Crystal structure and thermal behavior of isostructural binary complexes [Rh(en)3][Fe(CN)6] and [Rh(en)3][Cо(CN)6]
-
Pechenyuk Sophia
,
Zolotarev Andrey
Abstract
Binary complex compounds (BCC) [Rh(en)3][Fe(CN)6]·2H2O (I) and [Rh(en)3][Co(CN)6]·2H2O (II) have been prepared and characterized by the X-ray diffraction, crystal optic, elemental and thermal analyses. The crystal structures I and II (space group P21/n) are described within the monoclinic crystal system, are insular and isostructural. The thermal behavior of BCC I and II is identical, with an exception of a higher temperature (~by 50°C) of II decomposition. In air atmosphere, the ligand removal is followed by the formation of, respectively, Rh+1/2Fe2O3 and Rh+Co that on further heating up to 1000°C convert into RhFeO3 and RhCoO1.5. The residues of annealing at 1000°C in argon atmosphere are Rh+1/2Fe2O3 and Rh+CoO, respectively.
References
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Articles in the same Issue
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Articles in the same Issue
- Frontmatter
- Graphical Synopsis
- Inorganic Crystal Structures
- Microporous uranyl chromates successively formed by evaporation from acidic solution
- Crystal packing and crystallization tendency from the melt of 2-((2-ethylphenyl)amino)nicotinic acid
- Organic and Metalorganic Crystal Structures
- The role of hydrogen bonds in order-disorder transition of a new incommensurate low temperature phase β-[Zn-(C7H4NO4)2]·3H2O
- Structural investigation and Hirshfeld surface analysis of three organic picrate salts
- Crystal structure and thermal behavior of isostructural binary complexes [Rh(en)3][Fe(CN)6] and [Rh(en)3][Cо(CN)6]
- Towards clathrates. 2. The frozen states of hydration of tert-butanol
- Anion-directed assembly of lanthanide coordination polymers with SMMs properties based on a dihydrazone ligand
- Crystallographic Computing
- DIANNA (diffraction analysis of nanopowders) – a software for structural analysis of nanosized powders
- A new cubic Ia3̅d crystal structure observed in a model single component system by molecular dynamics simulation
