Home Synthese und Röntgen-Strukturuntersuchung von Rb4Cd(VO)(V2O7)2Cl und Tl4Cd(VO)(V2O7)2Cl / Synthesis and X-Ray Structure Analysis of Rb4Cd(VO)(V2O7)2Cl und Tl4Cd(VO)(V2O7)2Cl
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Synthese und Röntgen-Strukturuntersuchung von Rb4Cd(VO)(V2O7)2Cl und Tl4Cd(VO)(V2O7)2Cl / Synthesis and X-Ray Structure Analysis of Rb4Cd(VO)(V2O7)2Cl und Tl4Cd(VO)(V2O7)2Cl

  • B. Mertens and Hk. Müller-Buschbaum
Published/Copyright: June 2, 2014
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Abstract

Single crystals of (I) Rb4Cd(VO)(V2O7)2Cl und Tl4Cd(VO)(V2O7)2Cl have been prepared by flux techniques. The compounds were examined by X-ray analysis. They crystallize with tetragonal symmetry, space group C14-P4 with (I): a=9.142(1); c=5.525(1), (II): a=9.150(1), c=5.405(1) A, Z = 4. Both compound belong to the K4CuV5O15Cl-Type. V (l) forms V2O7 double tetrahedra, connected by square V(2)O5 pyramids and CdO4Cl2 octahedra. The short V(2)-O distance indicates a vanadyl group.

Received: 1997-1-27
Published Online: 2014-6-2
Published in Print: 1997-4-1

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