Abstract
In this review, we classify and analyze the structural data of more than 80 monomeric platinum coordination complexes with an inner coordination sphere of PtP4 in which only organophosphines are involved. On the basis of the coordination mode of respective organophosphines, these complexes can be divided into six subgroups: Pt(PL)4, Pt(PL)2(PL′)2, Pt(η2-P2L)(PL)2, Pt(η2-P2L)2, Pt(η2-P2L)(η2-P2L′)2, and Pt(η4-P4L). The chelating ligands forming wide varieties of metallocycles: (P=P), (PNP), (PCP), (PC2P), (PP2P), (PC2NP), (PNCNP), (PNPNP), (POHOP), (POBOP), (PCNCP), (PC3P), (PC4P), and (PC2OC2P). The effects of both steric and electronic factors reflect on the values of P-Pt-P chelate angles. The total mean values of Pt-P elongate in the order: 2.289 Å (tetradentate)<2.306 Å (monodentate)<2.320 Å (bidentate). The same order shows the respective covalent bond weaknesses.
Funding source: Agentúra Ministerstva školstva, vedy, výskumu a športu SR
Award Identifier / Grant number: VEGA 1/0463/18 and APVV-15-0585
Funding statement: This work was supported by the projects Agentúra Ministerstva školstva, vedy, výskumu a športu SR, Funder Id: 10.13039/501100003194, Grant Numbers: VEGA 1/0463/18 and APVV-15-0585.
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Organophosphines in PtP4 derivatives; structural aspects
- Periodic law and system of chemical elements: 150 years from the date of discovery
- Comparison and assessment of zeolite catalysts performance dimethyl ether and light olefins production through methanol: a review
Articles in the same Issue
- Frontmatter
- Organophosphines in PtP4 derivatives; structural aspects
- Periodic law and system of chemical elements: 150 years from the date of discovery
- Comparison and assessment of zeolite catalysts performance dimethyl ether and light olefins production through methanol: a review