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Effect of compatibilizer type on the properties of thermoplastic elastomers based on recycled polyethylene at high ground tire rubber content

  • Roberto C. Vázquez-Fletes , Youhong Wang , Rubén González-Núñez and Denis Rodrigue EMAIL logo
Published/Copyright: February 12, 2025
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International Polymer Processing
From the journal International Polymer Processing Volume 40 Issue 2

Abstract

In this study, compatibilized thermoplastic elastomers (TPE) based on recycled high-density polyethylene (HDPE) and high ground tire rubber (GTR) content (70, 80 and 90 wt%) were prepared by twin-screw extrusion followed by injection molding. The main objective of the work was to use three different compatibilizers and to compare their efficiency: ethylene-octene copolymer (Engage 8180), styrene-ethylene-butylene-styrene grafted with maleic anhydride (SEBS-g-MA) (Kraton FG1901X) and a trans-polyoctenamer (Vestenamer 8012). A morphological analysis showed that the addition of a compatibilizer produced more homogeneous structures, significantly improving mechanical performance compared with their uncompatibilized counterparts. This modification had a direct effect on all the properties, especially the tensile properties which were evaluated at different crosshead speeds (10, 50, 100 and 500 mm/min) to better see differences in the interfacial state. High elongations at break exceeding 100 % for highly filled recycled blends (up to 90 wt% of GTR) with Kraton FG1901X were obtained, highlighting superior compatibility efficiency. In general, adding GTR to recycled PE produced a more elastic TPE. Increasing the GTR concentration led to lower modulus (from 300 MPa for R-PE to 50 MPa for 70 % GTR). The main conclusion of the work was that injection molding of TPE with high GTR content (above 70 %) was only possible by adding compatibilizers. Nevertheless, the best performance to produce high GTR content TPE was obtained using Kraton FG1901X probably due to its grafted functionality (maleic anhydride, MA) leading to better interfacial interactions between the phases.

Keywords: recycled polyethylene; ground tire rubber; compatibilization; morphology; mechanical properties
Corresponding author: Denis Rodrigue, Department of Chemical Engineering and CERMA, Université Laval, Quebec, QC, G1V0A6, Canada, E-mail:

  1. Research ethics: All research has been carried out in conformance with the highest international and local standards of rigor and integrity.

  2. Informed consent: Not applicable.

  3. Author contributions: Conceptualization: Denis Rodrigue, Youhong Wang; investigation: Youhong Wang, Roberto C. Vazquez Fletes; Data curation: Denis Rodrigue, Ruben Gonzalez Nunez, Roberto C. Vazquez Fletes. The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors declare no potential conflict of interest.

  6. Research funding: The authors acknowledge the financial support of the National Council of Science and Technology of Mexico (CONACyT) for scholarships (711143 and 740545) and Y. Wang for a scholarship from the China Scholarship Council.

  7. Data availability: Not applicable.

References

Alvarez-Barajas, R., Cuadri, A.A., Delgado-Sanchez, C., Navarro, F.J., and Partal, P. (2024). Bio and waste-based binders with hybrid rubberized-thermoplastic characteristics for roofing. Polym. Test. 130: 108317, https://doi.org/10.1016/j.polymertesting.2023.108317.Search in Google Scholar

Book Drobny, J.G. (2014). Handbook of thermoplastic elastomers, 2nd ed PDL Handbook series, Amsterdam.10.1016/B978-0-323-22136-8.00013-2Search in Google Scholar

Colom, X., Cañavate, J., Carrillo, F., and Suñol, J. (2009). Effect of the particle size and acid pretreatments on compatibility and properties of recycled HDPE plastic bottles filled with ground tyre powder. J. Appl. Polym. Sci. 112: 1882–1890, https://doi.org/10.1002/app.29611.Search in Google Scholar

Datta, J. and Włoch, M. (2015). Morphology and properties of recycled polyethylene/ground tyre rubber/thermoplastic poly(ester-urethane) blends. Macromol. Res. 23: 1117–1125, https://doi.org/10.1007/s13233-015-3155-5.Search in Google Scholar

Davies, R.G. and Magee, C.L. (1975). The effect of strain-rate upon the tensile deformation of materials. J. Eng. Mater. Technol. 97: 151–155, https://doi.org/10.1115/1.3443275.Search in Google Scholar

De Sousa, F.D.B., Scuracchio, C.H., Hu, G., and Hoppe, S. (2017). Devulcanization of waste tire rubber by microwaves. Polym. Degrad. Stab. 138: 169–181, https://doi.org/10.1016/j.polymdegradstab.2017.03.008.Search in Google Scholar

Debska, B., Caetano, M.A., and Brigolini Silva, G.J. (2024). Study of the influence of accelerated aging on the physical and mechanical properties of polymer composites containing rubber, polyethylene and poly(ethylene terephthalate) waste. J. Clean. Prod. 444: 141273, https://doi.org/10.1016/j.jclepro.2024.141273.Search in Google Scholar

Dou, Y. and Rodrigue, D. (2018). Rotomolding of foamed and unfoamed GTR-LLDPE Blends: mechanical, morphological and physical properties. Cell. Polym. 37: 55–68, https://doi.org/10.1177/026248931803700201.Search in Google Scholar

Esmizadeh, E., Naderi, G., Bakhshandeh, G.R., Fasaie, M.R., and Ahmadi, S. (2017). Reactively compatibilized and dynamically vulcanized thermoplastic elastomers based on high-density polyethylene and reclaimed rubber. Polym. Sci. Ser. B 59: 362–371, https://doi.org/10.1134/s1560090417030046.Search in Google Scholar

Fazli, A. and Rodrigue, D. (2021). Morphological and mechanical properties of thermoplastic elastomers based on recycled high density polyethylene and recycled natural rubber. Int. Polym. Process. 36: 156–164, https://doi.org/10.1515/ipp-2020-4006.Search in Google Scholar

Fazli, A. and Rodrigue, D. (2022). Thermoplastic elastomers based on recycled high-density polyethylene/ground tire rubber/ethylene vinyl acetate: effect of ground tire rubber regeneration on morphological and mechanical properties. J. Thermoplast. Compos. Mater. 36: 2285–2310, https://doi.org/10.1177/08927057221095388.Search in Google Scholar PubMed PubMed Central

Fazli, A. and Rodrigue, D. (2020). Waste Rubber Recycling: a review on the evolution and properties of thermoplastic elastomers. Mater 13: 782, https://doi.org/10.3390/ma13030782.Search in Google Scholar PubMed PubMed Central

Geyer, R., Jambeck, J., and Law, K.L. (2017). Production, use, and fate of all plastics ever made. Sci. Adv. 3, https://doi.org/10.1126/sciadv.1700782.Search in Google Scholar PubMed PubMed Central

Grammelis, P., Margaritis, N., Dallas, P., Rakopoulos, D.C., and Mavrias, G. (2021). A review on management of end of life tires (ELTs) and alternative uses of textile fibers. Energies 14: 571, https://doi.org/10.3390/en14030571.Search in Google Scholar

Grigoryeva, O., Fainleib, A., Tolstov, A., Pissis, P., Spanoudaki, A., Vatalis, A., and Delides, C. (2006). Thermal analysis of thermoplastic elastomers based on recycled polyethylenes and ground tyre rubber. J. Therm. Anal. Calorim. 86: 229–233, https://doi.org/10.1007/s10973-005-7189-3.Search in Google Scholar

Grigoryeva, O., Tolstov, A., Starostenko, O., Fainleib, A., Lievana, E., and Karger-Kocsis, J. (2004). Part II characterisation. In: Composite technologies for 2020, 1st ed Elsevier eBooks, Cambridge, pp. 175–186.Search in Google Scholar

Heller, B., Simon‐Stőger, L., Makó, É., and Varga, C.A. (2022). Practical manner to GTR recycling in waste-HDPE/ABS. J. Polym. Res. 29, https://doi.org/10.1007/s10965-022-03167-3.Search in Google Scholar

Hrdlička, Z., Brejcha, J., Šubrt, J., Vrtiška, D., Malinová, L., Čadek, D., and Kadeřábková, A. (2021). Ground tyre rubber produced via ambient, cryogenic, and waterjet milling: the influence of milling method and particle size on the properties of SBR/NR/BR compounds for agricultural tyre treads. Plast. Rubber Compos. 51: 497–506, https://doi.org/10.1080/14658011.2021.2008713.Search in Google Scholar

Ismail, H., Awang, M., and Hazizan, M.A. (2006). Effect of waste tire dust (WTD) size on the mechanical and morphological properties of Polypropylene/Waste Tire Dust (PP/WTD) blends. Polym.-Plas. Technol. 45: 463–468, https://doi.org/10.1080/03602550600553739.Search in Google Scholar

Kakroodi, A.R. and Rodrigue, D. (2013). Highly filled thermoplastic elastomers from ground tire rubber, maleated polyethylene and high density polyethylene. Plast. Rubber Compos. 42: 115–122, https://doi.org/10.1179/1743289812y.0000000042.Search in Google Scholar

Karger‐Kocsis, J., Mészáros, L., and Bárány, T. (2012). Ground tyre Rubber (GTR) in thermoplastics, thermosets, and rubbers. J. Mater. Sci. 48: 1–38, https://doi.org/10.1007/s10853-012-6564-2.Search in Google Scholar

Kiss, L., Simon, D.A., Petrény, R., Kocsis, D., Barany, T., and Mészaros, L. (2022). Ground tire rubber filled low-density polyethylene: the effect of particle size. Adv. Ind. Eng. Poly. Res. 5: 12–17, https://doi.org/10.1016/j.aiepr.2021.07.001.Search in Google Scholar

Kościuszko, A., Sykutera, D., Czyżewski, P., Hoyer, S., Kroll, L., and Szczupak, B. (2022). Processing and mechanical properties of highly filled PP/GTR compounds. Mater 15: 3799, https://doi.org/10.3390/ma15113799.Search in Google Scholar PubMed PubMed Central

Liu, S., Peng, Z., Zhang, Y., Rodrigue, D., and Wang, S. (2022). Compatibilized thermoplastic elastomers based on highly filled polyethylene with ground tire rubber. J. Appl. Polym. Sci. 139, https://doi.org/10.1002/app.52999.Search in Google Scholar

Mahallati, P. and Rodrigue, D. (2014). Effect of feeding strategy on the mechanical properties of PP/recycled EPDM/PP-g-MA blends. Int. Polym. Process. 29: 280–286, https://doi.org/10.3139/217.2855.Search in Google Scholar

Marín-Genescà, M., García-Amorós, J., Bordes-Arroyo, J., Mujal-Rosas, R., and Vidal, L.M. (2019). Study and comparison on mechanical properties of various polymers reinforced with ground tires rubber (GTR). IOP Conf. Ser.: Mater. Sci. Eng. 542: 012027, https://doi.org/10.1088/1757-899x/542/1/012027.Search in Google Scholar

Mohajerani, A., Burnett, L., Smith, J.G., Markovski, S., Rodwell, G., Rahman, T., Kurmus, H., Mirzababaei, M., Arulrajah, A., Horpibulsuk, S., et al.. (2020). Recycling waste rubber tyres in construction Materials and Associated Environmental Considerations: a review. RCR 155: 104679, https://doi.org/10.1016/j.resconrec.2020.104679.Search in Google Scholar

Mohite, A.S., Rajpurkar, Y.D., and More, A.P. (2021). Bridging the gap between rubbers and plastics: a review on thermoplastic polyolefin elastomers. Polym. Bull. 79: 1309–1343, https://doi.org/10.1007/s00289-020-03522-8.Search in Google Scholar

Nikiema, J. and Asiedu, Z. (2022). A review of the cost and effectiveness of solutions to address plastic pollution. Environ. Sci. Pollut. Res. Int. 29: 24547–24573, https://doi.org/10.1007/s11356-021-18038-5.Search in Google Scholar PubMed PubMed Central

Nitiyah, K.K., Musa, L., Rasidi, M.S.M., Rahim, S.Z.A., Rahman, R., Azmi, A.A., and Rennie, A. (2021). A review on graft compatibilizer for thermoplastic elastomer blend. J. Phys. 2080: 012003, https://doi.org/10.1088/1742-6596/2080/1/012003.Search in Google Scholar

Riyapan, D., Riyajan, S., and Kowalczyk, A. (2015). “Green synthesis” and characterization of a maleated epoxidized natural rubber latex. Polym. Bull. 72: 671–691, https://doi.org/10.1007/s00289-014-1298-8.Search in Google Scholar

Rosales, C., Ait Hocine, N., Bernal, C., and Pettarin, V. (2024). Toughness improvement of LLDPE/PP blend by incorporation of GTR waste. Polym. Bull. 81: 6743–6760, https://doi.org/10.1007/s00289-023-05027-6.Search in Google Scholar

Scuracchio, C.H., Waki, D.A., and Da Silva, M.L.C.P. (2007). Thermal analysis of ground tire rubber devulcanized by microwaves. J. Therm. Anal. Calorim. 87: 893–897, https://doi.org/10.1007/s10973-005-7419-8.Search in Google Scholar

Sonnier, R., Leroy, É., Clerc, L., Bergeret, A., Lopez-Cuesta, J.M., Bretelle, A.S., and Ienny, P. (2008). Compatibilizing thermoplastic/ground tyre rubber powder blends: efficiency and limits. Polym. Test. 27: 901–907, https://doi.org/10.1016/j.polymertesting.2008.07.003.Search in Google Scholar

Statista. Annual production of plastics worldwide from 1950 to 2021. https://www.statista.com/statistics/282732/global-production-of-plastics-since-1950/ (Accessed 9 October 2023).Search in Google Scholar

Tolstov, A., Grigoryeva, O., Fainleib, A., Danilenko, I., Spanoudaki, A., Pissis, P., and Grenet, J. (2007). Reactive compatibilization of Polyethylene/Ground tire rubber inhomogeneous blends via interactions of Pre‐Functionalized polymers in interface. Macromol. Symp. 254: 226–232, https://doi.org/10.1002/masy.200750834.Search in Google Scholar

Utracki, L.A. (2002). Compatibilization of polymer blends. Can. J. Chem. Eng, Can. J. Chem. Eng. 80: 1008–1016, https://doi.org/10.1002/cjce.5450800601.Search in Google Scholar

Veilleux, J. and Rodrigue, D. (2016). Properties of recycled PS/SBR blends: effect of SBR pretreatment. Prog. Rubber Plast. Recycl. Technol. 32: 111–128, https://doi.org/10.1177/147776061603200301.Search in Google Scholar

Wang, Y.H., Chen, Y.K., and Rodrigue, D. (2018). Production of thermoplastic elastomers based on recycled PE and ground tire rubber: morphology, mechanical properties and effect of compatibilizer addition. Int. Polym. Process. 33: 525–534, https://doi.org/10.3139/217.3544.Search in Google Scholar

Whelan, D.N. (2017). Chapter 4 thermoplastic elastomers. In: Brydsons plastics materials, 8th ed Elsevier eBooks, Amsterdam, pp. 653–703.10.1016/B978-0-323-35824-8.00024-4Search in Google Scholar

Yaqoob, H., Teoh, Y.H., Sher, F., Jamil, M.A., Murtaza, D., Qubeissi, M.A., Hassan, M.U., and Mujtaba, M. (2021). Current status and potential of tire pyrolysis oil production as an alternative fuel in developing countries. Sustainability 13: 3214, https://doi.org/10.3390/su13063214.Search in Google Scholar

Zedler, Ł., Kowalkowska-Zedler, D., Vahabi, H., Saeb, M.R., Colom, X., Wang, S., and Formela, K. (2019). Preliminary investigation on auto-thermal extrusion of ground tire rubber. Mater 12: 2090, https://doi.org/10.3390/ma12132090.Search in Google Scholar PubMed PubMed Central

Received: 2024-08-21
Accepted: 2024-12-23
Published Online: 2025-02-12
Published in Print: 2025-05-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/ipp-2024-0110
Keywords for this article
recycled polyethylene; ground tire rubber; compatibilization; morphology; mechanical properties

Articles in the same Issue

  1. Frontmatter
  2. Review Article
  3. Corrosion resistive conducting polymeric nanocomposite-based coatings on steel: a mechanistic insight
  4. Research Articles
  5. Effect of compatibilizer type on the properties of thermoplastic elastomers based on recycled polyethylene at high ground tire rubber content
  6. Analyzing the effects of solid fraction and heat treatment on the mechanical properties of 3D printed polymer lattices
  7. Effect of polyvinyl acetate on the properties of biodegradable thermoplastic starch/polyethylene glycol blends
  8. A color masterbatch assistance system for optimizing product color by masterbatch addition in injection molding of post-industrial recyclates
  9. Enhancing 3D printing with composite filaments incorporating electronic waste: a study on flexural and compression strength
  10. Development of enhanced co-continuous PVDF/PET nanocomposites via synergistic effects of graphite particle size, hybrid systems, and reduced graphene oxide
  11. Integration of nanographene and action of fiber sequences on functional behaviour of composite laminates
  12. Effect of chain branching on the rheological properties of HDPE/LLDPE and HDPE/LDPE blends under shear and elongational flows and evaluation of die swell and flow instabilities
  13. Effect of graphene nanoplatelets (GnPs) on low velocity impact properties of hybrid kevlar/basalt fiber reinforced epoxy based composites
  14. Sustainability in rotational molding: a study on recycling and the influence of additives
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