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Temperature- and moisture-dependency of CsLiB6O10. A new phase, β-CsLiB6O10

  • Natalia A. Sennova EMAIL logo , Gerhard Cordier , Barbara Albert , Stanislav K. Filatov , Rimma S. Bubnova , Ludmila I. Isaenko , Lyubov I. Gubenko , Jan-Peter Klöckner and Marc H. Prosenc
Published/Copyright: October 24, 2014
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 229 Issue 11

Abstract

The structural behavior of the non-linear optical, nanoporous compound CsLiB6O10 was studied in a wide temperature range. Both the highly anisotropic thermal expansion of the borate with temperature variation and the deterioration of its crystals were investigated. The electron density distribution was analyzed in detail. A reversible, partial transition to a new modification, β-CsLiB6O10, was observed during cooling crystalline and moist samples of CsLiB6O10 to –25 °C. The crystal structure of the new phase is described.

Keywords: caesium lithium borate; crystal structure; electron density; phase transition; thermal expansion
Corresponding author: Natalia A. Sennova, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Germany; and Department of Crystallography, St. Petersburg State University, Russia, E-mail:

Acknowledgments

The authors are grateful to Dr. K. Hofmann and H. Wolf (Eduard-Zintl-Institute, TU Darmstadt), Dr. M. Hinterstein (DESY, Hamburg), Dr. M. G. Fofanova.

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Supplemental Material

The online version of this article (DOI: 10.1515/zkri-2014-1758) offers supplementary material, available to authorized users.

Received: 2014-4-11
Accepted: 2014-8-29
Published Online: 2014-10-24
Published in Print: 2014-11-1

©2014 by De Gruyter

Articles in the same Issue

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  2. Graphical Synopsis
  3. Preface
  4. Special issue on Russian-German research collaboration
  5. Original Articles
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  9. Temperature- and moisture-dependency of CsLiB6O10. A new phase, β-CsLiB6O10
  10. Crystallography between Kiel and St. Petersburg: review of collaboration and the crystal structure of [Tl5(SiO4)(OH)]2[Tl6(SO4)(OH)4]
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https://doi.org/10.1515/zkri-2014-1758
Keywords for this article
caesium lithium borate; crystal structure; electron density; phase transition; thermal expansion

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Preface
  4. Special issue on Russian-German research collaboration
  5. Original Articles
  6. Synthesis and thermal behaviour of pauflerite, β-VOSO4, and its α-modification
  7. The pressure effect on crystal structure of complex ferroelectrics Ba4Sm2Fe2Nb8O30 and Ba4Gd2Fe2Nb8O30
  8. Crystal structure of a giant supramolecule encapsulating o-carborane
  9. Temperature- and moisture-dependency of CsLiB6O10. A new phase, β-CsLiB6O10
  10. Crystallography between Kiel and St. Petersburg: review of collaboration and the crystal structure of [Tl5(SiO4)(OH)]2[Tl6(SO4)(OH)4]
  11. High-pressure crystal chemistry of coesite-I and its transition to coesite-II
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