crystal Structure, and Vibrational Spectra of Rubidiumperoxoniobate (Rb3NbO8)
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https://doi.org/10.1515/znb-1997-0912
Keywords for this article
Rubidiumperoxoniobate; Vibrational Spectra; Preparation

Articles in the same Issue

  1. Ternary Rare Earth Transition Metal Zinc Compounds RT2Zn20 with T = Fe, Ru, Co, Rh, and Ni
  2. Darstellung und Kristallstrukturanalyse von K3BiO3 und Rb3BiO3 / Synthesis and Crystal Structure Determination of K3BiO3 and Rb3BiO3
  3. Silyl Derivatives of the Mixed Sandwiches Cyclopentadienyl Manganese Benzene and Cyclopentadienyl Manganese Biphenyl, CpMn(C6H6) and CpMn(C6H5-Ph)
  4. Synthese dreizähniger Liganden durch Spaltung von 3,5-Diphenyl-1,2-dithioliumsalzen mit (Thio)benzoylhydrazin oder 2-Hydroxy-5-methyl-anilin. Strukturen der gebildeten Nickelchelate / Synthesis of Tridentate Ligands by Cleavage of 3.5-Diphenyl-1.2-dithiolium Salts with (Thio)benzoylhydrazine or 2-Hydroxy-5-methyl-aniline. Structures of the Corresponding Nickel Chelates
  5. Synthese thermisch stabiler N-Silylformaldehyd-hydrazone / Synthesis of Thermally Stable N-Silylformaldehyde-Hydrazones
  6. Die Kristallstrukturen von PHF4, PH2F3 und PHF2. Moden molekularer Packung bei tiefer Temperatur [1] / The Crystal Structures of PHF4, PH2F3 and PHF2. Molecular Packing Modes at Low Temperature
  7. Imidazolin-2-iminato-Derivate der Thiokohlensäure [1] / Imidazolin-2-iminato Derivatives of Thiourea [1]
  8. Calorimetrie an Lanthantrihalogeniden und Ammoniumlanthanhalogeniden / Calorimetry of Lanthanum Trihalides and of Ammonium Lanthanum Halides
  9. Weitere Verbindungen des Ba17Ln16Zn8Pt4O57- Typs mit Ln = Dy, Ho, Er, Y / More Compounds of the Ba17Ln16Zn8Pt4O57 Type with Ln = Dy, Ho, Er, Y
  10. Structure and Energy Spectra of Molecules Containing Anti-Aromatic Ring Systems. IV. Aromaticity and Anti-Aromaticity in Electronic Ground and Excited States
  11. Ligandenaustauschreaktionen von Molybdänhexacarbonyl mit dreizähnigen diaciden Liganden / Ligand Exchange Reactions of Molybdenum Hexacarbonyl with Tridentate Diacidic Ligands
  12. Darstellung, Kristallstruktur und Schwingungsspektren von Rubidiumperoxoniobat (Rb3NbO8) / Preparation, Crystal Structure, and Vibrational Spectra of Rubidiumperoxoniobate (Rb3NbO8)
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  14. Synthese, Kristallstrukturen und thermisches Verhalten von (trienH2)[Mn(H2O)3X 3]X . H2O (X=Cl,Br) / Synthesis, Crystal Structures and Thermal Behavior of (trienH2)[Mn(H2O)3X3]X . H2O (X=Cl,Br)
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  20. Preparation of Some New C19-Gibberellin Derivatives for Biochemical Studies
  21. On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
  22. [(N, N’, N”-Tricyclohexyl)-N”- cyclohexylcarbamoylguanidinium] Tetrachloroaurate(III) as a Product of the Reaction of Dicyclohexylcarbo- diimide with HAuCl4 . aq
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