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Analyzing the modulations induced in the mixed micellar behavior of 1-alkyl-3-butylimidazolium based surface-active ionic liquids with an antibiotic drug in aqueous media

  • Gagandeep Kaur is currently working as Senior Research Fellow at Dr B R Ambedkar National Institute of Technology Jalandhar. She is recipient of INSPIRE scholarship 2012 and INSPIRE fellowship 2017 by Department of Science and Technology, New Delhi, India. She has approximately 5 years of experience as a researcher in surface chemistry. She has published several research papers in reputed international journals in topics related to self-assembly and aggregation behaviour of surface-active ionic liquids. She is actively involved in research and has presented papers in prestigious national and international conferences.

         ,

    Ramanjeet Kaur is working as a Senior Research Fellow in Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar, Punjab, India. She has been awarded a scholarship from the UGC-SRF Delhi. She has been a Physical Chemistry researcher for over four years now. Her research interests lie in the micellization behaviour of surface-active ionic liquids in aqueous and in the presence of various additives, and she has published several articles on these topics in respected international journals.

         ,

    Jasmeet Kaur was born in 1994 in India. She received her bachelors and master degree in Chemistry in 2015 and 2017 from Guru Nanak Dev University, Amritsar, India. She joined PhD in 2019 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has published 3 international researches in most renowned journals and published 3 papers in national and international conferences.

         ,

    Harleen Singh is an Assistant Professor at Kanya Maha Vidyalaya, Jalandhar. He obtained his M.Sc. and Ph D degree in Physics from Dr B R Ambedkar National Institute of Technology Jalandhar. He has obtained Gold Medal in M.Sc. Physics by holding first position in Institute. His research interests include thermodynamics, fluid mechanics, surface and interfacial phenomena. He has more than 10 years of teaching experience. He has taught diverse theory courses at KMV Jalandhar, ranging from fundamental to advanced physics.

         ,

    Harsh Kumar was born in 1977 in India. He received his bachelors, masters and doctoral degree from Kurukshetra University, India in 1996, 1998 and 2002. He joined as a faculty in the Department of Chemistry in 2007 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. Currently, he is working as an Associate Professor in the same department. He is having 20 years’ experience of teaching under graduate and post graduate students of Chemistry. He has supervised more than 50 candidates for masters and doctoral thesis. He has published more than 200 papers in referred national and international journals. His research interests are Physical Chemistry, Solution Thermodynamics of biomolecules, Ionic Liquids, Micellization behaviour of surfactants, Solution thermodynamics of binary liquid mixtures. He passed away in October 2022 owing to his serious health issues.

         and

    Pooja Sharma was born in 1994 in India. She received her bachelor degree in 2015 from Punjabi university Patiala and master degree in Chemistry in 2017 from Thapar University, Patiala, India. She joined PhD in 2018 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has published 5 international researches in most renowned journals and published 2 papers in national and international conferences.

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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 60 Issue 4

Abstract

The study aims to scrutinize the mixed micellization and interfacial behavior of two 1-alkyl-3-butylimidazolium based surface-active ionic liquids (SAILs) i.e., 1-decyl-3-butylimidazolium bromide [C10bim][Br] and 1-tetradecyl-3-butylimidazolium bromide [C14bim][Br] under the influence of streptomycin sulphate (SS) drug in 5 mM concentration in aqueous media. Imidazolium-based SAILs have unique physicochemical properties and greater surface activity than conventional surfactants, which allows them to increase drug permeability, making them better drug carriers than currently available formulations. To fully utilize [C14bim][Br] and [C10bim][Br] in drug delivery applications, deep insight into the interactions occurring in the mixed micellar [C10bim][Br]/[C14bim][Br] systems in the drug’s presence are necessary to be examined. Thus, the study is conducted using conductivity and surface tension measurement techniques to fully exploit the self-assembly, micellization behavior and interactions occurring in the pure and mixed micellar system of [C10bim][Br]/[C14bim][Br] in water and 5 mM of SS solution in aqueous media. For this, various thermodynamic, surface-active and mixed micellar parameters of micellization have been calculated and analyzed with respect to change in mole fraction, temperature and addition of SS in solution.

Keywords: aggregation; [C10bim][Br]; [C14bim][Br]; interfacial behavior; streptomycin sulphate; surface-active ionic liquid
Corresponding author: Pooja Sharma, Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar, 144011, Punjab, India, E-mail:
Harsh Kumar: Deceased.

Funding source: Science and Engineering Research Board

Award Identifier / Grant number: Unassigned

About the authors

Gagandeep Kaur

Gagandeep Kaur is currently working as Senior Research Fellow at Dr B R Ambedkar National Institute of Technology Jalandhar. She is recipient of INSPIRE scholarship 2012 and INSPIRE fellowship 2017 by Department of Science and Technology, New Delhi, India. She has approximately 5 years of experience as a researcher in surface chemistry. She has published several research papers in reputed international journals in topics related to self-assembly and aggregation behaviour of surface-active ionic liquids. She is actively involved in research and has presented papers in prestigious national and international conferences.

Ramanjeet Kaur

Ramanjeet Kaur is working as a Senior Research Fellow in Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar, Punjab, India. She has been awarded a scholarship from the UGC-SRF Delhi. She has been a Physical Chemistry researcher for over four years now. Her research interests lie in the micellization behaviour of surface-active ionic liquids in aqueous and in the presence of various additives, and she has published several articles on these topics in respected international journals.

Jasmeet Kaur

Jasmeet Kaur was born in 1994 in India. She received her bachelors and master degree in Chemistry in 2015 and 2017 from Guru Nanak Dev University, Amritsar, India. She joined PhD in 2019 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has published 3 international researches in most renowned journals and published 3 papers in national and international conferences.

Harleen Singh

Harleen Singh is an Assistant Professor at Kanya Maha Vidyalaya, Jalandhar. He obtained his M.Sc. and Ph D degree in Physics from Dr B R Ambedkar National Institute of Technology Jalandhar. He has obtained Gold Medal in M.Sc. Physics by holding first position in Institute. His research interests include thermodynamics, fluid mechanics, surface and interfacial phenomena. He has more than 10 years of teaching experience. He has taught diverse theory courses at KMV Jalandhar, ranging from fundamental to advanced physics.

Harsh Kumar

Harsh Kumar was born in 1977 in India. He received his bachelors, masters and doctoral degree from Kurukshetra University, India in 1996, 1998 and 2002. He joined as a faculty in the Department of Chemistry in 2007 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. Currently, he is working as an Associate Professor in the same department. He is having 20 years’ experience of teaching under graduate and post graduate students of Chemistry. He has supervised more than 50 candidates for masters and doctoral thesis. He has published more than 200 papers in referred national and international journals. His research interests are Physical Chemistry, Solution Thermodynamics of biomolecules, Ionic Liquids, Micellization behaviour of surfactants, Solution thermodynamics of binary liquid mixtures. He passed away in October 2022 owing to his serious health issues.

Pooja Sharma

Pooja Sharma was born in 1994 in India. She received her bachelor degree in 2015 from Punjabi university Patiala and master degree in Chemistry in 2017 from Thapar University, Patiala, India. She joined PhD in 2018 at Dr. BR Ambedkar National Institute of Technology, Jalandhar, India. She has published 5 international researches in most renowned journals and published 2 papers in national and international conferences.

Acknowledgments

Gagandeep Kaur would like to thank Department of Science and Technology (DST), New Delhi for giving a DST INSPIRE Fellowship (IF170753).

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Authors acknowledge financial assistance provided by the Science and Engineering Research Board (SERB), New Delhi (EMR/2015/002059) and the Department of Science and Technology (DST), New Delhi (DST-FIST [CSI-228/2011]).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The article contains supplementary material (https://doi.org/10.1515/tsd-2023-2512).

Received: 2023-03-07
Accepted: 2023-03-31
Published Online: 2023-07-04
Published in Print: 2023-07-26

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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  13. Investigation of aggregation behavior and surface properties of cationic surface-active ionic liquids and sodium carboxymethylcellulose mixed systems
  14. Ionic Liquids
  15. CuCl2-modified ionic liquids for alkylation of benzene with 1-dodecene
  16. Micellar Catalysis
  17. Kinetic study of Ru(III) – catalyzed oxidation of L-phenylalanine by hexacyanoferrate(III) in an anionic surfactant medium
  18. Detergent Ingredient
  19. Effects of surfactants and enzymes on the direct determination of protein on fabric using the BCA reaction
  20. Synthesis
  21. Production of high content of N-methyldiethanolamine di-ester via heterogeneous transesterification
https://doi.org/10.1515/tsd-2023-2512
Keywords for this article
aggregation; [C10bim][Br]; [C14bim][Br]; interfacial behavior; streptomycin sulphate; surface-active ionic liquid

Articles in the same Issue

  1. Frontmatter
  2. Novel Surfactants
  3. Surface and foaming properties of an anionic CO2-switchable tail surfactant
  4. Biosurfactant Production (Special Topic Section)
  5. Comparing the performances of different sulfonating agents in sulfonation of methyl esters synthesized from used cooking oil
  6. Single batch co-production of Pseudomonad polyhydroxybutyrate and rhamnolipids on wasted cooking oil under salinity stress
  7. Drug Delivery Systems
  8. Felodipine-loaded Spanlastics: superior nanocarriers for transdermal delivery
  9. Thermodynamics and micellization behavior of choline based ionic liquids in presence of drug Cetrizine dihydrochloride
  10. Synthesis of non-ionic surfactants nano-vesicles for clarithromycin oral delivery
  11. Analyzing the modulations induced in the mixed micellar behavior of 1-alkyl-3-butylimidazolium based surface-active ionic liquids with an antibiotic drug in aqueous media
  12. Surface-Active Ionic Liquids
  13. Investigation of aggregation behavior and surface properties of cationic surface-active ionic liquids and sodium carboxymethylcellulose mixed systems
  14. Ionic Liquids
  15. CuCl2-modified ionic liquids for alkylation of benzene with 1-dodecene
  16. Micellar Catalysis
  17. Kinetic study of Ru(III) – catalyzed oxidation of L-phenylalanine by hexacyanoferrate(III) in an anionic surfactant medium
  18. Detergent Ingredient
  19. Effects of surfactants and enzymes on the direct determination of protein on fabric using the BCA reaction
  20. Synthesis
  21. Production of high content of N-methyldiethanolamine di-ester via heterogeneous transesterification
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