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Effects of the Types and Addition Amounts of Sludge on the True Rheological Properties of Petroleum Coke Slurry Flowing in Pipelines

  • Meng Liu EMAIL logo , Yufeng Duan and Xiuyuan Ma
Published/Copyright: March 14, 2015

Abstract

Effects of the types and addition amounts of sludge on the true rheological properties of petroleum coke water/sludge slurry (PCWS/PCSS) flowing in pipelines were investigated using the Tikhonov regularization method. Results show that PCWS of 59.8 wt% changes from pseudo-plastic fluid to dilatant fluid as the shear rate increases. However, PCWS of 63.4 wt% is a very complex fluid: shear thinning at low shear rate, followed by shear thickening over a critical shear rate, and a subsequent shear thinning at high shear rate. Rheological properties of PCWS have a significant change after the sludge was added. PCSS changes from dilatant fluid to pseudo-plastic fluid when the addition amounts of sewage sludge ascend to 10 wt%. Petroleum coke particles are trapped by the stable “network” structures, which are formed by flocculent sludge particles. The wall slip velocity of PCSS is higher than that of PCWS with the sludge amount increases, which is beneficial for pipe transportation. In addition, the wall slip velocity of PCSS containing sewage or petrochemical sludge increases with the wall shear rate increases, but the slip velocity of PCSS containing paper mill sludge first increases and then decreases.

Funding statement: Funding: The research was supported by the National Science Foundation of China (No.51206028), the National Basic Research Program of China (973 Program, 2010CB227001) and China Postdoctoral Science Foundation (2012M520971).

Nomenclature

D

Diameter of pipeline (m)

L

Length of pipeline (m)

ΔP

Pressure drop (Pa)

Q

Total volumetric flow rate (m3/s)

Qs

Slip volumetric flow rate (m3/s)

Qc

Center volumetric flow rate (m3/s)

R

Radius of pipeline (m)

S1

Sum of the squares of the deviation (dimensionless)

S2

Second derivatives of the two unknown functions at the split point (dimensionless)

V

Velocity (m/s)

Vslip

column vector of slip velocity (dimensionless)

us

Slip velocity (m/s)

uc

Center velocity (m/s)

uslip (τw)

Unknown function of slip velocity (m/s)

Greek letters
τwm

Experimental wall shear stress (Pa)

γam

Experimental apparent shear rate (s−1)

γ(τw)

Unknown function of shear rate (s−1)

δi

Fractional deviation (dimensionless)

λ

Regularization parameter (dimensionless)

ηa

Apparent true shear viscosity (mPa s)

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Published Online: 2015-3-14
Published in Print: 2015-9-1

©2015 by De Gruyter

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