Home Oxidation of Higher Alkanes at Moderate Reaction Conditions with Ozone in Presence of Mesoporous Materials
Article
Licensed
Unlicensed Requires Authentication

Oxidation of Higher Alkanes at Moderate Reaction Conditions with Ozone in Presence of Mesoporous Materials

  • V. S. R. Rajasekhar Pullabhotla and S. B. Jonnalagadda EMAIL logo
Published/Copyright: November 30, 2016
Become an author with De Gruyter Brill
Author Information
Journal of Advanced Oxidation Technologies
From the journal Journal of Advanced Oxidation Technologies Volume 11 Issue 3

Abstract

The scope of mesoporous molecular sieves, Al-MCM-41, as catalysts in the ozone initiated fuctionalisation of higher n-alkanes at 20 ± 1 °C and ~1 atm conditions is investigated. Oxygen is introduced into carbonaceous site in the product molecule forming 2-, 3- and 4- keto- isomers as main products and carboxylic acids as minor products. The % conversion, reaction products and selectivity for the catalysed reactions are compared. In presence of catalysts, the relative selectivity towards 4-ketone is increased.

Keywords: Oxidation; mesoporous Al-MCM-41; n-Hexadecane; 4-Hexadecanone and Ozone
Received: 2008-3-27
Revised: 2008-6-20
Accepted: 2008-6-24
Published Online: 2016-11-30
Published in Print: 2008-8-1

© 2016 by Walter de Gruyter Berlin/Boston

Articles in the same Issue

  1. Toxicity Assessment and Degradation of Disperse Azo Dyes by Photoelectrocatalytic Oxidation on Ti/TiO2 Nanotubular Array Electrodes
  2. Photolysis and TiO2 Photocatalytic Treatment of Naproxen: Degradation, Mineralization, Intermediates and Toxicity
  3. Oxidation of Higher Alkanes at Moderate Reaction Conditions with Ozone in Presence of Mesoporous Materials
  4. Modulating the Oxidation of FMNH2 by Organophosphorus Compounds
  5. Enhancement of the Photodegradation of Methylene Blue by Combined Titania Photocatalyst and Photo-Fenton
  6. Epoxidation of Allyl Alcohol to Glycidol over Titanium-Silicalite Ti-Beta and Ti-MCM-41 Catalysts
  7. Photocatalysis with TiO2 and SnO2/TiO2 Films Examined by a Kinetic Model
  8. Photolytic and Photocatalytic Diminution and Preliminary Genotoxicity Studies of 2-Chloropyridine
  9. Photocatalytic Degradation of 4-Nitrophenol in a Continuous Reactor Containing Titanium Dioxide Supported on Glass Beads
  10. Photocatalytic Inactivation of Wild and Hyper-Adherent E. Coli Strains in Presence of Suspended or Supported TiO2. Influence of the Isoelectric Point of the Particle Size and of the Adsorptive Properties of Titania
  11. Comparison of UV- and UV/VUV-Induced Photolytic and Heterogeneous Photocatalytic Degradation of Phenol, with Particular Emphasis on the Intermediates
  12. Effect of Ozone Oxidation on the Molecular and Kinetic Properties of Effluent Organic Matter
  13. Treatment of Antibiotic Formulation Wastewaters by Fenton Process
  14. Homogeneous and Heterogeneous Catalytic Ozonation of Pulp Bleaching Effluent
  15. Spectroscopic and Mass-Spectrometric Study of Acridine Orange Photodegradation on the Surface of Mesoporous TiO2, SiO2 /TiO2 and SiO2 Films
  16. Application of Response Surface Methodology to Optimise C.I. Acid Orange 7 Azo Dye Mineralization by UV/H2O2 Process
  17. Chemical Treatment by Fenton’s Reagent Oxidation and Ozonation of Wastewaters from Olive Oil Mill
  18. Analysis of Primary Degradation and Decolourization of Dyes in Water by an H2O2/UV Advanced Oxidation Process
  19. A Novel Adsorption/Saturation Approach to Ultrasonic Degradation of Phenol
https://doi.org/10.1515/jaots-2008-0303
Keywords for this article
Oxidation; mesoporous Al-MCM-41; n-Hexadecane; 4-Hexadecanone and Ozone

Articles in the same Issue

  1. Toxicity Assessment and Degradation of Disperse Azo Dyes by Photoelectrocatalytic Oxidation on Ti/TiO2 Nanotubular Array Electrodes
  2. Photolysis and TiO2 Photocatalytic Treatment of Naproxen: Degradation, Mineralization, Intermediates and Toxicity
  3. Oxidation of Higher Alkanes at Moderate Reaction Conditions with Ozone in Presence of Mesoporous Materials
  4. Modulating the Oxidation of FMNH2 by Organophosphorus Compounds
  5. Enhancement of the Photodegradation of Methylene Blue by Combined Titania Photocatalyst and Photo-Fenton
  6. Epoxidation of Allyl Alcohol to Glycidol over Titanium-Silicalite Ti-Beta and Ti-MCM-41 Catalysts
  7. Photocatalysis with TiO2 and SnO2/TiO2 Films Examined by a Kinetic Model
  8. Photolytic and Photocatalytic Diminution and Preliminary Genotoxicity Studies of 2-Chloropyridine
  9. Photocatalytic Degradation of 4-Nitrophenol in a Continuous Reactor Containing Titanium Dioxide Supported on Glass Beads
  10. Photocatalytic Inactivation of Wild and Hyper-Adherent E. Coli Strains in Presence of Suspended or Supported TiO2. Influence of the Isoelectric Point of the Particle Size and of the Adsorptive Properties of Titania
  11. Comparison of UV- and UV/VUV-Induced Photolytic and Heterogeneous Photocatalytic Degradation of Phenol, with Particular Emphasis on the Intermediates
  12. Effect of Ozone Oxidation on the Molecular and Kinetic Properties of Effluent Organic Matter
  13. Treatment of Antibiotic Formulation Wastewaters by Fenton Process
  14. Homogeneous and Heterogeneous Catalytic Ozonation of Pulp Bleaching Effluent
  15. Spectroscopic and Mass-Spectrometric Study of Acridine Orange Photodegradation on the Surface of Mesoporous TiO2, SiO2 /TiO2 and SiO2 Films
  16. Application of Response Surface Methodology to Optimise C.I. Acid Orange 7 Azo Dye Mineralization by UV/H2O2 Process
  17. Chemical Treatment by Fenton’s Reagent Oxidation and Ozonation of Wastewaters from Olive Oil Mill
  18. Analysis of Primary Degradation and Decolourization of Dyes in Water by an H2O2/UV Advanced Oxidation Process
  19. A Novel Adsorption/Saturation Approach to Ultrasonic Degradation of Phenol
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 19.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/jaots-2008-0303/html?lang=en
Scroll to top button