Abstract
Hemicelluloses extracted prior to kraft pulping can subsequently be introduced as wet-end strength additives in a papermaking process. The 4-O-methyl glucuronoxylan (Me-GluX) extracted from Eucalyptus grandis (E. grandis) under mild alkaline conditions was cationized and added to bleached kraft pulp (BKP) from E. grandis before refining. The cationization by 2,3-epoxypropyltrimethylammonium chloride (ETA) was done in a central composite designed experiment. Me-GluX with an average molecular weight of 52,000 g mol-1 contained 27% Klason residue. The cationic Me-GluX had degrees of substitution of the cationic side chain between 0.05 and 0.73 and uronic acid content between 6.1% and 12.7%. The cationic Me-GluX as a wet-end strength additive was compared to cationic starch (CatStarch 134) in handsheets. The handsheets with cationic Me-GluX showed improvement in tensile, burst, and tear indices and had lower air permeability than those with CatStarch 134 at dosages between 1.0% and 2.0%. Accordingly, cationized Me-GluX is a potential green wet-end strength additive, which could fully or partially replace the synthetic and starch additives.
Acknowledgments
The authors would like to thank PAMSA and SAPPI for their financial support as well as for obtaining the initial samples. This work is based on the research supported in part by the National Research Foundation of South Africa through the Technology and Human Resources for Industry Program (THRIP) project number TP20090718000020. The grantholder acknowledges that opinions, findings, and conclusions or recommendations expressed in any publication generated by NRF-supported research are of the author(s) and that the NRF accepts no liability whatsoever in this regard.
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©2014 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Frontmatter
- Review Article
- Multistage oxygen delignification of high-kappa pine kraft pulp with peroxymonosulfuric acid (Px)
- Original Articles
- Pyrolysis gas-chromatography mass-spectrometry (Py-GC/MS) to identify compression wood in Pinus radiata saplings
- Cationization of Eucalyptus grandis 4-O-methyl glucuronoxylan for application as a wet-end additive in a papermaking process
- Extractives of mechanically wounded wood and knots in beech
- Complex between lignin and a Ti-based coupling agent
- Synthesis and biological activities of maleated rosin-based dithiourea compounds
- Thermoplastic deformation of poplar wood plasticized by ionic liquids measured by a nonisothermal compression technique
- Anomalous thermal expansion behaviors of wood under dry and low-temperature conditions
- Interfacial properties of magnesium phosphate ceramics and sugar maple (Acer saccharum)
- Off-axis tensile strength and evaluation of the in-plane shear strength of paper
- Migration of cesium chloride dissolved in the liquid water of sugi (Cryptomeria japonica D. Don) during drying at 65°C
- Numerical modeling of timber with knots: the progressively damaged lattice approach vs. the equivalent damaged continuum
- Meetings
- Meetings
Articles in the same Issue
- Frontmatter
- Review Article
- Multistage oxygen delignification of high-kappa pine kraft pulp with peroxymonosulfuric acid (Px)
- Original Articles
- Pyrolysis gas-chromatography mass-spectrometry (Py-GC/MS) to identify compression wood in Pinus radiata saplings
- Cationization of Eucalyptus grandis 4-O-methyl glucuronoxylan for application as a wet-end additive in a papermaking process
- Extractives of mechanically wounded wood and knots in beech
- Complex between lignin and a Ti-based coupling agent
- Synthesis and biological activities of maleated rosin-based dithiourea compounds
- Thermoplastic deformation of poplar wood plasticized by ionic liquids measured by a nonisothermal compression technique
- Anomalous thermal expansion behaviors of wood under dry and low-temperature conditions
- Interfacial properties of magnesium phosphate ceramics and sugar maple (Acer saccharum)
- Off-axis tensile strength and evaluation of the in-plane shear strength of paper
- Migration of cesium chloride dissolved in the liquid water of sugi (Cryptomeria japonica D. Don) during drying at 65°C
- Numerical modeling of timber with knots: the progressively damaged lattice approach vs. the equivalent damaged continuum
- Meetings
- Meetings