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Anion-directed assembly of lanthanide coordination polymers with SMMs properties based on a dihydrazone ligand

  • Lina Zhang , Peigao Duan , Yang Liu , Jingxian Sun , Dan Zhao EMAIL logo and Chenxia Du EMAIL logo
Published/Copyright: August 25, 2017
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 233 Issue 1

Abstract

Four new Ln(III)-based coordination polymers (CPs), [Eu(HL)Cl2(DMF)2]·(H2L) (1), [Dy(HL)Cl2(DMF)2]·(H2L) (2), [Er(HL)Cl2(DMF)(CH3OH)]·(DMF) (3) and [Yb(HL)Cl2(DMF)(H2O)]·(DMF) (4) (H2L=2,6-bis[(3-methoxysalicylidene)hydrazinocarbonyl]pyridine) have been synthesized through the reaction of Ln(III) chloride and H2L by using the vapour diffusion method. Interestingly, Cl− as a template agent plays a vital role in the formation of the target complexes. Single-crystal X-ray diffraction studies indicate that 1 and 2 are isostructural and crystallize in triclinic space group P1̅, while complexes 3 and 4 are isostructural and crystallize in monoclinic space group C2/c. Variable temperature magnetization measurement (χMT–T) demonstrates possible antiferromagnetic interactions in complex 2. Alternating-current (ac) susceptibility measurement furthermore indicated frequency dependence for both the in-phase (χ′) and out-of-phase (χ″) components in 2, suggesting that there is a slow relaxation behavior of the magnetization, which is typical of single-molecule magnets (SMMs). This is the first time that Ln(III) CPs based on such a dihydrazone ligand has been reported so far.

Keywords: anion template; dihydrazone ligand; lanthanide coordination polymers; single-molecule magnets

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21371154), the Key Scientific Research Project of Henan Province (16A150052), Science and Technology Research Project of Henan Province (172102210281) and Dr. Funds of Henan Polytechnic University (B2016-47).

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Supplemental Material:

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2017-2076).

Received: 2017-5-21
Accepted: 2017-8-2
Published Online: 2017-8-25
Published in Print: 2018-1-26

©2018 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. Microporous uranyl chromates successively formed by evaporation from acidic solution
  5. Crystal packing and crystallization tendency from the melt of 2-((2-ethylphenyl)amino)nicotinic acid
  6. Organic and Metalorganic Crystal Structures
  7. The role of hydrogen bonds in order-disorder transition of a new incommensurate low temperature phase β-[Zn-(C7H4NO4)2]·3H2O
  8. Structural investigation and Hirshfeld surface analysis of three organic picrate salts
  9. Crystal structure and thermal behavior of isostructural binary complexes [Rh(en)3][Fe(CN)6] and [Rh(en)3][Cо(CN)6]
  10. Towards clathrates. 2. The frozen states of hydration of tert-butanol
  11. Anion-directed assembly of lanthanide coordination polymers with SMMs properties based on a dihydrazone ligand
  12. Crystallographic Computing
  13. DIANNA (diffraction analysis of nanopowders) – a software for structural analysis of nanosized powders
  14. A new cubic Ia3̅d crystal structure observed in a model single component system by molecular dynamics simulation
https://doi.org/10.1515/zkri-2017-2076
Keywords for this article
anion template; dihydrazone ligand; lanthanide coordination polymers; single-molecule magnets

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. Microporous uranyl chromates successively formed by evaporation from acidic solution
  5. Crystal packing and crystallization tendency from the melt of 2-((2-ethylphenyl)amino)nicotinic acid
  6. Organic and Metalorganic Crystal Structures
  7. The role of hydrogen bonds in order-disorder transition of a new incommensurate low temperature phase β-[Zn-(C7H4NO4)2]·3H2O
  8. Structural investigation and Hirshfeld surface analysis of three organic picrate salts
  9. Crystal structure and thermal behavior of isostructural binary complexes [Rh(en)3][Fe(CN)6] and [Rh(en)3][Cо(CN)6]
  10. Towards clathrates. 2. The frozen states of hydration of tert-butanol
  11. Anion-directed assembly of lanthanide coordination polymers with SMMs properties based on a dihydrazone ligand
  12. Crystallographic Computing
  13. DIANNA (diffraction analysis of nanopowders) – a software for structural analysis of nanosized powders
  14. A new cubic Ia3̅d crystal structure observed in a model single component system by molecular dynamics simulation
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