Influence of different dimensional nanoparticles on the properties of poly(β-hydroxybutyrate-co-valerate) nanocomposites
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Jianxiang Chen
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Liqiang Deng
Abstract
In order to study the effect of nanoparticle dimensions on the thermodynamic properties of PHBV and PHBV blends, one-dimensional cellulose nanocrystals (CNC), two-dimensional graphene, and zero-dimensional hydrophobic nano-silica were selected to regulate the crystallization and mechanical properties of poly(β-hydroxybutyrate-co-valerate) (PHBV) and PHBV blends. The morphology, crystallization process, mechanical property and rheological response of PHBV nanomaterials were analyzed. Experimental results show that the three selected nanomaterials all hinder the crystallization process of PHBV, among which two-dimensional graphene exhibits the most obvious hindrance. At the same time, two-dimensional graphene can improve the tensile strength and impact strength of PHBV. However, in the rheological response of PHBV nanocomposites, zero-dimensional hydrophobic nano-silica and one-dimensional cellulose nanocrystals show more obvious regulatory effects than two-dimensional graphene.
Acknowledgments
Jianxiang Chen wishes to acknowledge Professor Defeng Wu (Yangzhou University) for the help with testing.
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Research ethics: Not applicable.
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Author contributions: Jianxiang Chen: Conceptualization, Methodology, Investigation, Writing – Original Draft, Writing – Review & Editing. Liqiang Deng: Validation, Writing – Review & Editing. Qianqian Chen: Formal analysis, Investigation.
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Competing interests: The authors state no conflict of interest.
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Research funding: None declared.
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Data availability: The raw data can be obtained on request from the corresponding author.
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© 2024 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Material Properties
- Effect of titanium diboride on the rheological characteristics of silica-based polyethylene glycol shear thickening fluid
- Influence of different dimensional nanoparticles on the properties of poly(β-hydroxybutyrate-co-valerate) nanocomposites
- Preparation and Assembly
- Multifunctional hydrogels for wound healing
- Stiff, strong, and tear-resistant physical hydrogels with widely tunable toughness by post-treatments
- Study on the adhesion of PTFE/PI composite films by interlocking synergistic effects
- Physically cross-linked scaffold composed of hydroxyapatite-chitosan-alginate-polyamide has potential to trigger bone regeneration in craniofacial defect
- Engineering and Processing
- Influence of CNTs on the gradient phase structure formed by the layered resin structure used to model the interlaminar region of interleaved FRPs
- Innovative reactor design for the preparation of polymer electrolyte membranes for vanadium flow batteries from preirradiation induced graft copolymerization of acrylic acid and AMPS on PVDF
Articles in the same Issue
- Frontmatter
- Material Properties
- Effect of titanium diboride on the rheological characteristics of silica-based polyethylene glycol shear thickening fluid
- Influence of different dimensional nanoparticles on the properties of poly(β-hydroxybutyrate-co-valerate) nanocomposites
- Preparation and Assembly
- Multifunctional hydrogels for wound healing
- Stiff, strong, and tear-resistant physical hydrogels with widely tunable toughness by post-treatments
- Study on the adhesion of PTFE/PI composite films by interlocking synergistic effects
- Physically cross-linked scaffold composed of hydroxyapatite-chitosan-alginate-polyamide has potential to trigger bone regeneration in craniofacial defect
- Engineering and Processing
- Influence of CNTs on the gradient phase structure formed by the layered resin structure used to model the interlaminar region of interleaved FRPs
- Innovative reactor design for the preparation of polymer electrolyte membranes for vanadium flow batteries from preirradiation induced graft copolymerization of acrylic acid and AMPS on PVDF
