Home Physical Sciences Radiolysis of Tertiary Butyl Hydroperoxide in Aqueous Solution. Reductive Cleavage by the Solvated Electron, the Hydrogen Atom, and, in Particular, the Superoxide Radical Anion
Article Open Access

Radiolysis of Tertiary Butyl Hydroperoxide in Aqueous Solution. Reductive Cleavage by the Solvated Electron, the Hydrogen Atom, and, in Particular, the Superoxide Radical Anion

  • Shailesh Phulkar , Balijepalli Sethu Madhava Rao , Heinz-Peter Schuchmann and Clemens von Sonntag
Published/Copyright: June 2, 2014
Download Article (PDF)
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 45 Issue 10

Received: 1990-5-9
Published Online: 2014-6-2
Published in Print: 1990-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Topotaktische Entwässerung von Cs2MnF5 · H2O zu Cs2MnF5 und die Kristallstrukturen beider Verbindungen / Topotactical Dehydration of Cs2MnF5 · H2O to Cs2MnF5 and the Crystal Structures of Both Compounds
  2. K{μ-Cl2Al[CH(SiMe3)2]2} – Kristallstruktur eines eindimensional über K – Cl-Brücken koordinationspolymeren Alanats / K{µ-Cl2Al[CH(SiMe3)2]2} – Crystal Structure of an Alanate Featuring a Onedimensional Coordination Polymer with K–Cl Bridges
  3. Zur Existenz schwacher Wechselwirkungen zwischen Sb(III) und Phenylgruppen: Sb2Br6(SPPh3)2, Sb2I6(SePPh3)2 · 2 CH2Cl2, Sb4Br12(SPMe2Ph)4 und (Ph4P)2Sb2Br8 · CH3CN / On the Existence of Weak Interactions between Sb(III) and Phenyl Groups: Sb,Br6(SPPh3)2, Sb2I6(SePPh3)2 · 2CH2Cl2, Sb4Br12(SPMe2Ph)4 and (Ph4P)2Sb2Br8 · CH3CN
  4. Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen, XLII / Silicon Compounds with Strong Intramolecular Steric Interactions, XLII
  5. Kupfer(I)-Komplexe mit ungesättigten Stickstoffliganden, V / Kupfer(I)-Komplexe mit Diazadienen als Chelate und Brücken: Röntgenstrukturenuntersuchungen an (DAD)Cu(μ-Cl)2Cu(DAD), [(DAD)2Cu]⁺ (CuCl2)-, (DAD)CuCl, [μ-(DAD)2Cu5Cl5]n und [μ-(DAD)Cu(OTf)]n (DAD = Diazadien) / Copper(I) Complexes with Unsaturated Nitrogen Ligands, V Copper(I) Complexes with Chelating and Bridging Diazadienes: X-Ray Diffraction Studies of (DAD)Cu(μ-Cl)2Cu(DAD), [(DAD)2Cu]+ (CuCl2)-, (DAD)CuCl, [μ-(DAD)2Cu5Cl5]n and [μ-(DAD)Cu(OTf)]n (DAD = Diazadiene)
  6. Untersuchungen an Benzamidinyl-2-phosphazen-Liganden / Investigations on Benzamidinyl-2-phosphazen Ligands
  7. Phase Transition of Na3As under Pressure
  8. Synthese und Kristallstruktur von [VCl2(15-Krone-5)]+[VOCl4]- / Synthesis and Crystal Structure of [VCl2(15-Crown-5)]+[VOCl4]-
  9. Verbindungen mit dem 1,3-Dimethyl-1,3-diaza-2-phosphetidin-4-on-Grundgerüst; Synthese von 1,3-Dimethyl-2-thia-1,3-diaza-2 λ4-phosphetidin-4-on-Derivaten / Compounds Involving the 1,3-Dimethyl-1,3-diaza-2-phosphetidine-4-one Structure; Synthesis of 1,3-Dimethyl-2-thia-1,3-diaza-2λ4-phosphetidine-4-one Derivatives
  10. 4-Substituierte 1,3,5,7-Tetramethyl-1,3,5,7-tetraaza-4λ5-phosphaspiro-[3.3]heptan-2,6-dione; Röntgenstrukturanalyse von 1,3,4,6,7,9,10-Heptamethyl-5-oxa-1,3,7,9,10-pentaaza-4 λ5,6 λ5-diphosphadispiro[3.1.3.1]decan-2,8-dion / 4-Substituted 1,3,5,7-Tetramethyl- 1,3,5,7-tetraaza-4λ5-phosphaspiro[3.3]heptane-2,6-diones; Crystal Structure of 1,3,4,6,7,9,10-Heptamethyl-5-oxa-1,3,7,9,10-pentaaza-4λ5,6λ5-diphosphadispiro[3.1.3.1]decane-2,8-dione
  11. Darstellung, Reaktionen und spektroskopische Charakterisierung von [Os2X8]2-, X = Cl, Br, I, und Kristallstruktur von (PPN)2[Os2I8] · 2 CH2Cl2 / Preparation, Reactions and Spectroscopic Characterization of [Os2X8]2-, X = Cl, Br, I, and Crystal Structure of (PPN)2[Os2I8] · 2 CH2Cl2
  12. Radiolysis of Tertiary Butyl Hydroperoxide in Aqueous Solution. Reductive Cleavage by the Solvated Electron, the Hydrogen Atom, and, in Particular, the Superoxide Radical Anion
  13. ESR Spectra and Reactivity towards Catechol of Iron(III) Complexes with 2-(2-Benzimidazolyl)phenol and its Benzoxazole Derivative
  14. New Pyoverdin-Type Siderophores from Pseudomonas fluorescens
  15. Notizen: Darstellung und Struktur von LiPd2Tl / Preparation and Structure of LiPd2Tl
  16. Notizen: Die Reaktion von (Butadien)zirconocen mit Iminoboran / The Reaction of (Butadiene)zirconocene with Iminoborane
  17. Notizen: Marginalin, a Substance from the Pygidial Glands of Dytiscus Marginalis (Coleoptera): Molecular Associations with Polyamines in vitro
  18. Notizen: (Pyridinium)[(1,2-dithioquadratato)-cuprat(I)]hydrat, eine Verbindung mit einer CuI···CuI-Zickzackkette / (Pyridinium)[( 1,2-dithiosquarato)-cuprate(I)]hydrate, a Compound with a CuI···CuI-Zigzag Chain
  19. Notizen: Tricyclische Phosphorane aus den Phosphonigsäuredichloriden RPCl2 (R = Ph, CH2Ph) und dem (Z)-Ketoenol CF3C(O)CH = C(OH)CF3 / Tricyclic Phosphoranes from the Phosphonous Dichlorides RPCl2 (R = Ph, CH2Ph) and the (Z)-Ketoenol CF3C(O)CH=C(OH)CF3
https://doi.org/10.1515/znb-1990-1012
Creative Commons
BY-NC-ND 3.0

Articles in the same Issue

  1. Topotaktische Entwässerung von Cs2MnF5 · H2O zu Cs2MnF5 und die Kristallstrukturen beider Verbindungen / Topotactical Dehydration of Cs2MnF5 · H2O to Cs2MnF5 and the Crystal Structures of Both Compounds
  2. K{μ-Cl2Al[CH(SiMe3)2]2} – Kristallstruktur eines eindimensional über K – Cl-Brücken koordinationspolymeren Alanats / K{µ-Cl2Al[CH(SiMe3)2]2} – Crystal Structure of an Alanate Featuring a Onedimensional Coordination Polymer with K–Cl Bridges
  3. Zur Existenz schwacher Wechselwirkungen zwischen Sb(III) und Phenylgruppen: Sb2Br6(SPPh3)2, Sb2I6(SePPh3)2 · 2 CH2Cl2, Sb4Br12(SPMe2Ph)4 und (Ph4P)2Sb2Br8 · CH3CN / On the Existence of Weak Interactions between Sb(III) and Phenyl Groups: Sb,Br6(SPPh3)2, Sb2I6(SePPh3)2 · 2CH2Cl2, Sb4Br12(SPMe2Ph)4 and (Ph4P)2Sb2Br8 · CH3CN
  4. Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen, XLII / Silicon Compounds with Strong Intramolecular Steric Interactions, XLII
  5. Kupfer(I)-Komplexe mit ungesättigten Stickstoffliganden, V / Kupfer(I)-Komplexe mit Diazadienen als Chelate und Brücken: Röntgenstrukturenuntersuchungen an (DAD)Cu(μ-Cl)2Cu(DAD), [(DAD)2Cu]⁺ (CuCl2)-, (DAD)CuCl, [μ-(DAD)2Cu5Cl5]n und [μ-(DAD)Cu(OTf)]n (DAD = Diazadien) / Copper(I) Complexes with Unsaturated Nitrogen Ligands, V Copper(I) Complexes with Chelating and Bridging Diazadienes: X-Ray Diffraction Studies of (DAD)Cu(μ-Cl)2Cu(DAD), [(DAD)2Cu]+ (CuCl2)-, (DAD)CuCl, [μ-(DAD)2Cu5Cl5]n and [μ-(DAD)Cu(OTf)]n (DAD = Diazadiene)
  6. Untersuchungen an Benzamidinyl-2-phosphazen-Liganden / Investigations on Benzamidinyl-2-phosphazen Ligands
  7. Phase Transition of Na3As under Pressure
  8. Synthese und Kristallstruktur von [VCl2(15-Krone-5)]+[VOCl4]- / Synthesis and Crystal Structure of [VCl2(15-Crown-5)]+[VOCl4]-
  9. Verbindungen mit dem 1,3-Dimethyl-1,3-diaza-2-phosphetidin-4-on-Grundgerüst; Synthese von 1,3-Dimethyl-2-thia-1,3-diaza-2 λ4-phosphetidin-4-on-Derivaten / Compounds Involving the 1,3-Dimethyl-1,3-diaza-2-phosphetidine-4-one Structure; Synthesis of 1,3-Dimethyl-2-thia-1,3-diaza-2λ4-phosphetidine-4-one Derivatives
  10. 4-Substituierte 1,3,5,7-Tetramethyl-1,3,5,7-tetraaza-4λ5-phosphaspiro-[3.3]heptan-2,6-dione; Röntgenstrukturanalyse von 1,3,4,6,7,9,10-Heptamethyl-5-oxa-1,3,7,9,10-pentaaza-4 λ5,6 λ5-diphosphadispiro[3.1.3.1]decan-2,8-dion / 4-Substituted 1,3,5,7-Tetramethyl- 1,3,5,7-tetraaza-4λ5-phosphaspiro[3.3]heptane-2,6-diones; Crystal Structure of 1,3,4,6,7,9,10-Heptamethyl-5-oxa-1,3,7,9,10-pentaaza-4λ5,6λ5-diphosphadispiro[3.1.3.1]decane-2,8-dione
  11. Darstellung, Reaktionen und spektroskopische Charakterisierung von [Os2X8]2-, X = Cl, Br, I, und Kristallstruktur von (PPN)2[Os2I8] · 2 CH2Cl2 / Preparation, Reactions and Spectroscopic Characterization of [Os2X8]2-, X = Cl, Br, I, and Crystal Structure of (PPN)2[Os2I8] · 2 CH2Cl2
  12. Radiolysis of Tertiary Butyl Hydroperoxide in Aqueous Solution. Reductive Cleavage by the Solvated Electron, the Hydrogen Atom, and, in Particular, the Superoxide Radical Anion
  13. ESR Spectra and Reactivity towards Catechol of Iron(III) Complexes with 2-(2-Benzimidazolyl)phenol and its Benzoxazole Derivative
  14. New Pyoverdin-Type Siderophores from Pseudomonas fluorescens
  15. Notizen: Darstellung und Struktur von LiPd2Tl / Preparation and Structure of LiPd2Tl
  16. Notizen: Die Reaktion von (Butadien)zirconocen mit Iminoboran / The Reaction of (Butadiene)zirconocene with Iminoborane
  17. Notizen: Marginalin, a Substance from the Pygidial Glands of Dytiscus Marginalis (Coleoptera): Molecular Associations with Polyamines in vitro
  18. Notizen: (Pyridinium)[(1,2-dithioquadratato)-cuprat(I)]hydrat, eine Verbindung mit einer CuI···CuI-Zickzackkette / (Pyridinium)[( 1,2-dithiosquarato)-cuprate(I)]hydrate, a Compound with a CuI···CuI-Zigzag Chain
  19. Notizen: Tricyclische Phosphorane aus den Phosphonigsäuredichloriden RPCl2 (R = Ph, CH2Ph) und dem (Z)-Ketoenol CF3C(O)CH = C(OH)CF3 / Tricyclic Phosphoranes from the Phosphonous Dichlorides RPCl2 (R = Ph, CH2Ph) and the (Z)-Ketoenol CF3C(O)CH=C(OH)CF3
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 1.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1990-1012/html
Scroll to top button