Abstract
The aim of the present work is to study the biodegradability enhancement of a wastewater containing a non-biodegradable compound, 4-chlorophenol (4-CP), using a so-called Advanced Oxidation Process (AOP) named Photo-Fenton (Ph-F). The location of this study is in a more complex project the aim of which is the connection of this AOP with a biological treatment. The parameters to be studied are the initial concentrations of Fe2+ and H2O2 and the operating temperature. The work was planned using an experimental design named Central Composite Design (CCD), in order to observe the effect of each factor on different responses, such as 4-CP removal, Total Organic Carbon (TOC) removal, Chemical Oxygen Demand (COD) removal, Biochemical Oxygen Demand (BOD5)/COD ratio evolution and total time until the total consumption of hydrogen peroxide. The operating conditions are optimized taking into account the operating costs. The results showed that Fe2+ and temperature do not affect the degradation and biodegradability enhancement results, but they affect significantly the time of the experiment, and consequently the operating costs.
© 2016 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Preface
- Removal of PAHs from Creosote Oil Contaminated Soil by Addition of Concentrated H2O2 and Biodegradation
- Kinetics of Wet Oxidation Reactions
- Biodegradability Enhancement of Wastewater Containing 4-Chlorophenol by Means of Photo-Fenton
- Experimental and Modelling Approach for the Comparison of Fenton and Electro-Fenton Processes. Preliminary Results
- TiO2/C Photocatalyst Prepared by Ethanol Vapour Treatment of TiO(OH)2
- Effects of Carbon Coating on TinO2n-1 for Decomposition of Iminoctadine Triacetate in Aqueous Solution under Visible Light
- Hybrid Plasma-Catalyst System for the Removal of Trichloroethylene in Air
- Photocatalytic Oxidation of Emerging Contaminants: Kinetics and Pathways for Photocatalytic Oxidation of Pharmaceutical Compounds
- Photocatalytic Degradation of four Textile Azo Dyes in Aqueous TiO2 Suspensions: Practical Outcomes and Revisited Pathways
- Decolouration of Dye Solutions Using Photoelectrocatalysis and Photocatalysis
- Aged Raw Landfill Leachate: Membrane Fractionation, H2O2/UV Treatment and Molecular Size Distribution Analysis
- Electrochemical Treatment of Trace Endocrine Disrupting Chemicals with a Three-Dimensional Electrode System
- Semiconductor Mediated Photocatalysed Degradation of a Pesticide Derivative, Acephate in Aqueous Suspensions of Titanium Dioxide
- Hexavalent Chromium Remediation by Bore-Hole Placed Reduction Barriers and Monitored Natural Attenuation
Articles in the same Issue
- Preface
- Removal of PAHs from Creosote Oil Contaminated Soil by Addition of Concentrated H2O2 and Biodegradation
- Kinetics of Wet Oxidation Reactions
- Biodegradability Enhancement of Wastewater Containing 4-Chlorophenol by Means of Photo-Fenton
- Experimental and Modelling Approach for the Comparison of Fenton and Electro-Fenton Processes. Preliminary Results
- TiO2/C Photocatalyst Prepared by Ethanol Vapour Treatment of TiO(OH)2
- Effects of Carbon Coating on TinO2n-1 for Decomposition of Iminoctadine Triacetate in Aqueous Solution under Visible Light
- Hybrid Plasma-Catalyst System for the Removal of Trichloroethylene in Air
- Photocatalytic Oxidation of Emerging Contaminants: Kinetics and Pathways for Photocatalytic Oxidation of Pharmaceutical Compounds
- Photocatalytic Degradation of four Textile Azo Dyes in Aqueous TiO2 Suspensions: Practical Outcomes and Revisited Pathways
- Decolouration of Dye Solutions Using Photoelectrocatalysis and Photocatalysis
- Aged Raw Landfill Leachate: Membrane Fractionation, H2O2/UV Treatment and Molecular Size Distribution Analysis
- Electrochemical Treatment of Trace Endocrine Disrupting Chemicals with a Three-Dimensional Electrode System
- Semiconductor Mediated Photocatalysed Degradation of a Pesticide Derivative, Acephate in Aqueous Suspensions of Titanium Dioxide
- Hexavalent Chromium Remediation by Bore-Hole Placed Reduction Barriers and Monitored Natural Attenuation