Home Dynamics investigation on methane hydrate formation process with combined promotion methods
Article
Licensed
Unlicensed Requires Authentication

Dynamics investigation on methane hydrate formation process with combined promotion methods

  • Yuanxia Wei , Jing Bai EMAIL logo , Junhao Xu , Chaoyue Zhang , Gengbiao Xie , Pan Li and Chun Chang
Published/Copyright: November 24, 2021

Abstract

Rapid generation of natural gas hydrates is the basis for the application of hydrate storage and transportation. In this work, the kinetic parameters of methane hydrate formation (gas consumption, gas consumption rate constant and reaction space velocity) both in the liquid continuous impinging stream (LIS) system and sodium dodecyl sulfate (SDS) + water and LIS combination system were investigated in a liquid-continuous impinging stream reactor. The gas consumption rate constant was 3.40 × 10−8 mol2 s−1 J−1 without the impinging stream, while it increased with the increase of impinging strength and reached the maximum value of 3.68 × 10−8 mol2 s−1 J−1 when the impinging strength was 0.21. In the SDS + water and LIS combination system, when the SDS concentration was 600 mg/L, the maximum gas consumption rate constant was 3.99 × 10−8 mol2 s−1 J−1 without the impinging stream, while it reached the maximum value of 4.61 × 10−8 mol2 s−1 J−1 when the impinging strength was 0.38. The results showed that the impinging stream can effectively promote the formation rate of methane hydrate, and single mechanical promotion was better than non-promoting mode but combination promotion methods was better than single mechanical promotion.


Corresponding author: Jing Bai, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; School of Mechanical and Power Engineering, Zhengzhou University, Zhengzhou 450001, China; Henan Outstanding Foreign Scientists’ Workroom, Zhengzhou 450001, China; and Engineering Laboratory of Henan Province for Biorefinery Technology and Equipment, Zhengzhou 450001, China, E-mail:

Funding source: National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809,"National Natural Science Foundation of China"

Award Identifier / Grant number: NSFC- 52006200

Award Identifier / Grant number: NSFC-U1404519

Funding source: Science and Technology Department of Henan Province http://dx.doi.org/10.13039/501100011447,"Science and Technology Department of Henan Province"

Award Identifier / Grant number: GZS2018004

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the National Natural Science Fund of China [grant number NSFC-U1404519]; the National Natural Science Fund of China [grant number NSFC-52006200]; and the Program of Biomass Resources Processing and Efficient Utilization of Outstanding Foreign Scientists’ Workroom [grant number GZS2018004].

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Aliabadi, M., A. Rasoolzadeh, F. Esmaeilzadeh, and A. Alamdari. 2015. “Experimental Study of Using CuO Nanoparticles as a Methane Hydrate Promoter.” Journal of Natural Gas Science and Engineering 27: 1518–22. https://doi.org/10.1016/j.jngse.2015.Search in Google Scholar

Bai, J., D. Liang, D. Li, S. Fan, J. Du, X. Dai, and Z. Long. 2010. “Continuous Formation Process of CO2 Gas Hydrate via a Vortex and Impinging Stream Reactor.” Energy & Fuels 24 (2): 1207–12. https://doi.org/10.1021/ef900694z.Search in Google Scholar

Bai, J., G. Xie, L. Li, Li Pan, S. Fang, and C. Chang. 2020. “Kinetics Investigation of Carbon Dioxide Hydrate Formation Process in a New Impinging Stream Reactor.” International Journal of Chemical Reactor Engineering 18 (1): 20190132. https://doi.org/10.1515/ijcre-2019-0132.Search in Google Scholar

Boswell, R., and T. S. Collett. 2011. “Current Perspectives on Gas Hydrate Resources.” Energy & Environmental Science 4 (4): 1206–15. https://doi.org/10.1039/c0ee00203h.Search in Google Scholar

Chong, Z. R., J. W. R. Moh, Z. Yin, J. Zhao, and P. Linga. 2018. “Effect of Vertical Wellbore Incorporation on Energy Recovery from Aqueous Rich Hydrate Sediments.” Applied Energy 229: 637–47. http://doi.rog/10.1016/j.apenergy.2018.08.020.10.1016/j.apenergy.2018.08.020Search in Google Scholar

Daimaru, T., A. Yamasaki, and Y. Yanagisawa. 2007. “Effect of Surfactant Carbon Chain Length on Hydrate Formation Kinetics.” Journal of Petroleum Science and Engineering 56 (1–3): 89–96. https://doi.org/10.1016/j.petrol.2005.07.007.Search in Google Scholar

Du, J., H. Li, and L. Wang. 2018. “Cooperative Effect of Surfactant Addition and Gas-Inducing Agitation on Methane Hydrate Formation Rate.” Fuel 230: 134–7. https://doi.org/10.1016/j.fuel.2018.05.035.Search in Google Scholar

Elperin, I. T. 1961. “Heat and Mass Transfer in Opposing Currents.” Journal of Engineering Physics 6: 62–8.Search in Google Scholar

Englezos, P., N. Kalogerakis, P. D. Dholabhai, and P. R. Bishnoi. 1987. “Kinetics of Formation of Methane and Ethane Gas Hydrates.” Chemical Engineering Science 42 (11): 2647–58.10.1016/0009-2509(87)87015-XSearch in Google Scholar

Fan, S., L. Yang, Y. Wang, X. Lang, Y. Wen, and L. Xia. 2014. “Rapid and High Capacity Methane Storage in Clathrate Hydrates Using Surfactant Dry Solution.” Chemical Engineering Science 106: 53–9. https://doi.org/10.1016/j.ces.2013.11.032.Search in Google Scholar

Federico, R., F. Mirko, and C. Beatrice. 2012. “Investigation on a novel reactor for gas hydrate production.” Applied Energy 99: 167–172, doi:http://doi.rog/10.1016/j.apenergy.2012.05.005.10.1016/j.apenergy.2012.05.005Search in Google Scholar

Ganji, H., M. Manteghian, K. Sadaghiani zadeh, M. R. Omidkhah, and H. Rahimi Mofrad. 2007. “Effect of Different Surfactants on Methane Hydrate Formation Rate, Stability and Storage Capacity.” Fuel 86: 434–41. https://doi.org/10.1016/j.fuel.2006.07.032.Search in Google Scholar

Golombok, M., E. Ineke, J. R. Luzardo, and Y. Y. He. 2009. “Resolving CO2 and Methane Hydrate Formation Kinetics.” Environmental Chemistry Letters 7 (4): 325–30. https://doi.org/10.1007/s10311-008-0173-y.Search in Google Scholar

Hao, W. F., J. Q. Wang, S. S. Fan, and W. B. Hao. 2007. “Study on Methane Hydration Process in a Semi-continuous Stirred Tank Reactor.” Energy Conversion and Management 48: 954–60. https://doi.org/10.1016/j.enconman.2006.08.007.Search in Google Scholar

Karaaslan, U., and M. Parlaktuna. 2000. “Surfactants as Hydrate Promoters.” Energy & Fuels 14 (5): 1103–7.10.1021/ef000069sSearch in Google Scholar

Li, A., L. Jiang, and S. Tang. 2017. “An Experimental Study on Carbon Dioxide Hydrate Formation Using a Gas-Inducing Agitated Reactor.” Energy 134: 629–37. https://doi.org/10.1016/j.energy.2017.06.023.Search in Google Scholar

Lin, Y., H. P. Veluswamy, and P. Linga. 2018. “Effect of Eco-Friendly Cyclodextrin on the Kinetics of Mixed Methane−Tetrahydrofuran Hydrate Formation.” Industrial & Engineering Chemistry Research 57: 5944–50. https://doi.org/10.1021/acs.iecr.7b05107.Search in Google Scholar

Link, D. D., E. P. Ladner, H. A. Elsen, and C. E. Taylor. 2003. “Formation and Dissociation Studies for Optimizing the Uptake of Methane by Methane Hydrates.” Fluid Phase Equilibria 211 (1): 1–10. https://doi.org/10.1016/S0378-3812(03)00153-5.Search in Google Scholar

Luo, Y.-T., J.-H. Zhu, S.-S. Fan, and G.-J. Chen. 2007. “Study on the Kinetics of Hydrate Formation in a Bubble Column.” Chemical Engineering Science 62 (4): 1000–9. https://doi.org/10.1016/j.ces.2006.11.004.Search in Google Scholar

McCallum, S. D., D. E. Riestenberg, O. Y. Zatsepina, and T. J. Phelps. 2007. “Effect of Pressure Vessel Size on the Formation of Gas Hydrates.” Journal of Petroleum Science and Engineering 56: 54–64. https://doi.org/10.1016/j.petrol.2005.08.004.Search in Google Scholar

Mech, D., G. Pandey, and J. S. Sangwai. 2015. “Effect of NaCl, Methanol and Ethylene Glycol on the Phase Equilibrium of Methane Hydrate in Aqueous Solutions of Tetrahydrofuran (THF) and Tetra-n-Butyl Ammonium Bromide (TBAB).” Fluid Phase Equilibria 402: 9–17. https://doi.org/10.1016/j.fluid.2015.05.030.Search in Google Scholar

Mizubayashi, H., T. Arai, S. Watanabe, N. Yanagisawa, et al. 2011. “Demonstration Study on Natural Gas Hydrate (NGH) Overland Transportation.” 三井造船技報 [0026-6825] Arai, T 203: 1–9.Search in Google Scholar

Mohebbi, V., A. Naderifar, R. M. Behbahani, and M. Moshfeghian. 2012. “Investigation of Kinetics of Methane Hydrate Formation during Isobaric and Isochoric Processes in an Agitated Reactor.” Chemical Engineering Science 76: 58–65. https://doi.org/10.1016/j.ces.2012.04.016.Search in Google Scholar

Mori, Y. 2015. “On the Scale-Up of Gas-Hydrate-Forming Reactors: The Case of Gas-dispersion-type Reactors.” Energies 8 (2): 1317–35. https://doi.org/10.3390/en8021317.Search in Google Scholar

Mori, Y. H. 2003. “Recent Advances in Hydrate-Based Technologies for Natural Gas Storage——a Review.” Journal of Chemical Industry and Engineering 54 (S1): 1–17.Search in Google Scholar

Skovborg, P., and P. Rasmussen. 1994. “A Mass Transport Limited Model for the Growth of Methane and Ethane Gas Hydrates.” Chemical Engineering Science 49: 1131–43. https://doi.org/10.1016/0009-2509(94)85085-2.Search in Google Scholar

Sloan, D. E. 2003. “Fundamental Principles and Applications of Natural Gas Hydrates.” Nature 426: 353–63. https://doi.org/10.1038/nature02135.Search in Google Scholar PubMed

Sloan, E. D., and C. A. Koh. 2007. Clathrate Hydrates of Natural Gases, 3rd ed. Los Angeles: CRC Press.10.1201/9781420008494Search in Google Scholar

Takaoki, T., K. Hirai, M. Kamei, and H. Kanda. 2005. “Study of Natural Gas Hydrate (NGH) Carriers.” In Proceedings of the Fifth International Conference on Gas Hydrates, Trondheim, Norway, 1258–65.Search in Google Scholar

Tang, L.-G., X.-S. Li, Z.-P. Feng, Y.-L. Lin, and S.-S. Fan. 2006. “Natural Gas Hydrate Formation in an Ejector Loop Reactor: Preliminary Study.” Industrial & Engineering Chemistry Research 45 (23): 7934–40. https://doi.org/10.1021/ie0609259.Search in Google Scholar

Tian, Y., Y. Li, H. An, J. Ren, and J. Su. 2017. “Kinetics of Methane Hydrate Formation in an Aqueous Solution with and without Kinetic Promoter (SDS) by Spray Reactor.” Journal of Chemistry 2017: 5. Article ID 5208915. https://doi.org/10.1155/2017/5208915.Search in Google Scholar

Veluswamy, H. P., A. J. H. Wong, and P. Babu. 2016. “Rapid Methane Hydrate Formation to Develop a Cost Effective Large Scale Energy Storage System.” Chemical Engineering Science 290: 161–73. https://doi.org/10.1016/j.cej.2016.01.026.Search in Google Scholar

Watanabe, S., S. Takahashi, H. Mizubayashi, S. Murata, and H. Murakami. 2008. “A Demonstration Project of NGH Land Transportation System.” In Proceedings of the 6th International Conference on Gas Hydrates, Vancouver, 6–10 July 2008.Search in Google Scholar

Xiao, P., X. M. Yang, C. Y. Sun, J. L. Cui, N. Li, and G. J. Chen. 2018. “Enhancing Methane Hydrate Formation in Bulk Water Using Vertical Reciprocating Impact.” Chemical Engineering Journal 336: 649–58. https://doi.org/10.1016/j.cej.2017.12.020.Search in Google Scholar

Yoslim, J., P. Linga, and P. Englezos. 2010. “Enhanced Growth of Methane–Propane Clathrate Hydrate Crystals with Sodium Dodecyl Sulfate, Sodium Tetradecyl Sulfate, and Sodium Hexadecyl Sulfate Surfactants.” Journal of Crystal Growth 313 (1): 68–80. https://doi.org/10.1016/j.jcrysgro.2010.10.009.Search in Google Scholar

Zhang, J. S., S. Lee, and J. W. Lee. 2007. “Kinetics of Methane Hydrate Formation from SDS Solution.” Industrial & Engineering Chemistry Research 46 (19): 6353–9. https://doi.org/10.1021/ie070627r.Search in Google Scholar

Zhang, Z. E., Z. M. Liu, Z. Pan, F. M. Baena-Moreno, and M. R. Soltanian. 2020. “Effect of Porous Media and its Distribution on Methane Hydrate Formation in the Presence of Surfactant.” Applied Energy 261. https://doi.org/10.1016/j.apenergy.2019.114373.Search in Google Scholar

Zhao, J., Y. Zhao, W. Liang, S. Song, and Q. Gao. 2018a. “Semi-clathrate Hydrate Process of Methane in Porous Media-Mesoporous Materials of SBA-15.” Fuel 220: 446–52. http://doi.rog/10.1016/j.fuel.2018.01.010.10.1016/j.fuel.2018.01.010Search in Google Scholar

Zhao, Y., J. Zhao, W. Liang, Q. Gao, and D. Yang. 2018b. “Semi-clathrate Hydrate Process of Methane in Porous Media-Microporous Materials of 5A-type Zeolites.” Fuel 220: 185–91. http://doi.rog/10.1016/j.fuel.2018.01.067.10.1016/j.fuel.2018.01.067Search in Google Scholar

Zhong, D. L., S. Y. He, and D. J. Sun. 2014. “Comparison of Methane Hydrate Formation in Stirred Reactor and Porous Media in the Presence of SDS.” Energy Procedia 61: 1573–6. https://doi.org/10.1016/j.egypro.2014.12.174.Search in Google Scholar

Received: 2021-09-04
Accepted: 2021-11-10
Published Online: 2021-11-24

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 26.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/ijcre-2021-0229/html?lang=en
Scroll to top button