Nonisothermal crystallization kinetics of polybutene-1 containing nucleating agent with acid amides structure
-
Yongxian Zhao
,
Junyi Chen
Abstract
The nonisothermal crystallization behaviors of virgin isotactic polybutene-1 (iPB-1) and iPBn (iPB-1 containing a nucleating agent that owns acid amides structure; iPB/Mult920=100/0.5, mass ratio) were studied by means of differential scanning calorimetry (DSC). Modified Avrami theories (Ozawa method) and Mo method were used to analyze the DSC date. The results show that both methods are suitable to describe the crystallization process of iPB-1 and iPBn. Addition of 0.5% (mass ratio) nucleating agent can give rise to the nucleation effect, which increases the crystallization temperature (Tc) and the rate of crystallization of iPB-1, decreases the activation energy of crystallization (ΔE), and increases the crystallization rate of iPB-1 under the actual conditions.
This work was financially supported by the National Natural Science Foundation of China (51243002 and 51373084), the Natural Science Foundation of Shandong Province of China (ZR2010EM025 and ZR2012EMM003), and the Public Welfare Project of AQSIQ (201010009 and 201410083-03).
References
[1] Lucaini L, Seppala J, Lofgren B. Prog. Polym. Sci. 1988, 13, 37–62.Search in Google Scholar
[2] Tosaka M, Kamijo T, Tsuji M, Kohjiya S, Ogawa T, Isoda S, Kobayashi T. Macromolecules 2000, 33, 9666–9672.10.1021/ma001495fSearch in Google Scholar
[3] Danusso F, Gianotti G. Die Makromol. Chem. 1963, 61, 139–156.Search in Google Scholar
[4] Abedi S, Sharifi-Sanjiani N. Appl. Polym. Sci. 2000, 78, 2533–2539.Search in Google Scholar
[5] Busfield WK, Watson GS. ACS Symp. Series 1996, 6, 74–80.10.1021/bk-1996-0620.ch005Search in Google Scholar
[6] Yamashita M, Ueno S. Crystal Res. Technol. 2007, 42, 1222–1227.Search in Google Scholar
[7] Hong K-B, Joseph ES. J. Appl. Polym. Sci. 1985, 30, 3163–3188.Search in Google Scholar
[8] Kalay G, Kalay CR. J. Appl. Polym. Sci. 2003, 88, 814–824.Search in Google Scholar
[9] Cebe P, Hong S. Polymer 1986, 27, 1183–1192.10.1016/0032-3861(86)90006-6Search in Google Scholar
[10] Mandelkern L. Crystallization of Polymers, McGraw-Hill, New York, 1964, 306.Search in Google Scholar
[11] Jeziorny A. Polymer 1978, 19, 1142–1144.10.1016/0032-3861(78)90060-5Search in Google Scholar
[12] Shih CK. Adv. Polym. Technol. 1992, 11, 222–229.Search in Google Scholar
[13] Shih CK. Polym. Eng. Sci. 1995, 35, 1688–1694.Search in Google Scholar
[14] Kinssinger HE. J. Res. Natl. Stand. 1956, 57, 217–225.Search in Google Scholar
[15] Supaphol P, Dangseeyun N, Srimoaon P. Polym. Test. 2004, 23, 175–185.Search in Google Scholar
©2014 by Walter de Gruyter Berlin Boston
Articles in the same Issue
- Masthead
- Masthead
- Publisher’s note
- Editorial changes at the Journal of Polymer Engineering
- Editorial
- A new Editor-in-Chief for Journal of Polymer Engineering
- Original articles
- Microcellular injection molding of recycled poly(ethylene terephthalate) blends with chain extenders and nanoclay
- Structure and performance of polybutene-1 pipes produced via mandrel rotation extrusion
- Analysis of the effect of molecular weight and testing rate on shear strength of epoxidized natural rubber-based adhesives with a statistical model
- The use of waste rubber in natural rubber in the presence of maleic anhydride-grafted natural rubber (MA-g-NR): study on curing, rheology, morphology, and properties of the blend
- Morphology, mechanical, bound rubber, swelling, and dynamic mechanical studies of chlorobutyl elastomer nanocomposites: effect of multiwalled carbon nanotube and solvent
- Nonisothermal crystallization kinetics of polybutene-1 containing nucleating agent with acid amides structure
- The effect of organoclay contents on morphological characterization, mechanical and thermal properties of epoxidized natural rubber-50 toughened polyamide 6 nanocomposites
- Tensile properties of polycaprolactone/nano-CaCO3 composites
- Influence of two novel compatibilizers on the properties of LDPE/organoclay nanocomposites
- Development and characterization of novel photopolymerizable formulations for stereolithography
- Modeling of vapor-liquid equilibrium for binary polypropylene glycol/solvent solutions using cubic equation of state models: optimization and comparison of CEoS models
Articles in the same Issue
- Masthead
- Masthead
- Publisher’s note
- Editorial changes at the Journal of Polymer Engineering
- Editorial
- A new Editor-in-Chief for Journal of Polymer Engineering
- Original articles
- Microcellular injection molding of recycled poly(ethylene terephthalate) blends with chain extenders and nanoclay
- Structure and performance of polybutene-1 pipes produced via mandrel rotation extrusion
- Analysis of the effect of molecular weight and testing rate on shear strength of epoxidized natural rubber-based adhesives with a statistical model
- The use of waste rubber in natural rubber in the presence of maleic anhydride-grafted natural rubber (MA-g-NR): study on curing, rheology, morphology, and properties of the blend
- Morphology, mechanical, bound rubber, swelling, and dynamic mechanical studies of chlorobutyl elastomer nanocomposites: effect of multiwalled carbon nanotube and solvent
- Nonisothermal crystallization kinetics of polybutene-1 containing nucleating agent with acid amides structure
- The effect of organoclay contents on morphological characterization, mechanical and thermal properties of epoxidized natural rubber-50 toughened polyamide 6 nanocomposites
- Tensile properties of polycaprolactone/nano-CaCO3 composites
- Influence of two novel compatibilizers on the properties of LDPE/organoclay nanocomposites
- Development and characterization of novel photopolymerizable formulations for stereolithography
- Modeling of vapor-liquid equilibrium for binary polypropylene glycol/solvent solutions using cubic equation of state models: optimization and comparison of CEoS models
