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Potential applications of deep eutectic solvents in natural gas sweetening for CO2 capture

  • Tayeb Aissaoui

    Tayeb Aissaoui is the director of EURL P.B.M Company, Algeria. He is also a research student at University Setif 1, Algeria. After his graduation as a chemical engineer from University Setif 1, Algeria, Aissaoui joined University Malaya Center for Ionic Liquids, Malaysia. He also gained a Master’s degree in Islamic and other civilizations from Malaysia. In addition, he was the first director founder of The Algerian Academic Forum, Malaysia. He is the ambassador of The Asian Council of Science Editors (ACSE) in Algeria for the year 2016. He has published in both chemical engineering and political thought. His research interests include natural gas pretreatments, molecular modeling, ILs, DESs and political thought.

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    , Inas M. AlNashef

    Inas M. AlNashef joined King Saud University, Riyadh, Saudi Arabia, after obtaining his PhD from the University of South Carolina in 2004. In 2011, he was promoted to associate professor. He was very active in research related to green engineering and sustainability. In June 2014, he moved to Abu Dhabi (UAE) where he is now employed as an associate professor in the Department of Chemical Engineering, Masdar Institute of Science and Technology. He co-authored more than 80 peer-reviewed journal publications. In addition, he received 7 patents from US and EU Patent Offices.

    , Umair A. Qureshi

    Umair A. Qureshi graduated in organic chemistry from University of Sindh, Jamshoro, Pakistan, in 2008. He earned his PhD in analytical chemistry from the same university in 2015. In 2013–2014, he was also awarded a split PhD fellowship at University of Selcuk, Konya, Turkey. He serves as a lecturer of chemistry at Government Boys Degree College, Qasimabad, Hyderabad, Pakistan. Currently, he is doing postdoctoral research on nanofiber preparations and their applications in water treatment and gas capture at Mehran University of Engineering and Technology, Jamshoro, Pakistan. His research interests include waste water treatment (adsorption, advanced oxidation processes and membrane technology), ionic liquids and their applications in analytical chemistry and enzyme catalyzed degradation of recalcitrant pollutants.

    and Yacine Benguerba

    Yacine Benguerba graduated from the University of Constantine in 1998 (under the guidance of Dr. Mohamed Salah Koutchoukali). He received his PhD in chemical engineering (under the supervision of Prof. Brahim Djellouli) from Setif University in 2011. In 2015, he received the HDR (habilitation) at Setif University. His research interests include computational fluid dynamics, molecular modeling and optimization of chemical processes.

Published/Copyright: January 25, 2017
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Abstract

Novel solvents named deep eutectic solvents (DESs) have been intensively investigated in recent years. Their non-toxicity, biodegradability, low volatility, easy preparation and low cost make them promising green solvents for several industrial processes. This article provides a status review of the possible applications of DESs in natural gas (NG) sweetening by carbon dioxide (CO2) capturing. Investigations on preparation and chemical structures of DESs were reported. In addition, very recent physiochemical properties and applications of DESs were well discussed. Mainly, experimental and predicted solubilities of CO2 in DESs were reported and compared in this work. It was deduced that DESs offer some potential advantages over the conventional solvents, i.e. alkanolamines, in terms of absorption efficiency, easy preparation and low economic cost. It is expected that in coming decades, DESs will offer potential use in NG technology. Further investigations are highly required to highlight more about these neoteric solvents.

About the authors

Tayeb Aissaoui

Tayeb Aissaoui is the director of EURL P.B.M Company, Algeria. He is also a research student at University Setif 1, Algeria. After his graduation as a chemical engineer from University Setif 1, Algeria, Aissaoui joined University Malaya Center for Ionic Liquids, Malaysia. He also gained a Master’s degree in Islamic and other civilizations from Malaysia. In addition, he was the first director founder of The Algerian Academic Forum, Malaysia. He is the ambassador of The Asian Council of Science Editors (ACSE) in Algeria for the year 2016. He has published in both chemical engineering and political thought. His research interests include natural gas pretreatments, molecular modeling, ILs, DESs and political thought.

Inas M. AlNashef

Inas M. AlNashef joined King Saud University, Riyadh, Saudi Arabia, after obtaining his PhD from the University of South Carolina in 2004. In 2011, he was promoted to associate professor. He was very active in research related to green engineering and sustainability. In June 2014, he moved to Abu Dhabi (UAE) where he is now employed as an associate professor in the Department of Chemical Engineering, Masdar Institute of Science and Technology. He co-authored more than 80 peer-reviewed journal publications. In addition, he received 7 patents from US and EU Patent Offices.

Umair A. Qureshi

Umair A. Qureshi graduated in organic chemistry from University of Sindh, Jamshoro, Pakistan, in 2008. He earned his PhD in analytical chemistry from the same university in 2015. In 2013–2014, he was also awarded a split PhD fellowship at University of Selcuk, Konya, Turkey. He serves as a lecturer of chemistry at Government Boys Degree College, Qasimabad, Hyderabad, Pakistan. Currently, he is doing postdoctoral research on nanofiber preparations and their applications in water treatment and gas capture at Mehran University of Engineering and Technology, Jamshoro, Pakistan. His research interests include waste water treatment (adsorption, advanced oxidation processes and membrane technology), ionic liquids and their applications in analytical chemistry and enzyme catalyzed degradation of recalcitrant pollutants.

Yacine Benguerba

Yacine Benguerba graduated from the University of Constantine in 1998 (under the guidance of Dr. Mohamed Salah Koutchoukali). He received his PhD in chemical engineering (under the supervision of Prof. Brahim Djellouli) from Setif University in 2011. In 2015, he received the HDR (habilitation) at Setif University. His research interests include computational fluid dynamics, molecular modeling and optimization of chemical processes.

Acknowledgments

The authors would like to acknowledge Department of Chemical and Environmental Engineering, Masdar Institute of Science and Technology, Abu Dhabi, United Arab Emirates, and Laboratoire de Génie des Procédés Chimiques, Université Ferhat Abbas, Sétif 1, 19000 Sétif, Algeria, for supporting this work.

References

Abbott AP, Capper G, Davies DL, Rasheed RK, Tambyrajah V. Novel solvent properties of choline chloride/urea mixtures. Chem Commun 2003; 9: 70–71.10.1039/b210714gSearch in Google Scholar PubMed

Abbott AP, Boothby D, Capper G, Davies DL, Rasheed RK. Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. J Am Chem Soc 2004; 126: 9142–9147.10.1021/ja048266jSearch in Google Scholar PubMed

Abbott AP, Capper G, Gray S. Design of improved deep eutectic solvents using hole theory. ChemPhysChem 2006; 7: 803–806.10.1002/cphc.200500489Search in Google Scholar PubMed

Abbott AP, Barron JC, Ryder KS, Wilson D. Eutectic-based ionic liquids with metal-containing anions and cations. Chemistry 2007a; 13: 6495–6501.10.1002/chem.200601738Search in Google Scholar PubMed

Abbott AP, Harris RC, Ryder KS. Application of hole theory to define ionic liquids by their transport properties. J Phys Chem B 2007b; 111: 4910–4913.10.1021/jp0671998Search in Google Scholar PubMed

Abbott AP, Barron JC, Frisch G, Ryder KS, Silva AF. The effect of additives on zinc electrodeposition from deep eutectic solvents. Electrochimica Acta 2011a; 56: 5272–5279.10.1016/j.electacta.2011.02.095Search in Google Scholar

Abbott AP, Harris RC, Ryder KS, D’Agostino C, Gladden LF, Mantle MD. Glycerol eutectics as sustainable solvent systems. Green Chem 2011b; 13: 82–90.10.1039/C0GC00395FSearch in Google Scholar

Abbott AP, Ballantyne A, Harris RC, Juma JA, Ryder KS, Forrest G. A comparative study of nickel electrodeposition using deep eutectic solvents and aqueous solutions. Electrochimica Acta 2015; 176: 718–726.10.1016/j.electacta.2015.07.051Search in Google Scholar

Abo-Hamad A, Hayyan M, AlSaadi MA, Hashim MA. Potential applications of deep eutectic solvents in nanotechnology. Chem Eng J 2015; 273: 551–567.10.1016/j.cej.2015.03.091Search in Google Scholar

Aissaoui T. Novel contribution to the chemical structure of choline chloride based deep eutectic solvents. Pharm Anal Acta 2015; 6: 11.10.4172/2153-2435.1000448Search in Google Scholar

Aissaoui T, AlNashef IM. Neoteric FT-IR investigation on the functional groups of phosphonium-based deep eutectic solvents. Pharm Anal Acta 2015; 6: 11.10.4172/2153-2435.1000449Search in Google Scholar

Aissaoui T, AlNashef IM, Benguerba Y. Dehydration of natural gas using choline chloride based deep eutectic solvents: COSMO-RS prediction. J Nat Gas Sci Eng 2016; 30: 571–577.10.1016/j.jngse.2016.02.007Search in Google Scholar

Al-Lagtah NMA, Al-Habsi S, Onaizi SA. Optimization and performance improvement of Lekhwair natural gas sweetening plant using Aspen HYSYS. J Nat Gas Sci Eng 2015; 26: 367–381.10.1016/j.jngse.2015.06.030Search in Google Scholar

Al-Rashed OA, Ali SH. Modeling the solubility of CO2 and H2S in DEA-MDEA alkanolamine solutions using the electrolyte-UNIQUAC model. Sep Purif Technol 2012; 94: 71–83.10.1016/j.seppur.2012.04.007Search in Google Scholar

Ali E, Hadj-Kali MK, Mulyono S, Alnashef I, Fakeeha A, Mjalli F, Hayyan A. Solubility of CO2 in deep eutectic solvents: experiments and modelling using the Peng-Robinson equation of state. Chem Eng Res Des 2014; 92: 1898–1906.10.1016/j.cherd.2014.02.004Search in Google Scholar

Aljadri MAK. Novel deep eutectic solvents and their application in the liquid-liquid extraction of aromatic compounds. PhD thesis, University of Malaya, 2013.Search in Google Scholar

Anicai L, Petica A, Patroi D, Marinescu V, Prioteasa P, Costovici S. Electrochemical synthesis of nanosized TiO2 nanopowder involving choline chloride based ionic liquids. Mater Sci Eng B 2015; 199: 87–95.10.1016/j.mseb.2015.05.005Search in Google Scholar

Azizi N, Mariami M, Edrisi M. Greener construction of 4H-chromenes based dyes in deep eutectic solvent. Dyes Pigments 2014; 100: 215–221.10.1016/j.dyepig.2013.09.007Search in Google Scholar

Barzagli F, Mani F, Peruzzini M. Efficient CO2 absorption and low temperature desorption with non-aqueous solvents based on 2-amino-2-methyl-1-propanol (AMP). Int J Greenhouse Gas Control 2013; 16: 217–223.10.1016/j.ijggc.2013.03.026Search in Google Scholar

Bewley BR, Berkaliev A, Henriksen H, Ball DB, Ott LS. Waste glycerol from biodiesel synthesis as a component in deep eutectic solvents. Fuel Process Technol 2015; 138: 419–423.10.1016/j.fuproc.2015.05.025Search in Google Scholar

Boisset A, Jacquemin J, Anouti M. Physical properties of a new deep eutectic solvent based on lithium bis[(trifluoromethyl)sulfonyl]imide and N-methylacetamide as superionic suitable electrolyte for lithium ion batteries and electric double layer capacitors. Electrochimica Acta 2013; 102: 120–126.10.1016/j.electacta.2013.03.150Search in Google Scholar

Borhani TNG, Azarpour A, Akbari V, Wan Alwi SR, Manan ZA. CO2 capture with potassium carbonate solutions: a state-of-the-art review. Int J Greenhouse Gas Control 2015; 41: 142–162.10.1016/j.ijggc.2015.06.026Search in Google Scholar

Brakstad OG, Booth A, Eide-Haugmo I, Skjæran JA, Sørheim KR, Bonaunet K, Vang S-H, da Silva EF. Seawater biodegradation of alkanolamines used for CO2-capture from natural gas. Int J Greenhouse Gas Control 2012; 10: 271–277.10.1016/j.ijggc.2012.06.016Search in Google Scholar

Cao L, Huang J, Zhang X, Zhang S, Gao J, Zeng S. Imidazole tailored deep eutectic solvents for CO2 capture enhanced by hydrogen bonds. Phys Chem Chem Phys 2015; 17: 27306–27316.10.1039/C5CP04050GSearch in Google Scholar PubMed

Carriazo D, Serrano MC, Gutierrez MC, Ferrer ML, del Monte F. Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials. Chem Soc Rev 2012; 41: 4996–5014.10.1039/c2cs15353jSearch in Google Scholar PubMed

Chen Y, Ai N, Li G, Shan H, Cui Y, Deng D. Solubilities of carbon dioxide in eutectic mixtures of choline chloride and dihydric alcohols. J Chem Eng Data 2014; 59: 1247–1253.10.1021/je400884vSearch in Google Scholar

Chremos A, Forte E, Papaioannou V, Galindo A, Jackson G, Adjiman CS. Modelling the phase and chemical equilibria of aqueous solutions of alkanolamines and carbon dioxide using the SAFT-γ SW group contribution approach. Fluid Phase Equilibria 2016; 407: 280–297.10.1016/j.fluid.2015.07.052Search in Google Scholar

Constantin V, Adya AK, Popescu A-M. Density, transport properties and electrochemical potential windows for the 2-hydroxy-N,N,N-trimethylethanaminium chlorides based ionic liquids at several temperatures. Fluid Phase Equilibria 2015; 395: 58–66.10.1016/j.fluid.2015.03.025Search in Google Scholar

D'Agostino C, Harris RC, Abbott AP, Gladden LF, Mantle MD. Molecular motion and ion diffusion in choline chloride based deep eutectic solvents studied by 1H pulsed field gradient NMR spectroscopy. Phys Chem Chem Phys 2011; 13: 21383–21391.10.1039/c1cp22554eSearch in Google Scholar PubMed

Dai Y, van Spronsen J, Witkamp G-J, Verpoorte R, Choi YH. Natural deep eutectic solvents as new potential media for green technology. Analytica Chimica Acta 2013; 766: 61–68.10.1016/j.aca.2012.12.019Search in Google Scholar PubMed

Deng D, Han G, Jiang Y. Investigation of a deep eutectic solvent formed by levulinic acid with quaternary ammonium salt as an efficient SO2 absorbent. New J Chem 2015; 39: 8158–8164.10.1039/C5NJ01629KSearch in Google Scholar

Dinca C. Critical parametric study of circulating fluidized bed combustion with CO2 chemical absorption process using different aqueous alkanolamines. J Clean Prod 2016; 112: 1136–1149.10.1016/j.jclepro.2015.06.051Search in Google Scholar

Dinca C, Badea A, Stoica L, Pascu A. Absorber design for the improvement of the efficiency of post-combustion CO2 capture. J Energy Inst 2015; 88: 304–313.10.1016/j.joei.2014.08.003Search in Google Scholar

Figueroa JD, Fout T, Plasynski S, McIlvried H, Srivastava RD. Advances in CO2 capture technology – The U.S. Department of Energy’s Carbon Sequestration Program. Int J Greenhouse Gas Control 2008; 2: 9–20.10.1016/S1750-5836(07)00094-1Search in Google Scholar

Foo CK, Leo CY, Aramesh R, Aroua MK, Aghamohammadi N, Shafeeyan MS, Shamiri A. Density and viscosity of aqueous mixtures of N-methyldiethanolamines (MDEA), piperazine (PZ) and ionic liquids. J Mol Liq 2015; 209: 596–602.10.1016/j.molliq.2015.05.041Search in Google Scholar

Francisco M, van den Bruinhorst A, Zubeir LF, Peters CJ, Kroon MC. A new low transition temperature mixture (LTTM) formed by choline chloride+lactic acid: characterization as solvent for CO2 capture. Fluid Phase Equilibria 2013; 340: 77–84.10.1016/j.fluid.2012.12.001Search in Google Scholar

Frazier HD, Kohl AL. Selective absorption of hydrogen sulfide from gas streams. Ind Eng Chem 1950; 42: 2282.10.1021/ie50491a032Search in Google Scholar

Fu D, Zhang P. Investigation of the absorption performance and viscosity for CO2 capture process using [Bmim][Gly] promoted MDEA (N-methyldiethanolamine) aqueous solution. Energy 2015; 87: 165–172.10.1016/j.energy.2015.04.099Search in Google Scholar

Gao J, Cao L, Dong H, Zhang X, Zhang S. Ionic liquids tailored amine aqueous solution for pre-combustion CO2 capture: role of imidazolium-based ionic liquids. Appl Energy 2015; 154: 771–780.10.1016/j.apenergy.2015.05.073Search in Google Scholar

García G, Aparicio S, Ullah R, Atilhan M. Deep eutectic solvents: physicochemical properties and gas separation applications. Energy Fuels 2015a; 29: 2616–2644.10.1021/ef5028873Search in Google Scholar

García G, Atilhan M, Aparicio S. An approach for the rationalization of melting temperature for deep eutectic solvents from DFT. Chem Phys Lett 2015b; 634: 151–155.10.1016/j.cplett.2015.06.017Search in Google Scholar

García G, Atilhan M, Aparicio S. The impact of charges in force field parameterization for molecular dynamics simulations of deep eutectic solvents. J Mol Liq 2015c; 211: 506–514.10.1016/j.molliq.2015.07.070Search in Google Scholar

García G, Atilhan M, Aparicio S. A theoretical study on mitigation of CO2 through advanced deep eutectic solvents. Int J Greenhouse Gas Control 2015d; 39: 62–73.10.1016/j.ijggc.2015.05.004Search in Google Scholar

Ghareh Bagh FS, Shahbaz K, Mjalli FS, AlNashef IM, Hashim MA. Electrical conductivity of ammonium and phosphonium based deep eutectic solvents: measurements and artificial intelligence-based prediction. Fluid Phase Equilibria 2013; 356: 30–37.10.1016/j.fluid.2013.07.012Search in Google Scholar

Ghareh Bagh FS, Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM. Zinc (II) chloride-based deep eutectic solvents for application as electrolytes: preparation and characterization. J Mol Liq 2015; 204: 76–83.10.1016/j.molliq.2015.01.025Search in Google Scholar

Gu L, Huang W, Tang S, Tian S, Zhang X. A novel deep eutectic solvent for biodiesel preparation using a homogeneous base catalyst. Chem Eng J 2015; 259: 647–652.10.1016/j.cej.2014.08.026Search in Google Scholar

Hadj-Kali MK, Al-khidir KE, Wazeer I, El-blidi L, Mulyono S, AlNashef IM. Application of deep eutectic solvents and their individual constituents as surfactants for enhanced oil recovery. Colloid Surf A Physicochem Eng Aspects 2015; 487: 221–231.10.1016/j.colsurfa.2015.10.005Search in Google Scholar

Hayyan M, Mjalli FS, Hashim MA, AlNashef IM. A novel technique for separating glycerine from palm oil-based biodiesel using ionic liquids. Fuel Process Technol 2010; 91: 116–120.10.1016/j.fuproc.2009.09.002Search in Google Scholar

Hayyan A, Mjalli FS, AlNashef IM, Al-Wahaibi T, Al-Wahaibi YM, Hashim MA. Fruit sugar-based deep eutectic solvents and their physical properties. Thermochimica Acta 2012; 541: 70–75.10.1016/j.tca.2012.04.030Search in Google Scholar

Hayyan A, Hashim MA, Hayyan M, Mjalli FS, AlNashef IM. A novel ammonium based eutectic solvent for the treatment of free fatty acid and synthesis of biodiesel fuel. Ind Crops Prod 2013a; 46: 392–398.10.1016/j.indcrop.2013.01.033Search in Google Scholar

Hayyan A, Hashim MA, Mjalli FS, Hayyan M, AlNashef IM. A novel phosphonium-based deep eutectic catalyst for biodiesel production from industrial low grade crude palm oil. Chem Eng Sci 2013b; 92: 81–88.10.1016/j.ces.2012.12.024Search in Google Scholar

Hayyan A, Mjalli FS, AlNashef IM, Al-Wahaibi YM, Al-Wahaibi T, Hashim MA. Glucose-based deep eutectic solvents: physical properties. J Mol Liq 2013c; 178: 137–141.10.1016/j.molliq.2012.11.025Search in Google Scholar

Hayyan M, Hashim MA, Al-Saadi MA, Hayyan A, AlNashef IM, Mirghani MES. Assessment of cytotoxicity and toxicity for phosphonium-based deep eutectic solvents. Chemosphere 2013d; 9: 455–459.10.1016/j.chemosphere.2013.05.013Search in Google Scholar PubMed

Hayyan M, Hashim MA, Hayyan A, Al-Saadi MA, AlNashef IM, Mirghani MES, Saheed OK. Are deep eutectic solvents benign or toxic? Chemosphere 2013e; 90: 2193–2195.10.1016/j.chemosphere.2012.11.004Search in Google Scholar PubMed

Hayyan A, Hashim MA, Hayyan M, Mjalli FS, AlNashef IM. A new processing route for cleaner production of biodiesel fuel using a choline chloride based deep eutectic solvent. J Clean Prod 2014; 65: 246–251.10.1016/j.jclepro.2013.08.031Search in Google Scholar

Hayyan M, Aissaoui T, Hashim MA, AlSaadi MA, Hayyan A. Triethylene glycol based deep eutectic solvents and their physical properties. J Taiwan Inst Chem Eng 2015; 50: 24–30.10.1016/j.jtice.2015.03.001Search in Google Scholar

Hizaddin HF, Hadj-Kali MK, AlNashef IM, Mjalli FS, Hashim MA. Prediction of CO2 solubility in ionic liquids using the PSRK model. J Supercrit Fluids 2015; 100: 184–193.10.1016/j.supflu.2015.02.009Search in Google Scholar

Hou Y, Gu Y, Zhang S, Yang F, Ding H, Shan Y. Novel binary eutectic mixtures based on imidazole. J Mol Liq 2008; 143: 154–159.10.1016/j.molliq.2008.07.009Search in Google Scholar

Hsu Y-H, Leron RB, Li M-H. Solubility of carbon dioxide in aqueous mixtures of (reline+monoethanolamine) at T=(313.2 to 353.2) K. J Chem Thermodynamics 2014; 72: 94–99.10.1016/j.jct.2014.01.011Search in Google Scholar

Huang Z-L, Wu B-P, Wen Q, Yang T-X, Yanga Z. Deep eutectic solvents can be viable enzyme activators and stabilizers. J Chem Technol Biotechnol 2014; 89: 1975–1981.10.1002/jctb.4285Search in Google Scholar

Iliuta I, Hasib-ur-Rahman M, Larachi F. CO2 absorption in diethanolamine/ionic liquid emulsions – chemical kinetics and mass transfer study. Chem Eng J 2014; 240: 16–23.10.1016/j.cej.2013.11.063Search in Google Scholar

Ji X, Xie Y, Zhang Y, Lu X. CO2 capture/separation using choline chloride-based ionic liquids. 13th International Conference on Properties and Phase Equilibria for Products and Process Design, Brazil, 2013.Search in Google Scholar

Jibril B, Mjalli F, Naser J, Gano Z. New tetrapropylammonium bromide-based deep eutectic solvents: synthesis and characterizations. J Mol Liq 2014; 199: 462–469.10.1016/j.molliq.2014.08.004Search in Google Scholar

Kareem MA, Mjalli FS, Hashim MA, AlNashef IM. Phosphonium-based ionic liquids analogues and their physical properties. J Chem Eng Data 2010; 55: 4632–4637.10.1021/je100104vSearch in Google Scholar

Kim G, Choi W, Lee C-H, Lee K. Enhancement of dissolved inorganic carbon and carbon fixation by green alga Scenedesmus sp. in the presence of alkanolamine CO2 absorbents. Biochem Eng J 2013; 78: 18–23.10.1016/j.bej.2013.02.010Search in Google Scholar

Kleiner B, Fleischer P, Schörken U. Biocatalytic synthesis of biodiesel utilizing deep eutectic solvents: a two-step-one-pot approach with free lipases suitable for acidic and used oil processing. Process Biochem 2016; 51: 1808–1816.10.1016/j.procbio.2015.10.016Search in Google Scholar

Kohl AL, Nielsen RB, editors. Chapter 2. Alkanolamines for hydrogen sulfide and carbon dioxide removal. In: Gas purification, 5th ed. Houston: Gulf Professional Publishing, 1997: 40–186.10.1016/B978-088415220-0/50002-1Search in Google Scholar

Kohl AL, Riesenfeld FC. Gas purification. Houston: Gulf Publishing, 1985.Search in Google Scholar

Kow K-K, Sirat K. Novel manganese(II)-based deep eutectic solvents: synthesis and physical properties analysis. Chin Chem Lett 2015; 26: 1311–1314.10.1016/j.cclet.2015.05.049Search in Google Scholar

Kudłak B, Owczarek K, Namieśnik J. Selected issues related to the toxicity of ionic liquids and deep eutectic solvents – a review. Environ Sci Pollut Res Int 2015; 22: 11975–11992.10.1007/s11356-015-4794-ySearch in Google Scholar PubMed

Kumar-Krishnan S, Prokhorov E, Arias de Fuentes O, Ramirez M, Bogdanchikova N, Sanchez IC, Mota-Morales JD, Luna-Barcenas G. Temperature-induced Au nanostructure synthesis in a nonaqueous deep-eutectic solvent for high performance electrocatalysis. J Mater Chem A 2015; 3: 15869–15875.10.1039/C5TA02606GSearch in Google Scholar

Leron RB, Li M-H. High-pressure density measurements for choline chloride: urea deep eutectic solvent and its aqueous mixtures at T=(298.15 to 323.15) K and up to 50 MPa. J Chem Thermodyn 2012; 54: 293–301.10.1016/j.jct.2012.05.008Search in Google Scholar

Leron RB, Soriano AN, Li M-H. Densities and refractive indices of the deep eutectic solvents (choline chloride+ethylene glycol or glycerol) and their aqueous mixtures at the temperature ranging from 298.15 to 333.15K. J Taiwan Inst Chem Eng 2012; 43: 551–557.10.1016/j.jtice.2012.01.007Search in Google Scholar

Leron RB, Li M-H. Solubility of carbon dioxide in a choline chloride–ethylene glycol based deep eutectic solvent. Thermochimica Acta 2013a; 551: 14–19.10.1016/j.tca.2012.09.041Search in Google Scholar

Leron RB, Li M-H. Solubility of carbon dioxide in a eutectic mixture of choline chloride and glycerol at moderate pressures. J Chem Thermodyn 2013b; 57: 131–136.10.1016/j.jct.2012.08.025Search in Google Scholar

Leron RB, Caparanga A, Li M-H. Carbon dioxide solubility in a deep eutectic solvent based on choline chloride and urea at T=303.15–343.15K and moderate pressures. J Taiwan Inst Chem Eng 2013; 44: 879–885.10.1016/j.jtice.2013.02.005Search in Google Scholar

Leroy E, Decaen P, Jacquet P, Coativy G, Pontoire B, Reguerre A-L, Lourdinb D. Deep eutectic solvents as functional additives for starch based plastics. Green Chem 2012; 14: 3063–3066.10.1039/c2gc36107hSearch in Google Scholar

Li X, Hou M, Han B, Wang X, Zou L. Solubility of CO2 in a choline chloride+urea eutectic mixture. J Chem Eng Data 2008; 53: 548−550.10.1021/je700638uSearch in Google Scholar

Li G, Deng D, Chen Y, Shan H, Ai N. Solubilities and thermodynamic properties of CO2 in choline-chloride based deep eutectic solvents. J Chem Thermodyn 2014; 75: 58–62.10.1016/j.jct.2014.04.012Search in Google Scholar

Li R, Chu Q, Liang J. Electrodeposition and characterization of Ni-SiC composite coatings from deep eutectic solvent. RSC Adv 2015a; 5: 44933–44942.10.1039/C5RA05918FSearch in Google Scholar

Li R, Liang J, Hou Y, Chu Q. Enhanced corrosion performance of Zn coating by incorporating graphene oxide electrodeposited from deep eutectic solvent. RSC Adv 2015b; 5: 60698–60707.10.1039/C5RA11577ASearch in Google Scholar

Li B-H, Zhang N, Smith R. Simulation and analysis of CO2 capture process with aqueous monoethanolamine solution. Appl Energy 2016; 161: 707–717.10.1016/j.apenergy.2015.07.010Search in Google Scholar

Liang Z, Rongwong W, Liu H, Fu K, Gao H, Cao F, Zhang R, Sema T, Henni A, Sumon K, Nath D, Gelowitz D, Srisang W, Saiwan C, Benamor A, Al-Marri M, Shi H, Supap T, Chan C, Zhou Q, Abu-Zahra M, Wilson M, Olson W, Idem R, Tontiwachwuthikul P. Recent progress and new developments in post-combustion carbon-capture technology with amine based solvents. Int J Greenhouse Gas Control 2015; 40: 26–54.10.1016/j.ijggc.2015.06.017Search in Google Scholar

Lin C-M, Leron RB, Caparanga AR, Li M-H. Henry’s constant of carbon dioxide-aqueous deep eutectic solvent (choline chloride/ethylene glycol, choline chloride/glycerol, choline chloride/malonic acid) systems. J Chem Thermodyn 2014; 68: 216–220.10.1016/j.jct.2013.08.029Search in Google Scholar

Lindberg D, de la Fuente Revenga M, Widersten M. Deep eutectic solvents (DESs) are viable cosolvents for enzyme-catalyzed epoxide hydrolysis. J Biotechnol 2010; 147: 169–171.10.1016/j.jbiotec.2010.04.011Search in Google Scholar PubMed

Liu L, Zhao C, Xu J, Li Y. Integrated CO2 capture and photocatalytic conversion by a hybrid adsorbent/photocatalyst material. Appl Catal B Environ 2015; 179: 489–499.10.1016/j.apcatb.2015.06.006Search in Google Scholar

Long T, Deng Y, Gan S, Chen J. Application of choline chloride·xZnCl2 ionic liquids for preparation of biodiesel. Chinese J Chem Eng 2010; 18: 322–327.10.1016/S1004-9541(08)60359-6Search in Google Scholar

Lu J-G, Zheng Y-F, He D-L. Selective absorption of H2S from gas mixtures into aqueous solutions of blended amines of methyldiethanolamine and 2-tertiarybutylamino-2-ethoxyethanol in a packed column. Sep Purif Technol 2006; 52: 209–217.10.1016/j.seppur.2006.04.003Search in Google Scholar

Lu J-G, Lu C-T, Chen Y, Gao L, Zhao X, Zhang H, Xu Z-W. CO2 capture by membrane absorption coupling process: application of ionic liquids. Appl Energy 2014; 115: 573–581.10.1016/j.apenergy.2013.10.045Search in Google Scholar

Lu M, Han G, Jiang Y, Zhang X, Deng D, Ai N. Solubilities of carbon dioxide in the eutectic mixture of levulinic acid (or furfuryl alcohol) and choline chloride. J Chem Thermodyn 2015a; 88: 72–77.10.1016/j.jct.2015.04.021Search in Google Scholar

Lu J-G, Lu Z-Y, Gao L, Cao S, Wang J-T, Gao X, Tang Y-Q, Tan W-Y. Property of diethanolamine glycinate ionic liquid and its performance for CO2 capture. J Mol Liq 2015b; 211: 1–6.10.1016/j.molliq.2015.06.059Search in Google Scholar

Luis P, Van Gerven T, Van der Bruggen B. Recent developments in membrane-based technologies for CO2 capture. Prog Energy Combust Sci 2012; 38: 419–448.10.1016/j.pecs.2012.01.004Search in Google Scholar

Luo J, Conrad O, Vankelecom IFJ. Physicochemical properties of phosphonium-based and ammonium-based protic ionic liquids. J Mater Chem 2012; 22: 20574–20579.10.1039/c2jm34359bSearch in Google Scholar

Lv B, Shi Y, Sun C, Liu N, Li W, Li S. CO2 capture by a highly-efficient aqueous blend of monoethanolamine and a hydrophilic amino acid ionic liquid [C2OHmim][Gly]. Chem Eng J 2015a; 270: 372–377.10.1016/j.cej.2015.02.010Search in Google Scholar

Lv B, Sun C, Liu N, Li W, Li S. Mass transfer and kinetics of CO2 absorption into aqueous monoethanolamine/1-hydroxyethy-3-methyl imidazolium glycinate solution. Chem Eng J 2015b; 280: 695–702.10.1016/j.cej.2015.06.004Search in Google Scholar

Malaquias JC, Steichen M, Dale PJ. One-step electrodeposition of metal precursors from a deep eutectic solvent for Cu(In,Ga)Se2 thin film solar cells. Electrochimica Acta 2015; 151: 150–156.10.1016/j.electacta.2014.11.089Search in Google Scholar

Mandal BP, Biswas AK, Bandyopadhyay SS. Selective absorption of H2S from gas streams containing H2S and CO2 in aqueous solutions of N-methyldiethanolamine and 2-amino-2-methyl-1-propanol. Sep Purif Technol 2004; 35: 191–202.10.1016/S1383-5866(03)00139-4Search in Google Scholar

Maugeri Z, Dominguez de Maria P. Novel choline-chloride-based deep-eutectic-solvents with renewable hydrogen bond donors: levulinic acid and sugar-based polyols. RSC Adv 2012; 2: 421–425.10.1039/C1RA00630DSearch in Google Scholar

McCann N, Maeder M, Attalla M. Simulation of enthalpy and capacity of CO2 absorption by aqueous amine systems. Ind Eng Chem Res 2008; 47: 2002–2009.10.1021/ie070619aSearch in Google Scholar

Mjalli FS, Vakili-Nezhaad G, Shahbaz K, AlNashef IM. Application of the Eötvos and Guggenheim empirical rules for predicting the density and surface tension of ionic liquids analogues. Thermochimica Acta 2014; 575: 40–44.10.1016/j.tca.2013.10.017Search in Google Scholar

Mohsenzadeh A, Al-Wahaibi Y, Al-Hajri R, Jibril B, Joshi S, Pracejus B. Investigation of formation damage by deep eutectic solvents as new EOR agents. J Petrol Sci Eng 2015a; 129: 130–136.10.1016/j.petrol.2015.02.035Search in Google Scholar

Mohsenzadeh A, Al-Wahaibi Y, Jibril A, Al-Hajri R, Shuwa S. The novel use of deep eutectic solvents for enhancing heavy oil recovery. J Petrol Sci Eng 2015b; 130: 6–15.10.1016/j.petrol.2015.03.018Search in Google Scholar

Mokhatab S, Poe WA. Handbook of natural gas transmission and processing. Waltham, MA: Elsevier, 2012.10.1016/B978-0-12-386914-2.00012-1Search in Google Scholar

Mondal MK, Balsora HK, Varshney P. Progress and trends in CO2 capture/separation technologies: a review. Energy 2012; 46: 431–441.10.1016/j.energy.2012.08.006Search in Google Scholar

Morrison HG, Sun CC, Neervannan S. Characterization of thermal behavior of deep eutectic solvents and their potential as drug solubilization vehicles. Int J Pharm 2009; 378: 136–139.10.1016/j.ijpharm.2009.05.039Search in Google Scholar PubMed

Mukesh C, Mondal D, Sharma M, Prasad K. Choline chloride-thiourea, a deep eutectic solvent for the production of chitin nanofibers. Carbohydr Polym 2014; 103: 466–471.10.1016/j.carbpol.2013.12.082Search in Google Scholar PubMed

Najafloo A, Zoghi AT, Feyzi F. Measuring solubility of carbon dioxide in aqueous blends of N-methyldiethanolamine and 2-((2-aminoethyl)amino)ethanol at low CO2 loadings and modelling by electrolyte SAFT-HR EoS. J Chem Thermodyn 2015; 82: 143–155.10.1016/j.jct.2014.11.006Search in Google Scholar

Paiva A, Craveiro R, Aroso I, Martins M, Reis RL, Duarte ARC. Natural deep eutectic solvents – solvents for the 21st century. ACS Sustainable Chem Eng 2014; 2: 1063–1071.10.1021/sc500096jSearch in Google Scholar

Pal P, AbuKashabeh A, Al-Asheh S, Banat F. Role of aqueous methyldiethanolamine (MDEA) as solvent in natural gas sweetening unit and process contaminants with probable reaction pathway. J Nat Gas Sci Eng 2015; 24: 124–131.10.1016/j.jngse.2015.03.007Search in Google Scholar

Pedram MZ, Omidkhah M, Amooghin AE. Synthesis and characterization of diethanolamine-impregnated cross-linked polyvinylalcohol/glutaraldehyde membranes for CO2/CH4 separation. J Ind Eng Chem 2014; 20: 74–82.10.1016/j.jiec.2013.04.024Search in Google Scholar

Perkins SL, Painter P, Colina CM. Molecular dynamic simulations and vibrational analysis of an ionic liquid analogue. J Phys Chem B 2013; 117: 10250–10260.10.1021/jp404619xSearch in Google Scholar PubMed

Radošević K, Bubalo MC, Srček VG, Grgas D, Dragičević TL, Redovniković IR. Evaluation of toxicity and biodegradability of choline chloride based deep eutectic solvents. Ecotoxicol Environ Saf 2015; 112: 46–53.10.1016/j.ecoenv.2014.09.034Search in Google Scholar PubMed

Raghuwanshi VS, Ochmann M, Hoell A, Polzer F, Rademann K. Deep eutectic solvents for the self-assembly of gold nanoparticles: a SAXS, UV-Vis, and TEM investigation. Langmuir 2014; 30: 6038–6046.10.1021/la500979pSearch in Google Scholar PubMed

Rengstl D, Fischer V, Kunz W. Low-melting mixtures based on choline ionic liquids. Phys Chem Chem Phys 2014; 16: 22815–22822.10.1039/C4CP02860KSearch in Google Scholar PubMed

Ru C, Konig B. Low melting mixtures in organic synthesis – an alternative to ionic liquids? Green Chem 2012; 14: 2969–2982.10.1039/c2gc36005eSearch in Google Scholar

Ru J, Hua Y, Xu C, Li J, Li Y, Wang D, Gong K, Zhou Z. Preparation of sub-micrometer lead wires from PbO by electrodeposition in choline chloride-urea deep eutectic solvent. Adv Powder Technol 2015a; 26: 91–97.10.1016/j.apt.2014.08.008Search in Google Scholar

Ru J, Hua Y, Xu C, Li J, Li Y, Wang D, Qi C, Jie Y. Morphology-controlled preparation of lead powders by electrodeposition from different PbO-containing choline chloride-urea deep eutectic solvent. Appl Surf Sci 2015b; 335: 153–159.10.1016/j.apsusc.2015.02.045Search in Google Scholar

Sabouni R, Kazemian H, Rohani S. Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs). Environ Sci Pollut Res 2014; 21: 5427–5449.10.1007/s11356-013-2406-2Search in Google Scholar PubMed

Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM. Using deep eutectic solvents for the removal of glycerol from palm oil-based biodiesel. J Appl Sci 2010; 10: 3349−3354.10.3923/jas.2010.3349.3354Search in Google Scholar

Shabaz K, Mjalli FS, Hashim MA, AlNashef IM. Using deep eutectic solvents based on methyl triphenyl phosphonium bromide for the removal of glycerol from palm-oil-based biodiesel. Energy Fuels 2011; 25: 2671−2678.10.1021/ef2004943Search in Google Scholar

Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM. Eutectic solvents for the removal of residual palm oil-based biodiesel catalyst. Sep Purif Technol 2011a; 81: 216–222.10.1016/j.seppur.2011.07.032Search in Google Scholar

Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM. Prediction of deep eutectic solvents densities at different temperatures. Thermochimica Acta 2011b; 515: 67–72.10.1016/j.tca.2010.12.022Search in Google Scholar

Shahbaz K, Baroutian S, Mjalli FS, Hashim MA, AlNashef IM. Densities of ammonium and phosphonium based deep eutectic solvents: prediction using artificial intelligence and group contribution techniques. Thermochimica Acta 2012a; 527: 59–66.10.1016/j.tca.2011.10.010Search in Google Scholar

Shahbaz K, Baroutian S, Mjalli FS, Hashim MA, AlNashef IM. Prediction of glycerol removal from biodiesel using ammonium and phosphunium based deep eutectic solvents using artificial intelligence techniques. Chemom Intell Lab Syst 2012b; 118: 193–199.10.1016/j.chemolab.2012.06.005Search in Google Scholar

Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM. Prediction of the surface tension of deep eutectic solvents. Fluid Phase Equilibria 2012c; 319: 48–54.10.1016/j.fluid.2012.01.025Search in Google Scholar

Shahbaz K, Bagh FSG, Mjalli FS, AlNashef IM, Hashim MA. Prediction of refractive index and density of deep eutectic solvents using atomic contributions. Fluid Phase Equilibria 2013; 354: 304–311.10.1016/j.fluid.2013.06.050Search in Google Scholar

Shojaeian A, Haghtalab A. Solubility and density of carbon dioxide in different aqueous alkanolamine solutions blended with 1-butyl-3-methylimidazolium acetate ionic liquid at high pressure. J Mol Liq 2013; 187: 218–225.10.1016/j.molliq.2013.07.016Search in Google Scholar

Singh BS, Lobo HR, Pinjari DV, Jarag KJ, Pandit AB, Shankarling GS. Ultrasound and deep eutectic solvent (DES): a novel blend of techniques for rapid and energy efficient synthesis of oxazoles. Ultrason Sonochem 2013; 20: 287–293.10.1016/j.ultsonch.2012.06.003Search in Google Scholar PubMed

Siongco KR, Leron RB, Li M-H. Densities, refractive indices, and viscosities of N,N-diethylethanol ammonium chloride-glycerol or -ethylene glycol deep eutectic solvents and their aqueous solutions. J Chem Thermodyn 2013; 65: 65–72.10.1016/j.jct.2013.05.041Search in Google Scholar

Smith EL, Abbott AP, Ryder KS. Deep eutectic solvents (DESs) and their applications. Chem Rev 2014; 114: 11060–11082.10.1021/cr300162pSearch in Google Scholar PubMed

Song G, Zhu X, Chen R, Liao Q, Ding Y-D, Chen L. An investigation of CO2 adsorption kinetics on porous magnesium oxide. Chem Eng J 2016; 283: 175–183.10.1016/j.cej.2015.07.055Search in Google Scholar

Su WC, Wong DSH, Li MH. Effect of water on solubility of carbon dioxide in (aminomethanamide+2-hydroxy-N,N,N-trimethylethanaminium chloride). J Chem Eng Data 2009; 54: 1951–1955.10.1021/je900078kSearch in Google Scholar

Sze LL, Pandey S, Ravula S, Pandey S, Zhao H, Baker GA, Baker SN. Ternary deep eutectic solvents tasked for carbon dioxide capture. ACS Sustainable Chem Eng 2014; 2: 2117–2123.10.1021/sc5001594Search in Google Scholar

Tohidi M, Mahyari FA, Safavi A. A seed-less method for synthesis of ultra-thin gold nanosheets by using a deep eutectic solvent and gum arabic and their electrocatalytic application. RSC Advances 2015; 5: 32744–32754.10.1039/C4RA17053ASearch in Google Scholar

Trivedi TJ, Lee JH, Hyeon JL, Jeong YK, Choi JW. Deep eutectic solvents as attractive media for CO2 capture. Green Chem 2016; 18: 2834–2842.10.1039/C5GC02319JSearch in Google Scholar

Ullah R, Atilhan M, Anaya B, Khraisheh M, Garcia G, ElKhattat A, Tariq M, Aparicio S. A detailed study of cholinium chloride and levulinic acid deep eutectic solvent system for CO2 capture via experimental and molecular simulation approaches. Phys Chem Chem Phys 2015; 17: 20941–20960.10.1039/C5CP03364KSearch in Google Scholar PubMed

Uma Maheswari A, Palanivelu K. Carbon dioxide capture and utilization by alkanolamines in deep eutectic solvent medium. Ind Eng Chem Res 2015; 54: 11383−11392.10.1021/acs.iecr.5b01818Search in Google Scholar

Wang GN, Dai Y, Hu XB, Xiao F, Wu YT, Zhang ZB, Zhou Z. Novel ionic liquid analogs formed by triethylbutylammonium carboxylate-water mixtures for CO2 absorption. J Mol Liq 2012a; 168: 17–20.10.1016/j.molliq.2011.12.006Search in Google Scholar

Wang H, Jing Y, Wang X, Yao Y, Jia Y. Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride. J Mol Liquids 2012b; 170: 20–24.10.1016/j.molliq.2012.03.017Search in Google Scholar

Wang D, Tian P, Yang M, Xu S, Fan D, Su X, Yang Y, Wang C, Liu Z. Synthesis of SAPO-34 with alkanolamines as novel templates and their application for CO2 separation. Micropor Mesopor Mat 2014; 194: 8–14.10.1016/j.micromeso.2014.03.028Search in Google Scholar

Wang L, Zhu K-Q, Chen Q, He M-Y. Facile and environmentally friendly halogenation of BODIPYs in deep eutectic solvent. Dyes Pigments 2015; 112: 274–279.10.1016/j.dyepig.2014.07.024Search in Google Scholar

Wen Q, Chen J-X, Tang Y-L, Wang J, Yang Z. Assessing the toxicity and biodegradability of deep eutectic solvents. Chemosphere 2015; 132: 63–69.10.1016/j.chemosphere.2015.02.061Search in Google Scholar PubMed

Wu S-H, Caparanga AR, Leron RB, Li M-H. Vapor pressure of aqueous choline chloride-based deep eutectic solvents (ethaline, glyceline, maline and reline) at 30–70°C. Thermochimica Acta 2012; 544: 1–5.10.1016/j.tca.2012.05.031Search in Google Scholar

Xie H, Wang P, He N, Yang X, Chen J. Toward rational design of amines for CO2 capture: substituent effect on kinetic process for the reaction of monoethanolamine with CO2. J Environ Sci 2015; 37: 75–82.10.1016/j.jes.2015.03.033Search in Google Scholar

Xie Y, Dong H, Zhang S, Lu X, Ji X. Effect of water on the density, viscosity, and CO2 solubility in choline chloride/urea. J Chem Eng Data 2014; 59: 3344–3352.10.1021/je500320cSearch in Google Scholar

Xiong QQ, Tu JP, Ge X, Wang XL, Gu CD. One-step synthesis of hematite nanospindles from choline chloride/urea deep eutectic solvent with highly powerful storage versus lithium. J Power Sources 2015; 274: 1–7.10.1016/j.jpowsour.2014.10.020Search in Google Scholar

Yadav A, Trivedi S, Rai R, Pandey S. Densities and dynamic viscosities of (choline chloride+glycerol) deep eutectic solvent and its aqueous mixtures in the temperature range (283.15–363.15) K. Fluid Phase Equilibria 2014; 367: 135–142.10.1016/j.fluid.2014.01.028Search in Google Scholar

Yadav A, Kar JR, Verma M, Naqvi S, Pandey S. Densities of aqueous mixtures of (choline chloride+ethylene glycol) and (choline chloride+malonic acid) deep eutectic solvents in temperature range 283.15–363.15 K. Thermochimica Acta 2015; 600: 95–101.10.1016/j.tca.2014.11.028Search in Google Scholar

Yancheshmeh MS, Radfarnia HR, Iliuta MC. High temperature CO2 sorbents and their application for hydrogen production by sorption enhanced steam reforming process. Chem Eng J 2016; 283: 420–444.10.1016/j.cej.2015.06.060Search in Google Scholar

Yang H, Xu Z, Fan M, Gupta R, Slimane RB, Bland AE, Wright I. Progress in carbon dioxide separation and capture: a review. J Environ Sci 2008; 20: 14–27.10.1016/S1001-0742(08)60002-9Search in Google Scholar

Yang Z-Z, He L-N, Zhao Y-N, Li B, Yu B. CO2 capture and activation by superbase/polyethylene glycol and its subsequent conversion. Energy Environ Sci 2011; 4: 3971−3975.10.1039/c1ee02156gSearch in Google Scholar

Yang DH, Hou M, Ning H, Zhang J, Ma J, Yang G, Han B. Efficient SO2 absorption by renewable choline chloride-glycerol deep eutectic solvents. Green Chem 2013; 15: 2261–2265.10.1039/c3gc40815aSearch in Google Scholar

Yu C-H, Tan C-S. CO2 capture by aqueous solution containing mixed alkanolamines and diethylene glycol in a rotating packed bed. Energy Procedia 2014; 63: 758–764.10.1016/j.egypro.2014.11.084Search in Google Scholar

Yue D, Jia Y, Yao Y, Sun J, Jing Y. Structure and electrochemical behavior of ionic liquid analogue based on choline chloride and urea. Electrochimica Acta 2012; 65: 30–36.10.1016/j.electacta.2012.01.003Search in Google Scholar

Zhang Q, De Oliveira Vigier K, Royer SB, Jerome F. Deep eutectic solvents: syntheses, properties and applications. Chem Soc Rev 2012; 41: 7108–7146.10.1039/c2cs35178aSearch in Google Scholar PubMed

Zhang C, Jia Y, Jing Y, Wang H, Hong K. Main chemical species and molecular structure of deep eutectic solvent studied by experiments with DFT calculation: a case of choline chloride and magnesium chloride hexahydrate. J Mol Model 2014; 20: 1–8.10.1007/s00894-014-2374-6Search in Google Scholar PubMed

Zhang QB, Abbott AP, Yang C. Electrochemical fabrication of nanoporous copper films in choline chloride-urea deep eutectic solvent. Phys Chem Chem Phys 2015; 17: 14702–14709.10.1039/C5CP01276GSearch in Google Scholar PubMed

Zhao H, Baker GA, Holmes S. New eutectic ionic liquids for lipase activation and enzymatic preparation of biodiesel. Org Biomol Chem 2011; 9: 1908–1916.10.1039/c0ob01011aSearch in Google Scholar PubMed PubMed Central

Zhao H, Zhang C, Crittle TD. Choline-based deep eutectic solvents for enzymatic preparation of biodiesel from soybean oil. J Mol Catal B 2013; 85–86: 243–247.10.1016/j.molcatb.2012.09.003Search in Google Scholar

Zhao Z, Dong H, Huang Y, Cao L, Gao J, Zhang X, Zhang S. Ionic degradation inhibitors and kinetic models for CO2 capture with aqueous monoethanolamine. Int J Greenhouse Gas Control 2015; 39: 119–128.10.1016/j.ijggc.2015.05.001Search in Google Scholar

Zubeir LF, Lacroix MHM, Kroon MC. Low transition temperature mixtures as innovative and sustainable CO2 capture solvents. J Phys Chem B 2014; 118: 14429–14441.10.1021/jp5089004Search in Google Scholar PubMed

Received: 2016-2-29
Accepted: 2016-10-18
Published Online: 2017-1-25
Published in Print: 2017-11-27

©2017 Walter de Gruyter GmbH, Berlin/Boston

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