Home Weitere Verbindungen des Ba17Ln16Zn8Pt4O57- Typs mit Ln = Dy, Ho, Er, Y / More Compounds of the Ba17Ln16Zn8Pt4O57 Type with Ln = Dy, Ho, Er, Y
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Weitere Verbindungen des Ba17Ln16Zn8Pt4O57- Typs mit Ln = Dy, Ho, Er, Y / More Compounds of the Ba17Ln16Zn8Pt4O57 Type with Ln = Dy, Ho, Er, Y

  • O. Sfreddo and Hk. Müller-Buschbaum
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 9

Abstract

Single crystals of Ba17Dy16Zn8Pt4O57 (I), Ba17Ho16Zn8Pt4O57 (II), Ba17Er16Zn8Pt4O57 (III) and Ba17YZn8Pt4O57 (IV) have been prepared by high temperature reactions using platinum crucibles. X-ray investigations led to tetragonal symmetry, space group C54h - I4/m, (I) - (IV): a = 22.905(1), 22.840(1), 22.795(1), 22.848(1) Å and c = 5.728(1), 5.722(1), 5.700(1), 5.709(1) Å,Z = 2. The crystal structure is characterized by small square, medium-sized quadrangular and large rectangular tunnels, which are filled by oxygen, barium and zinc. The polyhedra network is discussed with respect to the network of compounds of the Ba13Dy8Zn4Pt4O37 type.

Keywords: Barium; Rare Earth; Zinc; Platinum; Crystal Structure
Received: 1997-5-6
Published Online: 2014-6-2
Published in Print: 1997-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  1. Ternary Rare Earth Transition Metal Zinc Compounds RT2Zn20 with T = Fe, Ru, Co, Rh, and Ni
  2. Darstellung und Kristallstrukturanalyse von K3BiO3 und Rb3BiO3 / Synthesis and Crystal Structure Determination of K3BiO3 and Rb3BiO3
  3. Silyl Derivatives of the Mixed Sandwiches Cyclopentadienyl Manganese Benzene and Cyclopentadienyl Manganese Biphenyl, CpMn(C6H6) and CpMn(C6H5-Ph)
  4. Synthese dreizähniger Liganden durch Spaltung von 3,5-Diphenyl-1,2-dithioliumsalzen mit (Thio)benzoylhydrazin oder 2-Hydroxy-5-methyl-anilin. Strukturen der gebildeten Nickelchelate / Synthesis of Tridentate Ligands by Cleavage of 3.5-Diphenyl-1.2-dithiolium Salts with (Thio)benzoylhydrazine or 2-Hydroxy-5-methyl-aniline. Structures of the Corresponding Nickel Chelates
  5. Synthese thermisch stabiler N-Silylformaldehyd-hydrazone / Synthesis of Thermally Stable N-Silylformaldehyde-Hydrazones
  6. Die Kristallstrukturen von PHF4, PH2F3 und PHF2. Moden molekularer Packung bei tiefer Temperatur [1] / The Crystal Structures of PHF4, PH2F3 and PHF2. Molecular Packing Modes at Low Temperature
  7. Imidazolin-2-iminato-Derivate der Thiokohlensäure [1] / Imidazolin-2-iminato Derivatives of Thiourea [1]
  8. Calorimetrie an Lanthantrihalogeniden und Ammoniumlanthanhalogeniden / Calorimetry of Lanthanum Trihalides and of Ammonium Lanthanum Halides
  9. Weitere Verbindungen des Ba17Ln16Zn8Pt4O57- Typs mit Ln = Dy, Ho, Er, Y / More Compounds of the Ba17Ln16Zn8Pt4O57 Type with Ln = Dy, Ho, Er, Y
  10. Structure and Energy Spectra of Molecules Containing Anti-Aromatic Ring Systems. IV. Aromaticity and Anti-Aromaticity in Electronic Ground and Excited States
  11. Ligandenaustauschreaktionen von Molybdänhexacarbonyl mit dreizähnigen diaciden Liganden / Ligand Exchange Reactions of Molybdenum Hexacarbonyl with Tridentate Diacidic Ligands
  12. Darstellung, Kristallstruktur und Schwingungsspektren von Rubidiumperoxoniobat (Rb3NbO8) / Preparation, Crystal Structure, and Vibrational Spectra of Rubidiumperoxoniobate (Rb3NbO8)
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  19. Templat-Reaktionen von 3,5-Diphenyl-1,2-dithioliumchlorid mit (Thio)Benzoylhydrazin sowie Nickel- und Zinkacetat / Template Reactions of 3.5 - Diphenyl- 1.2-dithiolium Chloride with (Thio)Benzoylhydrazine and Nickel or Zinc Acetate
  20. Preparation of Some New C19-Gibberellin Derivatives for Biochemical Studies
  21. On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
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https://doi.org/10.1515/znb-1997-0909
Keywords for this article
Barium; Rare Earth; Zinc; Platinum; Crystal Structure

Articles in the same Issue

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  2. Darstellung und Kristallstrukturanalyse von K3BiO3 und Rb3BiO3 / Synthesis and Crystal Structure Determination of K3BiO3 and Rb3BiO3
  3. Silyl Derivatives of the Mixed Sandwiches Cyclopentadienyl Manganese Benzene and Cyclopentadienyl Manganese Biphenyl, CpMn(C6H6) and CpMn(C6H5-Ph)
  4. Synthese dreizähniger Liganden durch Spaltung von 3,5-Diphenyl-1,2-dithioliumsalzen mit (Thio)benzoylhydrazin oder 2-Hydroxy-5-methyl-anilin. Strukturen der gebildeten Nickelchelate / Synthesis of Tridentate Ligands by Cleavage of 3.5-Diphenyl-1.2-dithiolium Salts with (Thio)benzoylhydrazine or 2-Hydroxy-5-methyl-aniline. Structures of the Corresponding Nickel Chelates
  5. Synthese thermisch stabiler N-Silylformaldehyd-hydrazone / Synthesis of Thermally Stable N-Silylformaldehyde-Hydrazones
  6. Die Kristallstrukturen von PHF4, PH2F3 und PHF2. Moden molekularer Packung bei tiefer Temperatur [1] / The Crystal Structures of PHF4, PH2F3 and PHF2. Molecular Packing Modes at Low Temperature
  7. Imidazolin-2-iminato-Derivate der Thiokohlensäure [1] / Imidazolin-2-iminato Derivatives of Thiourea [1]
  8. Calorimetrie an Lanthantrihalogeniden und Ammoniumlanthanhalogeniden / Calorimetry of Lanthanum Trihalides and of Ammonium Lanthanum Halides
  9. Weitere Verbindungen des Ba17Ln16Zn8Pt4O57- Typs mit Ln = Dy, Ho, Er, Y / More Compounds of the Ba17Ln16Zn8Pt4O57 Type with Ln = Dy, Ho, Er, Y
  10. Structure and Energy Spectra of Molecules Containing Anti-Aromatic Ring Systems. IV. Aromaticity and Anti-Aromaticity in Electronic Ground and Excited States
  11. Ligandenaustauschreaktionen von Molybdänhexacarbonyl mit dreizähnigen diaciden Liganden / Ligand Exchange Reactions of Molybdenum Hexacarbonyl with Tridentate Diacidic Ligands
  12. Darstellung, Kristallstruktur und Schwingungsspektren von Rubidiumperoxoniobat (Rb3NbO8) / Preparation, Crystal Structure, and Vibrational Spectra of Rubidiumperoxoniobate (Rb3NbO8)
  13. Pressure Dependence of the Electrode Potentials of Some Iron(III/II), Cobalt(III/II), and Ni(III/II) Couples in Aqueous Solution: Estimation of the Reaction Volumes for M(III)/M(II) Couples
  14. Synthese, Kristallstrukturen und thermisches Verhalten von (trienH2)[Mn(H2O)3X 3]X . H2O (X=Cl,Br) / Synthesis, Crystal Structures and Thermal Behavior of (trienH2)[Mn(H2O)3X3]X . H2O (X=Cl,Br)
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  20. Preparation of Some New C19-Gibberellin Derivatives for Biochemical Studies
  21. On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
  22. [(N, N’, N”-Tricyclohexyl)-N”- cyclohexylcarbamoylguanidinium] Tetrachloroaurate(III) as a Product of the Reaction of Dicyclohexylcarbo- diimide with HAuCl4 . aq
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