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Complex permittivity measurements of RF plasma polymerized polyterpenol organic thin films employing split post dielectric resonator
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Kateryna Bazaka
Published/Copyright:
August 9, 2011
Abstract
In the fields of organic electronics and biotechnology, applications for organic polymer thin films fabricated using low-temperature non-equilibrium plasma techniques are gaining significant attention because of the physical and chemical stability of thin films and the low cost of production. Polymer thin films were fabricated from non-synthetic terpinen-4-ol using radiofrequency polymerization (13.56 MHz) on low loss dielectric substrates and their permittivity properties were ascertained to determine potential applications for these organic films. Real and imaginary parts of permittivity as a function of frequency were measured using the variable angle spectroscopic ellipsometer. The real part of permittivity (k) was found to be between 2.34 and 2.65 in the wavelength region of 400–1100 nm, indicating a potential low-k material. These permittivity values were confirmed at microwave frequencies. Dielectric properties of polyterpenol films were measured by means of split post dielectric resonators (SPDRs) operating at frequencies of 10 GHz and 20 GHz. Permittivity increased for samples deposited at higher RF energy – from 2.65 (25 W) to 2.83 (75 W) measured by a 20-GHz SPDR and from 2.32 (25 W) to 2.53 (100 W) obtained using a 10-GHz SPDR. The error in permittivity measurement was predominantly attributed to the uncertainty in film thickness measurement.
Published Online: 2011-08-09
Published Online: 2011-07-08
Published in Print: 2011-07-01
©2011 by Walter de Gruyter Berlin Boston
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Keywords for this article
permittivity;
polymer thin films;
polyterpenol films;
split post dielectric resonators
Articles in the same Issue
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- Fluctuation-induced forces in critical crosslinked polymer blends
- Chemical and physical properties of self-crosslinked poly(vinyl chloride)/nitrile rubber nanocomposites prepared by melt-mixing process
- An effective tool to characterize adhesion at the interface of binary polymer blends: a free volume study
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- Electrostrictive polymer composite for energy harvesters and actuators
- Dynamic mechanical behavior of phenoxy/carbon nanotube composites: assessment through different functionalization
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- Synthesis and characterization of modified poly(methyl methacrylate)/Al2O3nanocomposites as denture resins
- A study on the potential of NCF thermoplastic composites for use in aeronautic structural applications
- Electromagnetic response of polymer composites with quasi-spherical nanocarbon inclusions: theory below the percolation threshold
- Processing and characterization of titanium dioxide composites from vegetable oil resource
- Thermo-mechanical properties and thermal conductivity of CdS-trans-polyisoprene, polymer nanocomposite
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