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Enhanced stability of PVA electrospun fibers in water by adding cellulose nanocrystals

  • Anna Sutka EMAIL logo , Andris Sutka , Sergej Gaidukov , Martin Timusk , Janis Gravitis and Silvija Kukle
Published/Copyright: April 14, 2015
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Abstract

The solubility of electrospun poly(vinyl alcohol) nanofiber mats (PVAES-NFM) is strongly influenced by loading with nanocellulose (NC). The NC was derived from hemp shives obtained by steam explosion autohydrolysis followed by water and alkaline extraction, ball milling, and ultrasonication treatments. It was demonstrated for the first time that PVAES-NFM does not disintegrate in aqueous medium after simple adding of NC without any additional chemical or physical modification (PVAES-NFMNC). The structural and thermal studies on PVAES-NFMNC indicated that enhanced stability in aqueous medium can be explained by interactions between surface groups of NC and PVA macromolecules as well as by reinforcing the effect of NCs. The experimental findings could be important for filtration applications in environments with high relative humidity.


Corresponding author: Anna Sutka, Institute of Design Technology, Riga Technical University, Azenes 18, Riga LV-1048, Latvia, e-mail: ; and Laboratory of Biomass Eco-Efficient Conversion, Latvian State Institute of Wood Chemistry, Dzerbenes Street 27, Riga LV-1006, Latvia

Acknowledgments

The study has been supported by the European Social Fund within the project “Support for the Implementation of Doctoral Studies at Riga Technical University” and by the National Research Program “Forest and Earth Entrails Resources: Research and Sustainable Utilization – New Products and Technologies” (ResProd) (2010–2019). The authors kindly acknowledge the Institute of Silicate Materials for XRD measurements and recommendations.

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Received: 2014-9-30
Accepted: 2015-2-18
Published Online: 2015-4-14
Published in Print: 2015-8-1

©2015 by De Gruyter

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