Home Physical Sciences Darstellung, 11B-,13C-,1H-NMR- und Schwingungsspektren von Phenylundecahydro-closo-dodecaborat(2-) sowie Kristallstruktur von [As(C6H5)4]2[(C6H5)B12H11] / Preparation, 11B-, 13C-, 1H-NMR- and Vibrational Spectra of Phenylundecahydro-closo-dodecaborate(2-) and Crystal Structure of [As(C6H5)4]2[(C6H5)B12H11]
Article
Licensed
Unlicensed Requires Authentication

Darstellung, 11B-,13C-,1H-NMR- und Schwingungsspektren von Phenylundecahydro-closo-dodecaborat(2-) sowie Kristallstruktur von [As(C6H5)4]2[(C6H5)B12H11] / Preparation, 11B-, 13C-, 1H-NMR- and Vibrational Spectra of Phenylundecahydro-closo-dodecaborate(2-) and Crystal Structure of [As(C6H5)4]2[(C6H5)B12H11]

  • and
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 8

By reaction of [N(C4H9)4]2[B12H12] with chlorotriphenyltin at 170 °C the phenylundecahydro-closo-dodecaborate anion [(C6H5)B12H11]2- is formed which can be isolated by ion exchange chromatography on diethylaminoethyl(DEAE) cellulose. The crystal structure of [As(C6H5)4]2[(C6H5)B12H11] has been determined by single crystal X-ray diffraction analysis; triclinic, space group P1̄

with a = 11,0066(11), b = 11.1371(6), c = 22.236(2) Å, α = 93.040(6), β = 92.981(8), γ = 100.254(6)°, Z = 2. The 11B NMR spectrum reveals the features (1:5:5:1) of a monosubstituated B12 cage with the ipso B atom at - 6.1 and the antipodal B at -17.4 ppm. The 13C and 1H NMR spectra show the characteristic patterns of the phenyl group. The IR and Raman spectra exhibit characteristic BH stretching vibrations between 2464 and 2519 cm-1 and the CC stretching vibrations in the range of 1405 to 1592 cm-1.

Keywords: Phenylundecahydro-closo-dodecaborate(2-); Crystal Structure; 1H NMR Spectra; Vibrational Spectra
Received: 1997-5-2
Published Online: 2014-6-2
Published in Print: 1997-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Chlormethylchlorphosphane mit sperrigen Substituenten -Synthese und reduktive Enthalogenierung mit Fe2(CO)9 / Bulky Chloromethylchlorophosphines -Syntheses and Reductive Dehalogenation with Fe2 (CO)9
  2. Ein neues Verfahren zur numerischen Berechnung des Madelung-Anteils der Gitterenergie ionischer Kristalle / A New Method for the Numerical Calculation of the Madelung Contribution of the Lattice Energy in Ionic Crystals
  3. Synthesis and Crystal Structure of a Caesium Hydrogen Benzoylcyanoximate Complex with 18-Crown-6: Cs(18-Crown-6){H(L)2}
  4. Darstellung und Kristallstruktur von P4O8 / Preparation and Crystal Structure of P4O8
  5. Die Fulven-Route zum Pentaisopropylcyclopentadienid / The Fulvene Route to Pentaisopropylcyclopentadienide
  6. Synthese, Struktur-und EPR-Untersuchungen an 57Fe-markiertem Tetra-n-butylammonium-bis(1,1-dicyanoethen-2,2-dithiolato)nitrosyleisen(I), (n-Bu4N)2 [57Fe(NO)(i-mnt)2] / Synthesis, Structural, and EPR Investigations on 57Fe Enriched Tetra-n-butylammonium- bis(1,1-dicyanoethene-2,2-dithiolato)nitrosyliron(I), (n-Bu4N)2[57Fe(NO)(i-mnt)2]
  7. Hydrogenation of Toluene over La0.8Sr0.2Fe1-xCoxO3-z Perovskite Catalysts
  8. Darstellung, 11B-,13C-,1H-NMR- und Schwingungsspektren von Phenylundecahydro-closo-dodecaborat(2-) sowie Kristallstruktur von [As(C6H5)4]2[(C6H5)B12H11] / Preparation, 11B-, 13C-, 1H-NMR- and Vibrational Spectra of Phenylundecahydro-closo-dodecaborate(2-) and Crystal Structure of [As(C6H5)4]2[(C6H5)B12H11]
  9. Darstellung, 11B-, 1H-NMR und Schwingungsspektren von 4-Aminopyridylundecahydro-closo-dodecaborat(1-) sowie Kristallstruktur von (Ph4As)[(4-(NH)-C5H4N)B12H11]·2CH3CN / Synthesis, 11B , 1H NMR and Vibrational Spectra of 4-Aminopyridylundecahydro-closo- dodecaborate(1-) and Crystal Structure of (Ph4As)[(4-(NH)-C5H4N)B12H11]·2CH3CN
  10. A New Method for the Preparation of Ifosfamide and Cyclophosphamide
  11. N-Boryl-Substituted Bis(amino)stannylenes and -plumbylenes
  12. CuX (X = Br, I) Oligomers and Polymerie Chains in Tetramethylcyclotetra- arsoxane-Bridged Networks [CunXn{cyclo-(CH3AsO)4}2] (n = 4, 6, 8)
  13. Über die Bildung von N,N-Bistrifluormethylhydroxylammoniumsalzen (CF3)2N(X)OX+MF6- (X = H, D; M = As, Sb) / On the Formation of N,N-Bistrifluoromethylhydroxylammonium Salts (CF3)2N(X)OX+MF6- (X = H, D; M = As, Sb)
  14. Kristallstrukturen, Schwingungsspektren und Normalkoordinaten- analysen von cis- und trans-[OsX2(acac)2], X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of cis- and trans-[OsX2(acac)2], X = Cl, Br, I
  15. Darstellung und Kristallstruktur von [P(C6H5)4]2[2-SnCl2(C6H5)B10H9] / Synthesis and Crystal Structure of [P(C6H5)4]2 [2-SnCl2(C6H5)B10H9]
  16. Synthesis and Crystal Structure of Tetraphenylarsonium Pentachlorocarbonylosmate(IV), (Ph4As)[OsCl5(CO)]
  17. Kurze O-O-Abstände einer gemeinsamen Polyederkante bei Verknüpfung von PO4-Tetraedern mit VO6-Oktaedern im Vanadyl-Orthophosphat CaNi(VO)(PO4)2 / Short O-O Distances in Edge Sharing PO4 Tetrahedra and VO6 Octahedra of the Vanadyl- Orthophosphate CaNi(VO)(PO4)2
  18. SrZn(VO)(PO4)2 und BaCd(VO)(PO4)2: Zum BaZn(VO)(PO4)2-Typ verwandte, jedoch nicht isotype Vanadylphosphate / SrZn(VO)(PO4)2 and BaCd(VO)(PO4)2: Vanadylphosphates Related but not Isotypic to the BaZn(VO)(PO4 )2 Type
  19. Über ein cadmiumreiches Orthovanadat Ba2,5Cd11(VO4)9 mit Cadmium in oktaedrischer und tetragonal pyramidaler Koordination / On a Cadmium Rich Orthovanadate Ba2,5Cd11(VO4)9 Showing Cadmium in Octahedral and Square Pyramidal Coordination
  20. Transition Metal Complexes of Diazenes, XL [1] Iron Carbonyl Assisted Formation of Bicyclic 1,2-Dihydropyrazol-3-ones from Pyrazolines and Alkynes
  21. Polysulfonylamine, XC [1] Carbonsäure-Dimere, Wasser-Dimere und 18-Krone-6-Moleküle als Baugruppen eines supramolekularen Kettenpolymers: Darstellung und Struktur von (CH2CH2O)6 • 4H2O • 2HN(SO2C6H4-4-COOH)2 / Polysulfonylamines, XC [1] Carboxylic Acid Dimers, Water Dimers and 18-Crown-6 Molecules as Building Blocks in a Supramolecular Chain Polymer: Synthesis and Structure of (CH2CH2O)6 · 4H2O · 2HN(SO2C6H4-4-COOH)2
  22. Synthese und Eigenschaften von trans-Bisnitro-phthalocyaninato(2-)iridat(III) und Pyridin-nitro-phthalocyaninato(2-)iridium(III); Kristallstruktur von linear- Bis(triphenylphosphin)iminium-trans-Bisnitro-phthalocyaninato(2-)iridat(III) / Synthesis and Properties of trans-Bisnitro-phthalocyaninato(2-)iridate(III) and Pyridine-nitro-phthalocyaninato(2-)iridium(III); Crystal Structure of linear- Bis(triphenylphosphine)iminium trans-Bisnitro-phthalocyaninato(2-)iridate(III)
  23. Mehrkernige CpZr(IV)-und CpHf(IV)-Komplexe mit Oximatobrücken / Polynuclear CpZr(IV) and CpHf(IV) Complexes with Oximato Bridges
  24. Notizen: Determination of Signs of Coupling Constants for (Ethene)bis- (triphenylphosphane)platinum(0)
https://doi.org/10.1515/znb-1997-0808
Keywords for this article
Phenylundecahydro-closo-dodecaborate(2-); Crystal Structure; 1H NMR Spectra; Vibrational Spectra

Articles in the same Issue

  1. Chlormethylchlorphosphane mit sperrigen Substituenten -Synthese und reduktive Enthalogenierung mit Fe2(CO)9 / Bulky Chloromethylchlorophosphines -Syntheses and Reductive Dehalogenation with Fe2 (CO)9
  2. Ein neues Verfahren zur numerischen Berechnung des Madelung-Anteils der Gitterenergie ionischer Kristalle / A New Method for the Numerical Calculation of the Madelung Contribution of the Lattice Energy in Ionic Crystals
  3. Synthesis and Crystal Structure of a Caesium Hydrogen Benzoylcyanoximate Complex with 18-Crown-6: Cs(18-Crown-6){H(L)2}
  4. Darstellung und Kristallstruktur von P4O8 / Preparation and Crystal Structure of P4O8
  5. Die Fulven-Route zum Pentaisopropylcyclopentadienid / The Fulvene Route to Pentaisopropylcyclopentadienide
  6. Synthese, Struktur-und EPR-Untersuchungen an 57Fe-markiertem Tetra-n-butylammonium-bis(1,1-dicyanoethen-2,2-dithiolato)nitrosyleisen(I), (n-Bu4N)2 [57Fe(NO)(i-mnt)2] / Synthesis, Structural, and EPR Investigations on 57Fe Enriched Tetra-n-butylammonium- bis(1,1-dicyanoethene-2,2-dithiolato)nitrosyliron(I), (n-Bu4N)2[57Fe(NO)(i-mnt)2]
  7. Hydrogenation of Toluene over La0.8Sr0.2Fe1-xCoxO3-z Perovskite Catalysts
  8. Darstellung, 11B-,13C-,1H-NMR- und Schwingungsspektren von Phenylundecahydro-closo-dodecaborat(2-) sowie Kristallstruktur von [As(C6H5)4]2[(C6H5)B12H11] / Preparation, 11B-, 13C-, 1H-NMR- and Vibrational Spectra of Phenylundecahydro-closo-dodecaborate(2-) and Crystal Structure of [As(C6H5)4]2[(C6H5)B12H11]
  9. Darstellung, 11B-, 1H-NMR und Schwingungsspektren von 4-Aminopyridylundecahydro-closo-dodecaborat(1-) sowie Kristallstruktur von (Ph4As)[(4-(NH)-C5H4N)B12H11]·2CH3CN / Synthesis, 11B , 1H NMR and Vibrational Spectra of 4-Aminopyridylundecahydro-closo- dodecaborate(1-) and Crystal Structure of (Ph4As)[(4-(NH)-C5H4N)B12H11]·2CH3CN
  10. A New Method for the Preparation of Ifosfamide and Cyclophosphamide
  11. N-Boryl-Substituted Bis(amino)stannylenes and -plumbylenes
  12. CuX (X = Br, I) Oligomers and Polymerie Chains in Tetramethylcyclotetra- arsoxane-Bridged Networks [CunXn{cyclo-(CH3AsO)4}2] (n = 4, 6, 8)
  13. Über die Bildung von N,N-Bistrifluormethylhydroxylammoniumsalzen (CF3)2N(X)OX+MF6- (X = H, D; M = As, Sb) / On the Formation of N,N-Bistrifluoromethylhydroxylammonium Salts (CF3)2N(X)OX+MF6- (X = H, D; M = As, Sb)
  14. Kristallstrukturen, Schwingungsspektren und Normalkoordinaten- analysen von cis- und trans-[OsX2(acac)2], X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of cis- and trans-[OsX2(acac)2], X = Cl, Br, I
  15. Darstellung und Kristallstruktur von [P(C6H5)4]2[2-SnCl2(C6H5)B10H9] / Synthesis and Crystal Structure of [P(C6H5)4]2 [2-SnCl2(C6H5)B10H9]
  16. Synthesis and Crystal Structure of Tetraphenylarsonium Pentachlorocarbonylosmate(IV), (Ph4As)[OsCl5(CO)]
  17. Kurze O-O-Abstände einer gemeinsamen Polyederkante bei Verknüpfung von PO4-Tetraedern mit VO6-Oktaedern im Vanadyl-Orthophosphat CaNi(VO)(PO4)2 / Short O-O Distances in Edge Sharing PO4 Tetrahedra and VO6 Octahedra of the Vanadyl- Orthophosphate CaNi(VO)(PO4)2
  18. SrZn(VO)(PO4)2 und BaCd(VO)(PO4)2: Zum BaZn(VO)(PO4)2-Typ verwandte, jedoch nicht isotype Vanadylphosphate / SrZn(VO)(PO4)2 and BaCd(VO)(PO4)2: Vanadylphosphates Related but not Isotypic to the BaZn(VO)(PO4 )2 Type
  19. Über ein cadmiumreiches Orthovanadat Ba2,5Cd11(VO4)9 mit Cadmium in oktaedrischer und tetragonal pyramidaler Koordination / On a Cadmium Rich Orthovanadate Ba2,5Cd11(VO4)9 Showing Cadmium in Octahedral and Square Pyramidal Coordination
  20. Transition Metal Complexes of Diazenes, XL [1] Iron Carbonyl Assisted Formation of Bicyclic 1,2-Dihydropyrazol-3-ones from Pyrazolines and Alkynes
  21. Polysulfonylamine, XC [1] Carbonsäure-Dimere, Wasser-Dimere und 18-Krone-6-Moleküle als Baugruppen eines supramolekularen Kettenpolymers: Darstellung und Struktur von (CH2CH2O)6 • 4H2O • 2HN(SO2C6H4-4-COOH)2 / Polysulfonylamines, XC [1] Carboxylic Acid Dimers, Water Dimers and 18-Crown-6 Molecules as Building Blocks in a Supramolecular Chain Polymer: Synthesis and Structure of (CH2CH2O)6 · 4H2O · 2HN(SO2C6H4-4-COOH)2
  22. Synthese und Eigenschaften von trans-Bisnitro-phthalocyaninato(2-)iridat(III) und Pyridin-nitro-phthalocyaninato(2-)iridium(III); Kristallstruktur von linear- Bis(triphenylphosphin)iminium-trans-Bisnitro-phthalocyaninato(2-)iridat(III) / Synthesis and Properties of trans-Bisnitro-phthalocyaninato(2-)iridate(III) and Pyridine-nitro-phthalocyaninato(2-)iridium(III); Crystal Structure of linear- Bis(triphenylphosphine)iminium trans-Bisnitro-phthalocyaninato(2-)iridate(III)
  23. Mehrkernige CpZr(IV)-und CpHf(IV)-Komplexe mit Oximatobrücken / Polynuclear CpZr(IV) and CpHf(IV) Complexes with Oximato Bridges
  24. Notizen: Determination of Signs of Coupling Constants for (Ethene)bis- (triphenylphosphane)platinum(0)
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Winner of the OpenAthens UX Award 2026
Winner of the OpenAthens UX Award 2026
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 25.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1997-0808/html
Scroll to top button