Chemometric approach for prediction of uranium pathways in the soil
-
Mirjana Stojanović
,
Lato Pezo
Abstract
Understanding the effect of soil parameters (pH, Eh and organic and inorganic ligands availability) on uranium mobility under different geochemical conditions is fundamental for reliable prediction of its behaviour and fate in the environment. In this study, the impact of total and available phosphorus content, humus and acidity of Serbian agricultural soils on the content of total and available uranium were evaluated by Response Surface Methodology (RSM), second order polynomial regression models (SOPs) and artificial neural networks (ANNs). The performance of ANNs was compared with the performance of SOPs and experimental results. SOPs showed high coefficients of determination (0.785–0.956), while ANN model performed high prediction accuracy: 0.8893–0.904. According to the results, total and available uranium content in the soil were mostly affected by pH, statistically significant at p < 0.05 level. For the same responses the total phosphorus was found to be also very influential, statistically significant at p < 0.05 and p < 0.10 levels. The impact of available phosphourus and humus was much more influential on total and available uranium content, compared to total phosphorus content. Proposed chemometric approach will be very helpful in preserving the natural resources and practical application for risk assessment modeling of uranium environmental pathways.
©2014 Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Frontmatter
- Excitation functions and yields for cyclotron production of radiorhenium via deuteron irradiation: natW(d,xn)181,182(A+B),183,184(m+g),186gRe nuclear reactions and tests on the production of 186gRe using enriched 186W
- A route for polonium 210 production from alpha-particle irradiated bismuth-209 target
- High accuracy plutonium mass determination by controlled-potential coulometry
- Chemometric approach for prediction of uranium pathways in the soil
- Thermodynamic model for the solubility of Ba(SeO4, SO4) precipitates
- Suitability of various materials for porous filters in diffusion experiments
- Detoxification of azinophos methyl using gamma radiation mediated advance oxidation process and investigation of degradation products by HPLC and GC-MS
- Investigation of elemental and radiological contamination of soils in two shipyards in Chittagong, Bangladesh
- Radionuclide content and state of isotopic disequilibrium in some utilized smoking pastes
- Assessment of natural radioactivity in major building materials of Xiangyang, China
Articles in the same Issue
- Frontmatter
- Excitation functions and yields for cyclotron production of radiorhenium via deuteron irradiation: natW(d,xn)181,182(A+B),183,184(m+g),186gRe nuclear reactions and tests on the production of 186gRe using enriched 186W
- A route for polonium 210 production from alpha-particle irradiated bismuth-209 target
- High accuracy plutonium mass determination by controlled-potential coulometry
- Chemometric approach for prediction of uranium pathways in the soil
- Thermodynamic model for the solubility of Ba(SeO4, SO4) precipitates
- Suitability of various materials for porous filters in diffusion experiments
- Detoxification of azinophos methyl using gamma radiation mediated advance oxidation process and investigation of degradation products by HPLC and GC-MS
- Investigation of elemental and radiological contamination of soils in two shipyards in Chittagong, Bangladesh
- Radionuclide content and state of isotopic disequilibrium in some utilized smoking pastes
- Assessment of natural radioactivity in major building materials of Xiangyang, China
