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Polycyclic 3d-metalchelates formed owing to inner-sphere transmutations in the gelatin matrix: synthesis and structures

  • Oleg V. Mikhailov is the author of more than 1100 scientific publications in nine different languages; among them, there are 15 monographs and books, more than 30 reviews (including 10 in international scientific journals), and about 500 original research articles in authoritative (among them, there are more than 250 articles in 25 international) scientific journals. He has 125 patents on various inventions, too. He is the author of three popular scientific books (without co-authors), and more than 60 articles in popular scientific journals. He received grants from the Russian Foundation of Basic Researches (RFBR, 14 projects, 1996–2016), the International Scientific Soros Education Program (ISSEP, 2 projects, 1994–1998), the Russian Ministry of Education (1998–2000 and 2014–2016), and the Academy of Science of Tatarstan Republic (2001–2005). He is an active member of the International New York Academy of Sciences (since 1993), a full member of the Russian Academy of Natural History (since 2013), and a member of the American Chemical Society (since 2008).

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Published/Copyright: August 29, 2017

Abstract

Processes of synthesis of polycyclic compounds containing various 3d-elements, proceeding in gelatin matrix in the systems M(II) ion – (N,S)- or (N,O,S)-containing organic compound A – mono- or dicarbonyl-containing organic compound B, resulting in one of a variety of inner-sphere transmutations, namely “self-assembly”, have been considered and discussed. The chemical nature of the final products of such a synthesis formed under these specific conditions have been compared with the chemical nature of the final products formed by similar synthesis in solutions. It has been noted that in many cases, the nature and chemical composition of these products differ substantially. Specific features of the density functional theory calculated molecular structures of the metal macrocyclic compounds that can be formed due to such a synthesis in the systems indicated above have been discussed, too. The review covers the period 1990–2016.

About the author

Oleg V. Mikhailov

Oleg V. Mikhailov is the author of more than 1100 scientific publications in nine different languages; among them, there are 15 monographs and books, more than 30 reviews (including 10 in international scientific journals), and about 500 original research articles in authoritative (among them, there are more than 250 articles in 25 international) scientific journals. He has 125 patents on various inventions, too. He is the author of three popular scientific books (without co-authors), and more than 60 articles in popular scientific journals. He received grants from the Russian Foundation of Basic Researches (RFBR, 14 projects, 1996–2016), the International Scientific Soros Education Program (ISSEP, 2 projects, 1994–1998), the Russian Ministry of Education (1998–2000 and 2014–2016), and the Academy of Science of Tatarstan Republic (2001–2005). He is an active member of the International New York Academy of Sciences (since 1993), a full member of the Russian Academy of Natural History (since 2013), and a member of the American Chemical Society (since 2008).

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Received: 2017-3-10
Accepted: 2017-6-26
Published Online: 2017-8-29
Published in Print: 2017-6-27

©2017 Walter de Gruyter GmbH, Berlin/Boston

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