Superstructure formation in Sc5Cu2In4
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Nataliya L. Gulay
Abstract
Polycrystalline Sc5Cu2In4 was synthesized by induction melting of the elements and small single crystals were obtained by a slow cooling sequence. Sc5Cu2In4 is the first coinage metal representative in the family of the so-called 5-2-4 intermetallics. The Zr5Ir2In4 type structure of Sc5Cu2In4 was refined from single crystal X-ray diffractometer data: Pnma, a = 1716.75(6), b = 677.94(12), c = 760.69(2) pm, wR2 = 0.0531, 1932 F2 values and 58 variables. Sc5Cu2In4 adopts a superstructure of the Lu5Ni2In4 type (doubling of the b axis and klassengleiche symmetry reduction from Pbam to Pnma), caused by dislocation of the copper atoms (puckering effect). Geometrically, Sc5Cu2In4 is a 4:1 intergrowth structure of distorted AlB2 and CsCl related slabs.
Funding source: Deutscher Akademischer Austauschdienst
Award Identifier / Grant number: 501100001654
Acknowledgments
The research stay of NG in Münster was supported by the Deutscher Akademischer Austauschdienst.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: This research was funded by Deutscher Akademischer Austauschdienst.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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© 2020 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Graphical Synopsis
- Miscellaneous
- Wolfgang Jeitschko, 27.05.1936--05.08.2020
- Original papers
- Superstructure formation in Sc5Cu2In4
- Cd2 and Co2 dumbbell formation in the yttrium-rich intermetallic compounds Y14Ni3Cd3 and Y6Co2Zn
- Crystal structure of the synthetic analogue of iwateite, Na2BaMn(PO4)2: an X-ray powder diffraction and Raman study
- Layered calcium hydrogen selenite chlorides Ca(HSeO3)Cl and Ca(HSeO3)Cl(H2O), the first halides obtained in СaCl2–H2SeO3–H2O system
- Crystal structure of incommensurate ηʺ-Cu1.235Sn intermetallic
- Synthesis, properties and crystal structure of novel Copper(II) ammine complex with [Pd(CN)4]2− building blocks
- Water soluble biguanide salts and their 1,3,5-triazine derivatives as inhibitors of acetylcholinesterase and α-glucosidase
- Letter
- Attractive halogen···halogen interactions in crystal structure of trans-dibromogold(III) complex
Articles in the same Issue
- Frontmatter
- Graphical Synopsis
- Miscellaneous
- Wolfgang Jeitschko, 27.05.1936--05.08.2020
- Original papers
- Superstructure formation in Sc5Cu2In4
- Cd2 and Co2 dumbbell formation in the yttrium-rich intermetallic compounds Y14Ni3Cd3 and Y6Co2Zn
- Crystal structure of the synthetic analogue of iwateite, Na2BaMn(PO4)2: an X-ray powder diffraction and Raman study
- Layered calcium hydrogen selenite chlorides Ca(HSeO3)Cl and Ca(HSeO3)Cl(H2O), the first halides obtained in СaCl2–H2SeO3–H2O system
- Crystal structure of incommensurate ηʺ-Cu1.235Sn intermetallic
- Synthesis, properties and crystal structure of novel Copper(II) ammine complex with [Pd(CN)4]2− building blocks
- Water soluble biguanide salts and their 1,3,5-triazine derivatives as inhibitors of acetylcholinesterase and α-glucosidase
- Letter
- Attractive halogen···halogen interactions in crystal structure of trans-dibromogold(III) complex
