Abstract
Chicken eggshell powder (ESP) as natural source of CaCO3 was incorporated as natural filler into High Density Polyethylene (HDPE).This natural source can be considered as an effective alternative for the commercial calcium carbonate (CC) filler. Characterization of ESP and CC was investigated by FTIR and XRD analysis. HDPE composites filled with 30 phr (ESP) and (CC) were prepared using internal mixer. 2 phr maleic anhydride (MA) was added as compatibilizing agent to HDPE/ESP composite. The prepared composites were vulcanized by using γ-radiation at doses from 50 to 150 kGy. Mechanical and flame retardancy properties of all composites were investigated; composites were thermally analyzed using TGA and DSC. The results showed that, the mechanical properties of HDPE decrease by incorporation of ESP or CC into it, as it was noticed that the mechanical properties of HDPE/ESP composite were better than the mechanical properties of HDPE/CC composite. Moreover, addition of MA led to improvement in mechanical properties of the HDPE/ESP composite. As well, the thermal stability and flame retardancy of the composites increased by adding ESP or CC to HDPE. The results were proved by scanning electron microscopy (SEM).
Author contributions: Maysa A. Mohamed: Visualization, Writing review & editing. Rania Mounir: Methodology, Software, Writing original draft. Mai. M. EL-Zayat: Methodology, Software, Writing original draft. Heba A. Raslan: Methodology, Software, Writing original draft.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Saeb, M. R., Ghaffari, M., Rastin, H., Khonakdar, H. A., Simon, F., Najafi, F., Goodarzi, V., Vijayan, P. P., Puglia, D., Asl, F. H., Formela, K. Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels. RSC Adv. 2017, 7, 2230; https://doi.org/10.1039/c6ra24772e.Search in Google Scholar
2. Ji, G., Zhu, H., Qi, C., Zeng, M. Mechanism of interactions of eggshell microparticles with epoxy resins. Polym. Eng. Sci. 2009, 49, 1388; https://doi.org/10.1002/pen.21339.Search in Google Scholar
3. Dakhel, H. R. Using eggshell as filler in elastomeric compounds: effect of incubation period on its performance toward elastomers. e-Polymers 2008, 8, 140; https://doi.org/10.1515/epoly.2008.8.1.1618.Search in Google Scholar
4. Rezanavaz, R., Razavi Aghjeh, M. K., Babaluo, A. A. Rheology, morphology, and thermal behavior of HDPE/clay nanocomposites. Polym. Compos. 2010, 31, 1036; https://doi.org/10.1002/pc.20889.Search in Google Scholar
5. Wang, Q., Gao, J., Wang, R., Hua, Z. Mechanical and rheological properties of HDPE/graphite composite with enhanced thermal conductivity. Polym. Compos. 2001, 22, 103; https://doi.org/10.1002/pc.10521.Search in Google Scholar
6. Moez, A. A., Aly, S. S., Elshaer, Y. H. Effect of gamma radiation on low density polyethylene (LDPE) films: optical, dielectric and FTIR studies. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 2012, 93, 207; https://doi.org/10.1016/j.saa.2012.02.031.Search in Google Scholar
7. Farahana, R. N., Supri, A. G., Leng, T. P. Effect of maleic anhydride (MA) on properties of recycled high density polyethylene/ethylene vinyl acetate/egg shell powder (rHDPE/EVA/ESP) composites. Appl. Mech. Mater. 2014, 445, 95.10.4028/www.scientific.net/AMM.554.91Search in Google Scholar
8. Ferry, M., Pellizzi, E., Boughattas, I., Fromentin, E., Dauvois, V., deCombarieu, G., Coignet, P., Cochin, F., Ngono-Ravache, Y., Balanzat, E., Esnouf, S. Effect of cumulated dose on hydrogen emission from polyethylene irradiated under oxidative atmosphere using gamma rays and ion beams. Radiat. Phys. Chem. 2016, 118, 127; https://doi.org/10.1016/j.radphyschem.2015.06.006.Search in Google Scholar
9. Hamzah, M. S., Mariatti, M. Properties of flame-retardant fillers in polypropylene/ethylene propylene diene monomer composite. J. Thermoplast. Compos. Mater. 2013, 26, 1236; https://doi.org/10.1177/0892705712439561.Search in Google Scholar
10. Udomkan, N., Limsuwan, P. Temperature effects on freshwater snail shells: Pomacea canaliculata Lamarck as investigated by XRD, EDX, SEM and FTIR techniques. Mater. Sci. Eng. C 2008, 28, 316–319; https://doi.org/10.1016/j.msec.2007.03.001.Search in Google Scholar
11. Li, H.-Y., Tan, Y.-Q., Zhang, L., Zhang, Y.-X., Song, Y.-H., Ye, Y., Xia, M.-S. Bio-filler from waste shellfish shell: preparation, characterization, and its effect on the mechanical properties on polypropylene composites. J. Hazard. Mater. 2012, 217, 262.10.1016/j.jhazmat.2012.03.028Search in Google Scholar PubMed
12. Engin, B., Demirtas, H., Eken, M. Temperature effects on egg shells investigated by XRD, IR and ESR techniques. Radiat. Phys. Chem. 2006, 75, 277; https://doi.org/10.1016/j.radphyschem.2005.09.013.Search in Google Scholar
13. Coates, J. Interpretation of infrared spectra, a practical approach. In Encyclopedia of Analytical Chemistry; Meyers, R. A., Ed.; JohnWiley & Sons: Chichester, UK, 2000; pp. 10815–10837.10.1002/9780470027318.a5606Search in Google Scholar
14. Eshwaran, S. B., Amit, D., Hadi, R., Hoda, S., Seyed, H. J., Henri, V., Farhood, N., Hossein, A. K., Krzysztof, F., Maryam, J., Payam, Z., Mohammad, R. S. The taste of waste: the edge of eggshell over calcium carbonate in acrylonitrile butadiene rubber. J. Polym. Environ. 2019, 27, 2489.10.1007/s10924-019-01530-ySearch in Google Scholar
15. EL-Zayat, M. M., Mohamed, R. M., Raslan, H. A. Evaluation of surface treatment and gamma irradiation on the performance of palm fiber/natural rubber biocomposites. J. Macromol. Sci. Part A Pure Appl. Chem. 2020, 57, 354; https://doi.org/10.1080/10601325.2019.1698964.Search in Google Scholar
16. Nakano, T., Ikawa, N. I., Ozimek, L. Chemical composition of chicken eggshell and shell membranes. Poult. Sci. 2003, 82, 510–514; https://doi.org/10.1093/ps/82.3.510.Search in Google Scholar
17. Toro, P., Quijada, R., Arias, J. L., Yazdani‐Pedram, M. Mechanical and morphological studies of poly(propylene)-filled eggshell composites. Macromol. Mater. Eng. 2007, 292, 1034; https://doi.org/10.1002/mame.200700147.Search in Google Scholar
18. Intharapat, P., Kongnoo, A., Kateungngan, K. The potential of chicken eggshell waste as a bio-filler filled epoxidized natural rubber (ENR) composite and its properties. J. Polym. Environ. 2013, 21, 258; https://doi.org/10.1007/s10924-012-0475-9.Search in Google Scholar
19. Toro, P., Quijada, R., Yazdani-Pedram, M., Arias, J. L. Eggshell, a new bio-filler for polypropylene composites. Mater. Lett. 2007, 61, 4350; https://doi.org/10.1016/j.matlet.2007.01.102.Search in Google Scholar
20. Farahana, R. N., Suprib, A. G., Tehc, P. L. Effect of PVC-MA coupling agent on tensile, water absorption and morphological properties of recycled high density polyethylene/ethylene vinyl acetate/eggshell powder composites. J. Adv. Res. Mater. Sci. 2015, 10, 1–11.Search in Google Scholar
21. Intharapat, P., Keawcamchat, R., Thongmark, C. The Comparison Properties of Eggshell Calcium Carbonate and Commercial Calcium Carbonate filled Natural Rubber and Epoxidized Natural Rubber; IE Network Conference: Bangkok, Thailand, 2345, 2012.Search in Google Scholar
22. Goodarzi, V., Monemian, S. A., Angaji, M. T., Motahari, S. Improvement of thermal and fire properties of polypropylene. J. Appl. Polym. Sci. 2008, 10, 2979.10.1002/app.28892Search in Google Scholar
23. Zaharescu, T., Jipa, S., Kappel, W., Supaphol, P. The control of thermal and radiation stability of polypropylene containing calcium carbonate nanoparticles. Macromol. Symp. 2006, 242, 324; https://doi.org/10.1002/masy.200651044.Search in Google Scholar
24. Amal, S. M. B., Yamuna, M. Characterization of raw eggshell powder (ESP) as a good bio-filler. J. Eng. Res. Technol. 2015, 2, 56–60.Search in Google Scholar
25. Murugan, S., Munusamy, Y., Muniandy, M., Ismail, H. Development of HDPE-modified eggshell composite. Polym. Compos. 2018, 39, 1637; https://doi.org/10.1002/pc.24108.Search in Google Scholar
26. Bootklad, M., Kaewtatip, K. Biodegradation of thermoplastic starch/eggshell powder composites. Carbohydr. Polym. 2013, 97, 320; https://doi.org/10.1016/j.carbpol.2013.05.030.Search in Google Scholar
© 2021 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Original Papers
- Extraction behavior of Pu(IV), Th(IV), and fission product elements with hexapropyl and hexabutyl phosphoramides
- Impact of selected cement additives and model compounds on the solubility of Nd(III), Th(IV) and U(VI): screening experiments in alkaline NaCl, MgCl2 and CaCl2 solutions at elevated ionic strength
- Liquid-liquid extraction of Nd+3 and Eu+3 from aqueous medium using oxytetracycline in dichloromethane
- Preparation of a carrier free 124Sb tracer produced in the Sn (p, n) reaction
- Utilization of nanotechnology in targeted radionuclide cancer therapy: monotherapy, combined therapy and radiosensitization
- Synthesis, characterization, and bioevaluation of 99mTc nitrido-oxiracetam as a brain imaging model
- Physico-mechanical comparative study on gamma irradiated high density polyethylene/eggshell and commercial calcium carbonate composites
- Determination of scalp hair selenium concentrations in Algerian psoriatic individuals using k0-standardization based on neutron activation analysis method
- Alpha track registration and revelation in CR-39 using new etching method for ultratrace alpha radioactivity quantification in solution media
Articles in the same Issue
- Frontmatter
- Original Papers
- Extraction behavior of Pu(IV), Th(IV), and fission product elements with hexapropyl and hexabutyl phosphoramides
- Impact of selected cement additives and model compounds on the solubility of Nd(III), Th(IV) and U(VI): screening experiments in alkaline NaCl, MgCl2 and CaCl2 solutions at elevated ionic strength
- Liquid-liquid extraction of Nd+3 and Eu+3 from aqueous medium using oxytetracycline in dichloromethane
- Preparation of a carrier free 124Sb tracer produced in the Sn (p, n) reaction
- Utilization of nanotechnology in targeted radionuclide cancer therapy: monotherapy, combined therapy and radiosensitization
- Synthesis, characterization, and bioevaluation of 99mTc nitrido-oxiracetam as a brain imaging model
- Physico-mechanical comparative study on gamma irradiated high density polyethylene/eggshell and commercial calcium carbonate composites
- Determination of scalp hair selenium concentrations in Algerian psoriatic individuals using k0-standardization based on neutron activation analysis method
- Alpha track registration and revelation in CR-39 using new etching method for ultratrace alpha radioactivity quantification in solution media