Home Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)
Article
Licensed
Unlicensed Requires Authentication

Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)

  • Zhiyuan Shen , Faliang Luo EMAIL logo , Jianghua Du , Xiaomei Lei and Lijie Ji
Published/Copyright: January 20, 2017
Become an author with De Gruyter Brill
Submit Manuscript Author Information
Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 37 Issue 8

Abstract

The blends of poly (butylene terephthalate) (PBT) and 4,4′-dihydroxyphenyl (DHP) were prepared by melt blending, and the effects of DHP on the crystallization and melting behaviors of PBT were investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and polarized optical microscopy (POM). The results showed that crystallization temperature and crystallinity of PBT apparently decreased with the addition of DHP. A remarkably decline in crystallization rate of PBT was achieved, and the blends had higher σe and q values than that of pure PBT as analyzed based on the Avrami equation and Lauritzen-Hoffman equation. The crystal structure of PBT did not change by the addition of DHP, while the spherulite size of PBT decreased.

Keywords: blends; crystallization; 4,4′-dihydroxyphenyl; melting; poly (butylene terephthalate)

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 21264012

Funding statement: We gratefully acknowledge the financial support from the National Natural Science Foundation of China (no. 21264012).

Acknowledgments

We gratefully acknowledge the financial support from the National Natural Science Foundation of China (no. 21264012).

References

[1] Yao X, Tian X, Zhang X, Zheng K, Zheng J, Wang R, Kang S, Cui P. J. Polym. Eng. Sci. 2009, 49, 799–807.10.1002/pen.21318Search in Google Scholar

[2] Oburoğlu N, Ercan N, Durmus A, Kaşgöz A. J. Appl. Polym. Sci. 2012, 123, 77–91.10.1002/app.34464Search in Google Scholar

[3] Deshmukh GS, Peshwe DR, Pathak SU, Ekhe JD. Ther Acta 2015, 606, 66–76.10.1016/j.tca.2015.03.008Search in Google Scholar

[4] Wu D, Zhou C, Fan X, Mao D, Bian Z. J. Appl. Polym. Sci. 2006, 99, 3257–3265.10.1002/app.22782Search in Google Scholar

[5] Yan H, Xu J, Mai K, Zeng H. Polymer 1999, 40, 4865–4875.10.1016/S0032-3861(98)00694-6Search in Google Scholar

[6] Jang J, Sim K. Polym. Test. 1998, 17, 507–521.10.1016/S0142-9418(97)00066-4Search in Google Scholar

[7] Liau W-B, Tung S-H, Lai W-C, Yang L-Y. Polymer 2006, 47, 8380–8388.10.1016/j.polymer.2006.09.046Search in Google Scholar

[8] Li J, He Y, Inoue Y. J. Polym. Sci., Part B: Polym. Phys. 2001, 39, 2108–2117.10.1002/polb.1185Search in Google Scholar

[9] Kuo S-W, Chan S-C, Chang F-C. Macromolecules 2003, 36, 6653–6661.10.1021/ma034695aSearch in Google Scholar

[10] Luo F-L, Luo F-H, Xing Q, Zhang X-Q, Jiao H-Q, Yao M, Luo C-T Wang D-J. Chin. J. Polym. Sci. 2013, 31, 1685–1696.10.1007/s10118-013-1364-ySearch in Google Scholar

[11] Si P-F, Luo F-L, Xue P, Yan D-G. J Polym Res. 2016, 23, 118–126.10.1007/s10965-016-1010-9Search in Google Scholar

[12] Shen Z-Y, Luo F-L, Bai H-C, Si P-F, Lei X-M, Ding S-F, Ji L-J. RSC Adv. 2016, 6, 17510–17518.10.1039/C5RA25438HSearch in Google Scholar

[13] Lim JY, Kim J, Kim S, Kwak S, Lee Y, Seo Y. Polymer 2015, 62, 11–18.10.1016/j.polymer.2015.02.012Search in Google Scholar

[14] Righetti MC, Munari A. Macromol. Chem. Phys. 1997, 198, 363–378.10.1002/macp.1997.021980212Search in Google Scholar

[15] Hergenrother WL, Nelson CJ. J. Polym. Sci., Polym. Chem. Edit. 1974, 12, 2905–2915.10.1002/pol.1974.170121217Search in Google Scholar

[16] Dou J, Liu Z. Polym. Int. 2013, 62, 1698–1710.10.1002/pi.4470Search in Google Scholar

[17] Hong P-D, Chung W-T, Hsu C-F. Polymer 2002, 43, 3335–3343.10.1016/S0032-3861(02)00163-5Search in Google Scholar

[18] Cai J, Liu M, Wang L, Yao K, Li S, Xiong H. Carbohydr. Polym. 2011, 86, 941–947.10.1016/j.carbpol.2011.05.044Search in Google Scholar

[19] Xiao X, Zeng Z, Xue W, Kong Q, Zhu W. Polym. Eng. Sci. 2013, 53, 482–490.10.1002/pen.23287Search in Google Scholar

[20] Kalkar AK, Deshpande VD, Vatsaraj BS. Thermochim. Acta 2013, 568, 74–94.10.1016/j.tca.2013.06.019Search in Google Scholar

[21] Hu G, Feng X, Zhang S, Yang M. J. Appl. Polym. Sci. 2008, 108, 4080–4089.10.1002/app.28048Search in Google Scholar

[22] Huang JW, Wen YL, Kang CC, Yeh MY, Wen SB. J. Appl. Polym. Sci. 2008, 109, 3070–3079.10.1002/app.27628Search in Google Scholar

[23] Briber RM, Thomas EL. Polymer 1986, 27, 66–70.10.1016/0032-3861(86)90356-3Search in Google Scholar

[24] Runt J, Miley DM, Zhang X, Gallagher KP, McFeaters K, Fishburn J. Macromolecules 1992, 25, 1929–1934.10.1021/ma00033a015Search in Google Scholar

Received: 2016-6-11
Accepted: 2016-12-5
Published Online: 2017-1-20
Published in Print: 2017-10-26

©2017 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Original articles
  3. 3D printing of hydroxyapatite polymer-based composites for bone tissue engineering
  4. Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)
  5. Effect of the particulate morphology of resin on the gelation process of PVC plastisols
  6. Effect of aluminum nitride concentration on different physical properties of low density polyethylene based nanocomposites
  7. Application of polyurethane membrane with surface modified ZSM-5 for pervaporation of phenol/water mixture
  8. Synergistic effects of hybridization of carbon black and carbon nanotubes on the mechanical properties and thermal conductivity of a rubber blend system
  9. Electrical conductivity of carbon nanotube/polypropylene composites prepared through microlayer extrusion technology
  10. Mechanical performance and electromagnetic shielding effectiveness of composites based on Ag-plating cellulose micro-nano fibers and epoxy
  11. Effect of screw configuration on the dispersion of nanofillers in thermoset polymers
  12. Study of a novel co-rotating non-twin screw extruder in processing flame retardant polymer materials
  13. Thermal influences in the star-pre-distributor of a spiral mandrel die
https://doi.org/10.1515/polyeng-2016-0206
Keywords for this article
blends; crystallization; 4,4′-dihydroxyphenyl; melting; poly (butylene terephthalate)

Articles in the same Issue

  1. Frontmatter
  2. Original articles
  3. 3D printing of hydroxyapatite polymer-based composites for bone tissue engineering
  4. Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)
  5. Effect of the particulate morphology of resin on the gelation process of PVC plastisols
  6. Effect of aluminum nitride concentration on different physical properties of low density polyethylene based nanocomposites
  7. Application of polyurethane membrane with surface modified ZSM-5 for pervaporation of phenol/water mixture
  8. Synergistic effects of hybridization of carbon black and carbon nanotubes on the mechanical properties and thermal conductivity of a rubber blend system
  9. Electrical conductivity of carbon nanotube/polypropylene composites prepared through microlayer extrusion technology
  10. Mechanical performance and electromagnetic shielding effectiveness of composites based on Ag-plating cellulose micro-nano fibers and epoxy
  11. Effect of screw configuration on the dispersion of nanofillers in thermoset polymers
  12. Study of a novel co-rotating non-twin screw extruder in processing flame retardant polymer materials
  13. Thermal influences in the star-pre-distributor of a spiral mandrel die
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 3.12.2025 from https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2016-0206/html?lang=en
Scroll to top button