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Synthesis, structure, photoluminescent, optical and magnetic properties of a novel thulium p-hydroxybenzenesulfonate complex

  • Rong-Hua Hu , Wen-Tong Chen EMAIL logo and Jian-gen Huang
Published/Copyright: October 25, 2018
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 234 Issue 3

Abstract

A novel thulium p-hydroxybenzenesulfonate complex [Tm(C6H5O4S)2(H2O)6](C6H5O4S)·3H2O (1) was solvothermally synthesized and characterized by elemental analyses, photoluminescence, solid-state UV/vis diffuse reflectance, magnetic measurements and single-crystal X-ray diffraction. Complex 1 features an ionic structure with the thulium ion possessing a square antiprismatic geometry. Complex 1 crystallized in the monoclinic system with space group P21. Photoluminescent measurements with solid-state sample demonstrate that the anti-Stokes emission bands in the red/NIR spectral region 710 and 812 nm are observed from the Tm3+ 4f intrashell transitions from the 3F2,3 excited states to the 3H6 and 1G4 excited state to the 3H5 state, respectively. Solid-state UV/vis diffuse reflectance spectra of complex 1 show the existence of a wide optical band gap of 3.56 eV. Variable-temperature magnetic susceptibility and field dependence magnetization measurements are also studied and the magnetic susceptibility obeys the Curie-Weiss law (χm=c/(T−θ)) with the value C being of 8.6 K and a negative Weiss constant θ being of −0.2 K.

Keywords: band gap; crystal; magnetism; photoluminescence; thulium

Acknowledgements

We thank the financial support of Jiangxi Provincial Department of Education’s Item of Science and Technology (GJJ170637) and the open foundation (20180008) of the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2017-2105).

Received: 2017-09-25
Accepted: 2018-09-25
Published Online: 2018-10-25
Published in Print: 2019-03-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides
  5. Organic and Metalorganic Crystal Structures
  6. Intermolecular hydrogen bonding H···Cl in crystal structure of palladium(II)-bis(diaminocarbene) complex
  7. Steric control of supramolecular association in structures of Zn(S2COR)2 with N,N′-bis(pyridin-4-ylmethyl)oxalamide
  8. Synthesis, structure, photoluminescent, optical and magnetic properties of a novel thulium p-hydroxybenzenesulfonate complex
  9. On the influence of small chemical changes upon the supramolecular association in substituted 2-(phenoxy)-1,4-naphthoquinones
  10. Crystallographic Computing
  11. PolyDis: simple quantification tool for distortion of polyhedra in crystalline solids
https://doi.org/10.1515/zkri-2017-2105
Keywords for this article
band gap; crystal; magnetism; photoluminescence; thulium

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides
  5. Organic and Metalorganic Crystal Structures
  6. Intermolecular hydrogen bonding H···Cl in crystal structure of palladium(II)-bis(diaminocarbene) complex
  7. Steric control of supramolecular association in structures of Zn(S2COR)2 with N,N′-bis(pyridin-4-ylmethyl)oxalamide
  8. Synthesis, structure, photoluminescent, optical and magnetic properties of a novel thulium p-hydroxybenzenesulfonate complex
  9. On the influence of small chemical changes upon the supramolecular association in substituted 2-(phenoxy)-1,4-naphthoquinones
  10. Crystallographic Computing
  11. PolyDis: simple quantification tool for distortion of polyhedra in crystalline solids
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