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Mn(II) and Cu(II) metal complexes with bisamine based bidentate ligand. Spectroscopic investigation, biological activity and gamma ray irradiation impact

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Published/Copyright: July 9, 2025
Radiochimica Acta
From the journal Radiochimica Acta Volume 113 Issue 9

Abstract

Mononuclear [Mn(L)Cl2(H2O)2].1½H2O (1), [Cu(L)Cl2(H2O)2] (2) and [Cu(L)Br2(H2O)2].2H2O (3) complexes were obtained via reaction of N,N’-(1,2-phenylene)bis (2-aminobenzamide (L) with Mn(II), Cu(II) halides, respectively. The structure of these metal chelates were confirmed using the various microanalyses and physiochemical tools as molar conductance, FT–IR spectra, thermogravimetric analysis (TG/DTG), UV–Vis, EPR, magnetic moment measurements, 3D molecular modeling and X–ray diffraction. The ligand forms hexacoordinated complexes having octahedral stereochemistry for all complexes. Gamma ray irradiation was applied to solid samples of complexes to examine the possible structure changes with γ–ray exposures (hereafter pointed to as 1A, 2A, 3A, respectively). The physical and chemical changes observed for γ–irradiated samples were examined by the same tools utilized for the as-prepared complexes. Spectroscopic results showed distortion of complex structure by γ–ray irradiation. TG/DTG results indicated that, thermal stability for all irradiated samples is not greatly affected by the applied γ-ray irradiation dose. The thermodynamic properties of the decomposition processes (E a , A, ΔH*, ΔS*, and ΔG*) were calculated from TGA using the Coats-Redfern equations. The results of XRD showed that, all samples are in nanoscale size and γ-ray irradiation altered the crystallite size. Also, dc solid-state electrical conductivity was performed and the activation energy were computed. Furthermore, the in vitro antimicrobial property for the ligand and all complexes before and after irradiation have been tested. The results showed that some complexes possessed good activity and irradiation enhanced the bioactivity of some complexes.

Keywords: gamma ray irradiation; Mn(II) and Cu(II) metal complexes; bisamine based bidentate ligand
Corresponding authors: Hanaa A. El-Boraey, Department of Chemistry, Faculty of Science, Menoufia University, Shebin El-Kom, 32511, Egypt, E-mail: ; and Ohyla A. El-Gammal, Department of Pathology, University Hospital, Menoufia University, Shebin El-Kom, 32511, Egypt, E-mail:

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission. Hanaa A. El-Boraey: writing – review and editing, visualization, supervision. Azza A. Serag El-Din: writing – original draft, data curation. Ahmed A. Sakr: methodology, funding acquisition, formal analysis, writing – original draft. Ohyla A. EL-Gammal: writing – review and editing, writing – original draft, visualization, data curation, conceptualization.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: No funding was received for this work.

  7. Data availability: The data can be obtained in the Supplementary materials.

References

1. Sumithra, I. Coming Trends of Radiation Effects on Transition Metal Hydrates, Complexes and Environmentally Benign Substances-A Review. J. Chem. Chem. Sci. 2018, 8 (3), 410–421; https://doi.org/10.29055/jccs/596.Search in Google Scholar

2. El-Boraey, H. A.; El-Domiaty, A. M. Influences of γ-ray Irradiation on Physico-Chemical, Structural, X-Ray Diffraction, Thermal and Antimicrobial Activity of Some γ-irradiated N′, N′′′-((Z)-ethane-1, 2-diylidine) Bis (2-aminobenzohydrazide) Metal Complexes. Appl. Radiat. Isot., 2021, 174, 109774; https://doi.org/10.1016/j.apradiso.2021.109774.Search in Google Scholar PubMed

3. El-Boraey, H. A.; Abdel-Hakeem, M. A. Facile Synthesis, Spectral, EPR, XRD and Antimicrobial Screening of Some γ-irradiated N′, N‴-(1E, 2E)-1, 2-diphenylethane-1, 2-diylidene) Bis (2-aminobenzohydrazide) Metal Complexes. J. Mol. Struct. 2020, 1211, 128086; https://doi.org/10.1016/j.molstruc.2020.128086.Search in Google Scholar

4. El-Boraey, H. A.; AboYehia, S. M.; El-Gammal, O. A. Influence of High Energy γ-irradiation on Some Binuclear Transition Metal Complexes of Pentadentate Ligand: Spectral, Thermal, Modelling, X-Ray Diffraction, Morphological and Solid Electrical Conductivity. Appl. Radiat. Isot., 2022, 182, 110121; https://doi.org/10.1016/j.apradiso.2022.110121.Search in Google Scholar PubMed

5. Aly, S. A.; Hassan, S. S.; El-Boraey, H. A.; Eldourghamy, A.; Abdalla, E. M.; Alminderej, F. M.; Elganzory, H. H. Synthesis, Biological Activity, and the Effect of Ionization Radiation on the Spectral, XRD, and TGA Analysis of Cu (I), Cu (II), Zn (II), and Cd (II) Complexes. Arab. J. Sci. Eng. 2023, 1–19; https://doi.org/10.1007/s13369-023-07988-2.Search in Google Scholar

6. El-Boraey, H. A.; El-Gammal, O. A.; Abdel Sattar, N. G. Impact of Gamma-Ray Irradiation on Some Aryl-Amide-Bridged Schiff-Base Complexes: Spectral, TGA, XRD, and Antioxidant Properties. J. Radioanal. Nucl. Chem. 2020, 323 (1), 241–252; https://doi.org/10.1007/s10967-019-06946-3.Search in Google Scholar

7. Alshater, H.; El-Boraey, H. A.; Homoda, A. M. A.; EL-Gammal, O. A. Improving the Surface Morphology and Crystallite Size of Isonicotinohydrazide Based Binuclear Cr (III), Zn (II) and Sn (IV) Complexes after Irradiation with γ-rays. J. Mol. Struct. 2021, 1232, 129985; https://doi.org/10.1016/j.molstruc.2021.129985.Search in Google Scholar

8. Sekkina, M. A.; El-Boraey, H. A.; Aly, S. Further Studies on the Properties and Effect of High Energetic Ionizing Radiation on Copper (II) Complexes: 1H NMR, Electronic Absorption, ESR Spectra and Solid Electrical Conductivity. J. Radioanal. Nucl. Chem. 2014, 300 (2), 867–872; https://doi.org/10.1007/s10967-014-3053-x.Search in Google Scholar

9. Aly, S. A.; Elganzory, H. H.; Mahross, M. H.; Abdalla, E. M. Quantum Chemical Studies and Effect of Gamma Irradiation on the Spectral, Thermal, X‐ray Diffraction and DNA Interaction with Pd(II), Cu(I), and Cd(II) of Hydrazone Derivatives. Appl. Organomet. Chem. 2021, 35 (4), e6153; https://doi.org/10.1002/aoc.6153.Search in Google Scholar

10. El-Boraey, H. A.; Abdel-Qader, A.; Hussien, M. A. Structure Elucidation, DNA Interaction, Potential Anticancer, Molecular Docking Activities, and γ-ray Irradiation Studies on Novel Mono- and Binuclear Fe (II), Ni (II), Co (II), and Hg (II) Schiff Base Complexes. Appl. Organomet. Chem. 2022, 36, e6791; https://doi.org/10.1002/aoc.6791.Search in Google Scholar

11. Reyhani, A.; Gholizadeh, A.; Khanlari, M. Effect of Gamma Radiation on the Optical and Structural Properties of ZnO Nanowires with Various Diameters. Opt. Mater. 2018, 75, 236–242.10.1016/j.optmat.2017.10.027Search in Google Scholar

12. EL-Gammal, O. A.; El-Boraey, H. A.; Alshater, H. DNA Binding, Potential Anticancer, Antioxidant and Molecular Docking Simulations of Some Isonicotinohydrazide Metal Complexes with the Impact of High Energy γ-rays Irradiation Doses: Synthesis and Structural Characterization. J. Mol. Struct. 2024, 1310, 138236; https://doi.org/10.1016/j.molstruc.2024.138236.Search in Google Scholar

13. Jayashri, T.; Viji, K. Spectral, X-Ray Diffraction, Surface Morphological and Thermal Studies of Gamma-Irradiated Potassium Bis (Oxalato) Zincate (II) Dihydrate. Radiat. Eff. Defects S. 2018, 173 (11), 1–10; https://doi.org/10.1080/10420150.2018.1517352.Search in Google Scholar

14. Ayad, M. I.; El-Boraey, H. A. Characterization, Thermal and Electrical Conductivity of Some Transition Metal Adducts. Int. J. Chem. Tech. Res. 2014, 6 (1), 266–275.Search in Google Scholar

15. Ntanatsidis, S.; Perontsis, S.; Konstantopoulou, S.; Kalogiannis, S.; Hatzidimitriou, A. G.; Papadopoulos, A. N.; George, P. Manganese(II) Complexes of Substituted Salicylaldehydes and α-diimines: Synthesis, Characterization and Biological Activity. J. Inorg. Biochem. 2022, 227, 111693; https://doi.org/10.1016/j.jinorgbio.2021.111693.Search in Google Scholar PubMed

16. El-Boraey, H. A.; Abdel-Rahman, R. M.; Atia, E. M.; Hilmy, K. M. H. Spectroscopic, Thermal and Toxicity Studies of Some 2-Amino-3-Cyano-1, 5-diphenylpyrrole Containing Schiff Bases Copper (II) Complexes. Cent. Eur. J. Chem. 2010, 8 (4), 820–833; https://doi.org/10.2478/s11532-010-0046-7.Search in Google Scholar

17. El-Boraey, H. A.; Mansour, A. I. Synthesis, Spectral and Gamma Ray Irradiation Studies on Metal Complexes of N, N′-naphthalene-1, 8-diylbis (2-aminobenzamide). Inorg. Nano-Met. Chem. 2018, 48, 8–15; https://doi.org/10.1080/24701556.2017.1357588.Search in Google Scholar

18. West, T. S. Complexometry With EDTA and Related Reagents; BDH Chemicals Ltd: Galway, Ireland, 1969.Search in Google Scholar

19. Kashar, T. I.; Hassan, S. S.; El-Boraey, H. A. Spectroscopic Inspection, DFT Analysis, Biological Evaluation and Molecular Docking Studies of New 2-(phenylamino)acetohydrazide Hydrazone Based- Transition Metal Complexes. Inorg. Chim. Acta 2024, 563, 121903; https://doi.org/10.1016/j.ica.2023.121903.Search in Google Scholar

20. Bauer, A. W.; Kirby, W. M. M.; Sherris, J. C.; Turck, M. Antibiotic Susceptibility Testing by a Standardized Single Disk Method. Am. J.Clin. Pathol. 1966, 45 (4), 493–496; https://doi.org/10.1093/ajcp/45.4_ts.493.Search in Google Scholar

21. Lorono, J. R.; Marpa, M.; Ramos, D.; Celis, C. Synthesis, Characterization, Density Functional Theory Calculations, and In Vitro Antibacterial Activity of Novel Transition Metal Complexes Containing an O3-Tridentate Amoxicillin-Based Schiff Base: a Silver(II) Complex as Alternative against Pseudomonas aeruginosa Resistant to Amoxicillin. Appl. Organomet. Chem. 2020, 34, e5755; https://doi.org/10.1002/aoc.5755.Anacona.Search in Google Scholar

22. Benkova, M.; Soukup, O.; Marek, J. Antimicrobial Susceptibility Testing: Currently Used Methods and Devices and the Near Future in Clinical Practice. J. Appl. Microbiol. 2020, 129, 806–822; https://doi.org/10.1111/jam.14704.Search in Google Scholar PubMed

23. Yousif, E.; Majeed, A.; Al-Sammarrae, K.; Salih, N.; Salimon, J.; Abdullah, B. Metal Complexes of Schiff Base: Preparation, Characterization and Antibacterial Activity. Arab. J. Chem. 2017, 10, S1639–S1644; https://doi.org/10.1016/j.arabjc.2013.06.006.Search in Google Scholar

24. Geary, W. G. The Use of Conductivity Measurements in Organic Solvents for the Characterization of Coordination Compounds. Coord. Chem. Rev. 1971, 7, 81–122; https://doi.org/10.1016/s0010-8545(00)80009-0.Search in Google Scholar

25. Swamy, S. J.; Jyothi, S.; Someshwar, P.; Shashank, K.; Rao, G. R. Synthesis and Structural Analysis of N4-Donar Ligands and Their Complexes with Some Bivalent Transition Metal Ions. J. Applic. Chem. 2012, 1 (2), 218–231.Search in Google Scholar

26. Elantabli, F. M.; El-Medani, S. M.; Al-Anazi, A.; Shehata, M. R.; Haukka, M.; Mohamed, R. G. Synthesis, Spectroscopic, Characterization, X-Ray Single Crystal, DNA Interaction, DFT and Molecular Docking Studies of a New Schiff Base Ligand Derived from 1-((2-Hydroxy-2-Phenylethylimino)methyl)naphthalen-2-Ol, and Some Transition Metal; Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Pd (II) Complexes. J. Mol. Struct. 2025, 1330, 141511; https://doi.org/10.1016/j.molstruc.2025.141511.Search in Google Scholar

27. El-Boraey, H. A. Serag El-Din, A. A. Transition Metal Complexes of a New 15-membered [N5] Penta-Azamacrocyclic Ligand with Their Spectral and Anticancer Studies. Spectrochimica Acta A 2014, 132, 663–671.10.1016/j.saa.2014.05.018Search in Google Scholar PubMed

28. El-Boraey, H. A. Coordination Behavior of Tetraaza [N4] Ligand towards Co (II), Ni (II), Cu (II), Cu (I) and Pd (II) Complexes: Synthesis, Spectroscopic Characterization and Anticancer Activity. Spectrochim. Acta A 2012, 97, 255–262; https://doi.org/10.1016/j.saa.2012.05.077.Search in Google Scholar PubMed

29. El-Boraey, H. A.; Serag El-Din, A. A. Gamma Ray Irradiated Binuclear and Mononuclear Transition Metal Complexes with Polydentate Ligand: Template Synthesis, Spectral, XRD, Morphology, Solid Electrical Conductivity and Antimicrobial Activity. J. Mol. Struct. 2023, 1281, 134842; https://doi.org/10.1016/j.molstruc.2022.134842.Search in Google Scholar

30. El-Boraey, H. A.; Emam, S. M.; Tolan, D. A.; El -Nahas, A. M. Structural Studies and Anticancer Activity of a Novel (N6O4) Macrocyclic Ligand and its Cu (II) Complexes. Spectrochim. Acta A 2011, 78 (1), 360–370; https://doi.org/10.1016/j.saa.2010.10.021.Search in Google Scholar PubMed

31. El-Asmy, A. A.; Al-Abdeen, A. Z.; Abo El-Maaty, W. M.; Mostafa, M. M. Synthesis and Spectroscopic Studies of 2,5-hexanedione Bis(isonicotinylhydrazone) and its First Raw Transition Metal Complexes. Spectrochim. Acta 2010, 75, 1516–1522; https://doi.org/10.1016/j.saa.2010.02.009.Search in Google Scholar PubMed

32. El-Boraey, H. A.; El-Ghnam, H.; Atia, E. M.; Hassan, S. S. Designing of Some VO(II), Co(II) and Hg(II) Schiff Base Complexes: Synthesis, Structure Elucidation, Anticancer and Biopesticidal Activities, DFT and Docking Approaches. Results Chem. 2024, 11, 101767; https://doi.org/10.1016/j.rechem.2024.101767.Search in Google Scholar

33. Sumithra, I.; Jayashri, T.; Krishnan, G. X-Ray Diffraction, Spectroscopic, Thermal and Surface Morphological Studies of Gamma-Irradiated Diaquamalonatomanganese (II)(DMM). J. Radioanal. Nucl. Chem. 2016, 307 (2), 835–842; https://doi.org/10.1007/s10967-015-4283-2.Search in Google Scholar

34. Gorgulu, G.; Cicek, M.; Dede, B. Synthesis and Characterization of a Novel Aminoketooxime Ligand and Enzymatic Efficiencies of its Metal Complexes. Acta Phys. Pol., A 2018, 133 (2), 244–249; https://doi.org/10.12693/aphyspola.133.244.Search in Google Scholar

35. El-Boraey, H. A.; Abdel-Rahman, R. M.; Atia, E. M.; El-Gammal, O. A. Synthesis, Spectral and Thermal Studies of New Schiff Base Copper(II) Complexes with Their Biological Effect on Entomopathogenic Nematodes. Vietnam J. Chem. 2022, 60 (2), 140–156; https://doi.org/10.1002/vjch.202100080.Search in Google Scholar

36. Sekkina, M. M. A.; Kashar, T. I.; Aly, S. A. Spectrochemical Study and Effect of High Energatic Gamma Ray on Copper (II) Complexes. Solid State Sci. 2011, 13 (12), 2080–2085.10.1016/j.solidstatesciences.2011.07.015Search in Google Scholar

37. El Boraey, H. A.; EL Gammal, O. A. Macrocyclic Cu(II) and Pd(II) Complexes with New 16-membered Tetradentate [N4] Ligand: Synthesis, Characterization, 3D Molecular Modeling and In Vitro Anticancer and Antimicrobial Activities. J. Incl. Phenom. Macrocycl. Chem. 2018, 90, 123–134; https://doi.org/10.1007/s10847-017-0774-9.Search in Google Scholar

38. El-Boraey, H. A.; El-Gammal, O. A. New 15-membered Tetraaza (N4) Macrocyclic Ligand and its Transition Metal Complexes: Spectral, Magnetic, Thermal and Anticancer Activity. Spectrochim.Acta A 2015, 138, 553–562; https://doi.org/10.1016/j.saa.2014.11.015.Search in Google Scholar PubMed

39. Bibi, S.; Mohamad, S.; Abdul Manan, N. S.; Ahmad, J.; Kamboh, M. A.; Khor, S. M.; Yamin, B. M.; Abdul Halim, S. N. Synthesis, Characterization, Photoluminescence, and Electrochemical Studies of Novel Mononuclear Cu (II) and Zn (II) Complexes with the 1-benzylimidazolium Ligand. J. Mol. Struct. 2017, 1141, 31–38; https://doi.org/10.1016/j.molstruc.2017.03.072.Search in Google Scholar

40. El-Boraey, H. A.; El-Salamony, M. A.; Hathout, A. A. Macrocyclic [N5] Transition Metal Complexes: Synthesis, Characterization and Biological Activities. J. Incl. Phenom. Macrocycl. Chem. 2016, 86, 153–166; https://doi.org/10.1007/s10847-016-0649-5.Search in Google Scholar

41. Reddy, G. N.; Losetty, V.; Reddy, K. R.; Yadav, C. H.; Sampath, S. Synthesis, Spectroscopic Characterization, Physicochemical Properties, Biological Activity and Docking Study of Cu (II) and La (III) Metal Complexes with a Schiff Base Ligand. Polyhedron 2023, 244, 116615; https://doi.org/10.1016/j.poly.2023.116615.Search in Google Scholar

42. Hathaway, B.; Billing, D. The Electronic Properties and Stereochemistry of Mono-Nuclear Complexes of the Copper (II) Ion. Coord. Chem. Reviews 1970, 5 (2), 143–207; https://doi.org/10.1016/s0010-8545(00)80135-6.Search in Google Scholar

43. Bharti, S.; Choudhary, M.; Mohan, B.; Rawat, S. P.; Sharma, S. R.; Ahmad, K. Syntheses, Characterization, Superoxide Dismutase, Antimicrobial, Crystal Structure and Molecular Studies of Copper (II) and Nickel (II) Complexes with 2-((E)-(2, 4-dibromophenylimino) Methyl)-4- Bromophenol as Schiff Base Ligand. J. Mol. Struct. 2017, 1149, 846e861; https://doi.org/10.1016/j.molstruc.2017.07.101.Search in Google Scholar

44. EL-Gammal, O. A.; Alshater, H. A.; El-Boraey, H. A. Schiff Base Metal Complexes of 4-Methyl-1h-Indol-3-Carbaldehyde Derivative as a Series of Potential Antioxidants and Antimicrobial: Synthesis, Spectroscopic Characterization and 3D Molecular Modeling. J. Mol. Struct. 2019, 1195, 220–230; https://doi.org/10.1016/j.molstruc.2019.05.101.Search in Google Scholar

45. Coats, A. W.; Redfern, J. P. Kinetic Parameters from Thermogravimetric Data. Nature 1964, 20, 68–122; https://doi.org/10.1038/201068a0.Search in Google Scholar

46. Horowitz, H. H.; Metzger, G. A New Analysis of Thermogravimetric Traces. J. Anal. Chem. 1963, 35, 1464; https://doi.org/10.1021/ac60203a013.Search in Google Scholar

47. Abdel-Rahman, L. H.; Abu-Dief, A. M.; Moustafa, H.; Hamdan, S. K. Ni(II) and Cu(II) Complexes with ONNO Asymmetric Tetradentate Schiff Base Ligand: Synthesis, Spectroscopic Characterization, Theoretical Calculations, DNA Interaction and Antimicrobial Studies. Appl. Organometal. Chem. 2017, 31, e3555; https://doi.org/10.1002/aoc.3555.Search in Google Scholar

48. Hyperchem Sketch Release v 15. 0.0 for Windows Molecular Modeling System; Hypercube, Inc., 2008.Search in Google Scholar

49. Sen, S. K.; Paul, T. C.; Dutta, S.; Matin, M. A.; Islam, M. F.; Hakim, M. A. Effect of Gamma (γ-) Irradiation on the Structural, Morphological, Optical and Electrical Properties of Spray Pyrolysis-Deposited H-MoO3 Thin Films. Surf. Interfaces 2019, 17, 100377; https://doi.org/10.1016/j.surfin.2019.100377.Search in Google Scholar

50. Ambala, A.; Lincoln, C. A. Synthesis, Characterization, Antimicrobial Activity and DNA Cleavage Study of (E)-2-(((2-(P-Tolyloxy)Quinolin-3-Yl)Methylene)Amino)Benzenethiol Schiff Base Metal Complexes. Chem. Data Coll. 2020, 27, 100372; https://doi.org/10.1016/j.cdc.2020.100372.Search in Google Scholar

51. Dhanaraj, C. J.; Hassan, I. U.; Johnson, J.; Joseph, J.; Joseyphus, R. S. Synthesis, Spectral Characterization, DNA Interaction, Anticancer and Molecular Docking Studies on Some Transition Metal Complexes with Bidentate Ligand. J. Photochem. Photobiol. B: Biol. 2016, 162, 115–124; https://doi.org/10.1016/j.jphotobiol.2016.06.032.Search in Google Scholar PubMed

52. Abd El‐Halim, H.; Mohamed, G. G.; Anwar, M. N. Antimicrobial and Anticancer Activities of Schiff Base Ligand and its Transition Metal Mixed Ligand Complexes with Heterocyclic Base. Appl. Organomet. Chem. 2018, 32 (1), e3899; https://doi.org/10.1002/aoc.3899.Search in Google Scholar

53. Jayashri, T.; Krishnan, G.; Rani, N. R. Effect of Gamma-Irradiation on Thermal Decomposition Kinetics, X-Ray Diffraction Pattern and Spectral Properties of Tris (1, 2-diaminoethane) Nickel (II) Sulphate. Radiat. Eff. Defects Solids 2014, 169 (12), 1019–1030.10.1080/10420150.2014.980257Search in Google Scholar

54. Gaber, M.; El-Wakiel, N.; Hemeda, O. M. Cr(III), Mn(II), Co(II), Ni(II) and Cu(II) Complexes of 7-((1h-Benzo[d] imidazole-2-yl)diazenyl)-5-nitroquinolin-8-ol.Synthesis, Thermal, Spectral, Electrical Measurements, Molecular Modeling and Biological Activity. J. Mol. Struct. 2019, 1180, 318–329; https://doi.org/10.1016/j.molstruc.2018.12.006.Search in Google Scholar

55. Abd El Wahed, M. G.; Manakhly, K. A.; Barakat, A.; Amer, M. Electrical Conductivity of Some Hydrazones and Binary Complexes with Transition Metals. Monatsh. für Chem. 1996, 127 (11), 1115–1122.10.1007/BF00844685Search in Google Scholar

56. Asran, A. M.; Aldhalmi, A. K.; Mansour, M. S. A.; El-Sherif, A. A. Tridentate N-Donor Schiff Base Metal Complexes: Synthesis,characterization, Computational Studies, and Assessment of Biomedical Applications in Cancer Therapy, Helicobacter pylori Eradication, and COVID-19 Treatment. Inorg. Chem. Commun. 2025, 171, 113371.10.1016/j.inoche.2024.113371Search in Google Scholar

57. Abd El-Kader, M.; Elabbasy, M. Gamma Radiation Modified the Optical, Electrical, and Antibacterial Characterization of CuONPs Doped in Polyethylene Oxide/polyvinyl Alcohol. J. Mater. Res. Technol. 2020, 9 (6), 16179–16185.10.1016/j.jmrt.2020.11.046Search in Google Scholar

58. El-ghamry, M. A.; Omar, F. M.; Abdelrahman, M. S. A.; Saleh, A. A. Nano Metal Complexes of a New Carbohydrazone Based Ligand as Potential Antitumor Agents: Structural Elucidation, Thermal Behavior, Molecular Modeling, Docking Simulation, DNA Cleavage, and AC Conductivity Studies. J. Mol. Struct. 2023, 1293, 136316; https://doi.org/10.1016/j.molstruc.2023.136316.Search in Google Scholar

Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/ract-2025-0034).

Received: 2025-03-10
Accepted: 2025-05-29
Published Online: 2025-07-09
Published in Print: 2025-09-25

© 2025 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Separation and purification of Zr from a low-temperature LiCl–KCl–CsCl eutectic by the formation of dendritic crystal
  4. Particle-reinforced ion exchange resin for selective separation and recovery of cesium from highly acidic water
  5. Green synthesis of MnFe2O4 nanoparticles using Elaeis guineensis Jacq. leaves and empty fruit bunches extract and its radiolabeling with 99mTc as a potential agent for dual-modality imaging SPECT/MRI
  6. Mn(II) and Cu(II) metal complexes with bisamine based bidentate ligand. Spectroscopic investigation, biological activity and gamma ray irradiation impact
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https://doi.org/10.1515/ract-2025-0034
Keywords for this article
gamma ray irradiation; Mn(II) and Cu(II) metal complexes; bisamine based bidentate ligand

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Separation and purification of Zr from a low-temperature LiCl–KCl–CsCl eutectic by the formation of dendritic crystal
  4. Particle-reinforced ion exchange resin for selective separation and recovery of cesium from highly acidic water
  5. Green synthesis of MnFe2O4 nanoparticles using Elaeis guineensis Jacq. leaves and empty fruit bunches extract and its radiolabeling with 99mTc as a potential agent for dual-modality imaging SPECT/MRI
  6. Mn(II) and Cu(II) metal complexes with bisamine based bidentate ligand. Spectroscopic investigation, biological activity and gamma ray irradiation impact
  7. Synergistic influence of carbon black and montmorillonite nano clay on mechanical, electrical, and acoustic properties of nitrile butadiene rubber nanocomposites via gamma radiation
  8. Erbium-borate modified glass with lead and barium: new composite materials for gamma ray shielding
  9. Gamma and neutron radiation shielding properties of Al2O3–B2O3–SiO2–ZnO–BaO glasses
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