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Feasibility of Micropollutants Treatment by Coupling Nanofiltration and Electrochemical Oxidation: Case of Hospital Wastewater

  • Yandi Lan , Clemence Coetsier , Christel Causserand EMAIL logo and Karine Groenen Serrano
Published/Copyright: April 17, 2015

Abstract

In spite of good performances of the membrane bioreactor (MBR) process, permeate from it can still contain refractory pollutants that have to be removed before water reuse or discharge. The present study is an attempt to combine the advantages of two well-known technologies, which are nanofiltration (NF) and electrochemical oxidation (EO) to treat MBR effluent from hospital wastewater. The concept is based on a preconcentration of micropollutants with a reduction of the wastewater volume by NF and treatment of the NF retentate by oxidation. During filtration process the rejection of ciprofloxacin, as a target molecule, reached beyond 97%. Then the NF retentate was treated by EO using a boron-doped diamond anode (BDD). Galvanostatic electrolyses showed that this anode is efficient to mineralize not only ciprofloxacin but also all the micropollutants and organics contained in MBR effluent. The results demonstrated that rapid mineralization occurred: the removal of total organic carbon and chemical oxygen demand (COD) reached 97% and 100%, respectively, in our conditions in 300 min maximum. The specific energy consumption for the total removal of COD was calculated to be 50 kW h kg˗1 COD.

Acknowledgments

Authors are grateful to the coordinator of the Project PANACEE supported by the French National Research Agency for allowing them access to hospital wastewater. They also wish to thank the company Polymem for providing membrane module.

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Published Online: 2015-4-17
Published in Print: 2015-6-1

©2015 by De Gruyter

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